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1.
We introduce a quantum key distribution protocol using mean multi-kings’ problem. Using this protocol, a sender can share a bit sequence as a secret key with receivers. We consider a relation between information gain by an eavesdropper and disturbance contained in legitimate users’ information. In BB84 protocol, such relation is known as the so-called information disturbance theorem. We focus on a setting that the sender and two receivers try to share bit sequences and the eavesdropper tries to extract information by interacting legitimate users’ systems and an ancilla system. We derive trade-off inequalities between distinguishability of quantum states corresponding to the bit sequence for the eavesdropper and error probability of the bit sequence shared with the legitimate users. Our inequalities show that eavesdropper’s extracting information regarding the secret keys inevitably induces disturbing the states and increasing the error probability.  相似文献   
2.
The cyclization reaction of diarylethenes having an azulene ring occurs only via higher excited states. Novel diarylethenes having an azulene ring with a strong donor or acceptor were synthesized and examined in these reactions. A derivative having an electron-donating 1,3-benzodithiol-2-ylidenemethyl group at the 1-position of the azulene ring showed photochromism, whereas neither a derivative having a π-conjugated electron-donating group at the 3-position of the azulene ring nor derivatives having a π-conjugated electron-withdrawing group at the 1- or 3-position of the azulene ring showed any photochromism. The photoreactivities of these compounds were explained by calculating forces and bond orders on the excited states using density functional theory (DFT) and time-dependent (TD)-DFT.  相似文献   
3.
This paper is concerned with the oscillatory behavior of the damped half-linear oscillator (a(t)?p(x′))′ + b(t)?p(x′) + c(t)?p(x) = 0, where ?p(x) = |x|p?1 sgn x for x ∈ ? and p > 1. A sufficient condition is established for oscillation of all nontrivial solutions of the damped half-linear oscillator under the integral averaging conditions. The main result can be given by using a generalized Young’s inequality and the Riccati type technique. Some examples are included to illustrate the result. Especially, an example which asserts that all nontrivial solutions are oscillatory if and only if p ≠ 2 is presented.  相似文献   
4.
The introduction of a five-membered ring α,α-disubstituted α-amino acid into l-Leu-based heptapeptides preferentially induced right-handed (P) helical structures. Using 5 ~ 20 mol% of a single helical foldamers-catalyst, enantioselective 1,4-addition reactions of dialkyl malonates to cycloalk-2-enones (5 ~ 7 rings) proceeded to give chiral 3-substituted cycloalkanones with 94 ~ 99% ee in moderate chemical yields, regardless of the ring size of substrates.  相似文献   
5.
6.
The isolated polystyrene chains spin-labeled with peroxide radical at the free end (IPSOO) in which the chain roots were covalently bonded to the surface of microcrystalline cellulose (MCC) powder were produced by mechanochemical polymerization of styrene initiated by MCC mechanoradicals. The IPSOO was used as motional probes at the ends of isolated polystyrene chains tethered on the surface of MCC powder. Two modes for the molecular motion of IPSOO were observed. One was a tumbling motion of IPSOO on the MCC surface, defined as a train state, and another was a free rotational motion of IPSOO protruding out from the MCC surface, defined as a tail state. The temperature of tumbling motion (T tum ) of IPSOO at the train state was at 90 K with anisotropic correlation times. T tum (90 K) is extremely low compared to the glass transition temperature (T g b ; 373 K) of polystyrene in the bulk. At temperatures above 219 K, the IPSOO was protruded out from the MCC surface, and freely rotated at the tail state. The train–tail transition temperature (T traintail ) was estimated to be 222 K. T tum (90 K) and T traintail (222 K) are due to the extremely low chain segmental density of IPSOO on the MCC surface under vacuum. The interaction between IPSOO and the MCC surface is a minor contributing factor in the mobility of IPSOO on the surface under vacuum. It was found that peroxy radicals are useful probes to characterize the chain mobility reflecting their environmental conditions.  相似文献   
7.
A comprehensive method for the construction of a high‐mannose‐type glycan library by systematic chemo‐enzymatic trimming of a single Man9‐based precursor was developed. It consists of the chemical synthesis of a non‐natural tridecasaccharide precursor, the orthogonal demasking of the non‐reducing ends, and trimming by glycosidases, which enabled a comprehensive synthesis of high‐mannose‐type glycans in their mono‐ or non‐glucosylated forms. It employed glucose, isopropylidene, and N‐acetylglucosamine groups for blocking the A‐, B‐, and C‐arms, respectively. After systematic trimming of the precursor, thirty‐seven high‐mannose‐type glycans were obtained. The power of the methodology was demonstrated by the enzymatic activity of human recombinant N‐acetylglucosaminyltransferase‐I toward M7–M3 glycans, clarifying the substrate specificity in the context of high‐mannose‐type glycans.  相似文献   
8.
The cathepsin B inhibitor surugamide B ( 2 ), along with structurally related derivatives (A and C–E), has previously been isolated from the marine actinomycete Streptomyces sp. JAMM992. The biosynthetic genes are unexpectedly part of a cluster of four non‐ribosomal peptide synthetase (NRPS) genes, two of which are responsible for the biosynthesis of the additional linear decapeptide surugamide F. However, the thioesterase domain required for the later stage of the biosynthesis of the cyclic peptides surugamides A–E is not present in any module architecture of the surugamide NRPSs. Herein, we report the first total synthesis of surugamide B ( 2 ) through the macrocyclization at the biomimetic position, which not only alleviated the Cα epimerization in the macrolactamization process, but also efficiently provided 2 in 34 % yield for 18 steps. Furthermore, both the chemical and enzymatic studies with the biosynthetic precursor mimics revealed that the stand‐alone enzyme SurE, which belongs to the penicillin‐binding protein family, is responsible for macrocyclization of the tethered octapeptidyl intermediate.  相似文献   
9.
Visible light-responsive TiO2 (Vis-TiO2) thin films able to absorb UV and visible light in wavelength regions of 250–600 nm were successfully developed by applying a radio-frequency magnetron sputtering deposition method. These Vis-TiO2 thin films exhibited high activity for the photocatalytic oxidation of 2-propanol diluted in water even under visible light irradiation (λ ≥ 450 nm). The photocatalytic activity of Vis-TiO2 thin films was dramatically enhanced by the deposition of Pt particles on the surface. Secondary ion mass spectrometry measurements revealed that Pt particles are distributed from the top surface to the deep bulk of Vis-TiO2 thin films with a columnar structure. The unique columnar structure of Vis-TiO2 thin films plays an important role in the high photocatalytic performance.  相似文献   
10.
Chiral cyclic α,α‐disubstituted amino acids, (3S,4S)‐ and (3R,4R)‐1‐amino‐3,4‐(dialkoxy)cyclopentanecarboxylic acids ((S,S)‐ and (R,R)‐Ac5cdOR; R: methyl, methoxymethyl), were synthesized from dimethyl L ‐(+)‐ or D ‐(?)‐tartrate, and their homochiral homoligomers were prepared by solution‐phase methods. The preferred secondary structure of the (S,S)‐Ac5cdOMe hexapeptide was a left‐handed (M) 310 helix, whereas those of the (S,S)‐Ac5cdOMe octa‐ and decapeptides were left‐handed (M) α helices, both in solution and in the crystal state. The octa‐ and decapeptides can be well dissolved in pure water and are more α helical in water than in 2,2,2‐trifluoroethanol solution. The left‐handed (M) helices of the (S,S)‐Ac5cdOMe homochiral homopeptides were exclusively controlled by the side‐chain chiral centers, because the cyclic amino acid (S,S)‐Ac5cdOMe does not have an α‐carbon chiral center but has side‐chain γ‐carbon chiral centers.  相似文献   
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