Denoising using nonlinear multiscale representations

The goal of this paper is to present some numerical results for the one-dimensional denoising problem by using the nonlinear multiscale representations. We introduce modified thresholding strategies in this new context which give significant significant improvements for one-dimensional denoising problems. To cite this article: B. Matei, C. R. Acad. Sci. Paris, Ser. I 338 (2004).     

Lanthanum-based perovskites obtained in molten nitrates or nitrites

Lanthanum-based perovskites, LaMO₃ (where M = Mn, Fe, Co, Ni), have been synthesised from lanthanum precursors and corresponding 3d transition metal salts in molten alkali metal nitrates or nitrites. The reactivity of eight precursors in three molten salts of different basicity was analysed. Single phase orthorhombic LaMnO_3.11, and orthorhombic LaFeO₃ have been obtained in molten NaNO₂ at 723 K, for 2 h. LaCoO₃ is also formed in molten nitrite, but an increase of basicity, by adding Na₂O₂, was necessary to obtain LaNiO₃. The reaction systems were investigated by thermal analysis. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and specific surface area measurements (BET method) were used to characterise the synthesised nanopowders.     

Pure and doped lanthanum cobaltites obtained by combustion method

We report the synthesis of La_1−xSr_xCoO₃ nanopowders by solution combustion method using metal nitrates and -alanine (alanine method) or urea (urea method) as fuel. The influence of metal nitrates/organic substance molar ratio and the type of fuel was investigated. The isolated complex precursors were characterized by atomic absorption spectroscopy (AAS), FT-IR spectra and DTA–TG analysis. The La_1−xSr_xCoO₃ (x = 0–0.3) powders were characterized by X-ray diffraction (XRD), scanning electron microscopy–energy-dispersive X-ray analysis (SEM–EDX), as well as by specific surface area measurements. XRD patterns indicate the formation of single-phase LaCoO₃ (rhombohedral) when as-synthesized powders were calcined at 873 K, 3 h in the case of the alanine method and at 1073 K, 3 h for urea-based system. Also, strontium doped lanthanum cobaltites obtained by both methods at 1273 K are single phase with rhombohedral perovskite-like structure as XRD data have proved. SEM investigation of pure and doped lanthanum cobaltites reveal that the samples prepared by both methods have fine particles with tendency of agglomerates formation with different shapes, spongy aspect and high porosity. La_1−xSr_xCoO₃ nanopowders obtained by alanine method have larger specific surface area values than those prepared by urea method.     

Mesoporous carbon supported ultrasmall palladium particles as highly active catalyst for Suzuki‐Miyaura reaction

A fast and efficient eco‐friendly two‐step preparation of a palladium‐containing mesoporous carbon catalyst ( C1 ) from green and readily available carbon precursors (phloroglucinol and glyoxal), a porogen template (pluronic F‐127) and PdCl₂ is described. Catalyst C1 contains ultra‐small Pd nanoparticles (1.2 nm) uniformly dispersed in the carbon network and shows an outstanding activity for Suzuki‐Miyaura reactions in pure water: extremely low amounts of palladium (10 μequiv. in most cases) are sufficient to afford almost palladium‐free products (containing <0.25 ppm of precious metal without further purification steps).     

Prevalence of Antimicrobial Resistant Bacteria from Conjunctival Flora in an Eye Infection Prone Breed (Saint Bernard)

The conjunctival bacterial resident and opportunistic flora of dogs may represent a major source of dissemination of pathogens throughout the environment or to other animals and humans. Nevertheless, contamination with bacteria from external sources is common. In this context, the study of the antimicrobial resistance (AMR) pattern may represent an indicator of multidrug resistant (MDR) strains exchange. The present study was focused on a single predisposed breed—Saint Bernard. The evaluated animals were healthy, but about half had a history of ocular disease/treatment. The swabs collected from conjunctival sacs were evaluated by conventional microbiological cultivation and antimicrobial susceptibility testing (AST). The most prevalent Gram-positive was Staphylococcus spp.; regardless of the history, while Gram-negative was Pseudomonas spp.; exclusively from dogs with a history of ocular disease/treatment. Other identified genera were represented by Bacillus, Streptococcus, Trueperella, Aeromonas and Neisseria. The obtained results suggest a possible association between the presence of mixed flora and a history of ocular disease/treatment. A high AMR was generally observed (90%) in all isolates, especially for kanamycin, doxycycline, chloramphenicol and penicillin. MDR was recorded in Staphylococcus spp. and Pseudomonas spp. This result together with a well-known zoonotic potential may suggest an exchange of these strains within animal human populations and the environment.     

Algorithm for preliminary evaluation of the correlation time of local dynamics in some polymeric materials

A method for preliminary evaluation of the correlation time of local dynamics of the polymeric chains, using the experimental nuclear magnetic resonance spin-lattice relaxation data, is proposed. The algorithm is based on the model of the passage of a particle over a potential energy barrier. This method was utilized for some molten polymers and concentrated polymeric solutions.     

Effect of boundary layer losses on 2D detonation cellular structures

We evaluate the effect of boundary layer losses on two-dimensional H2/O2/Ar cellular detonations obtained in narrow channels. The experiments provide the details of the cellular structure and the detonation speed deficits from the ideal CJ speed. We model the effect of the boundary layer losses by incorporating the flow divergence in the third dimension due to the negative boundary layer displacement thickness, modeled using Mirels’ theory. The cellular structures obtained numerically with the resulting quasi-2D formulation of the reactive Euler equations with two-step chain-branching chemistry are found in excellent agreement with experiment, both in terms of cell dynamics and velocity deficits, provided the boundary layer constant of Mirels is modified by a factor of 2. A significant increase in the cell size is found with increasing velocity deficit. This is found to be very well captured by the induction zone increase in slower detonations due to the lower temperatures in the induction zone.     

Characterization of Magnetic Nanoiron Oxides for the Removal of Metal Ions from Aqueous Solution

ABSTRACT

Two nanostructured hybrid materials are reported that include uncoated magnetic nanoiron oxides and magnetic nanoiron oxides treated with rose leaf extract. Atomic and molecular absorption spectrometry were used to evaluate the sensitivity of these materials for the isolation of Cr(VI), Zn(II), Pb(II), and Ca(II) from aqueous solution. The structure and physicochemical properties of the resulting nanohybrids were characterized by scanning electron microscopy coupled with energy-dispersive spectroscopy, atomic force microscopy, and X-ray diffraction. The results show that following 15?min of contact in acidic solution, the uncoated magnetic nanoiron oxides removed approximately 90% of Cr(VI), while the magnetic nanoiron oxides coated with rose leaf extract removed 92% of the analyte. These correspond to most industrial wastewater conditions. For the removal of Ca(II) and Zn(II), it was necessary to adjust the pH to neutral to maximize the efficiency. Pb(II) showed maximum removal efficiency when the solution is basic. The simple rose extract suspension was also used for metal removal with high capacity. The results demonstrate that the magnetic nanoiron oxides were uniformly distributed in the rose leaf extract. The extract served as a capping agent due to the presence of polyphenolics.