全文获取类型
收费全文 | 8115篇 |
免费 | 1322篇 |
国内免费 | 1117篇 |
专业分类
化学 | 6187篇 |
晶体学 | 104篇 |
力学 | 452篇 |
综合类 | 75篇 |
数学 | 834篇 |
物理学 | 2902篇 |
出版年
2024年 | 9篇 |
2023年 | 190篇 |
2022年 | 233篇 |
2021年 | 300篇 |
2020年 | 440篇 |
2019年 | 434篇 |
2018年 | 309篇 |
2017年 | 332篇 |
2016年 | 372篇 |
2015年 | 402篇 |
2014年 | 476篇 |
2013年 | 645篇 |
2012年 | 714篇 |
2011年 | 789篇 |
2010年 | 555篇 |
2009年 | 477篇 |
2008年 | 578篇 |
2007年 | 453篇 |
2006年 | 414篇 |
2005年 | 344篇 |
2004年 | 263篇 |
2003年 | 225篇 |
2002年 | 248篇 |
2001年 | 180篇 |
2000年 | 158篇 |
1999年 | 128篇 |
1998年 | 95篇 |
1997年 | 95篇 |
1996年 | 95篇 |
1995年 | 100篇 |
1994年 | 89篇 |
1993年 | 75篇 |
1992年 | 51篇 |
1991年 | 46篇 |
1990年 | 42篇 |
1989年 | 49篇 |
1988年 | 28篇 |
1987年 | 16篇 |
1986年 | 20篇 |
1985年 | 29篇 |
1984年 | 15篇 |
1983年 | 13篇 |
1982年 | 8篇 |
1981年 | 8篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1959年 | 2篇 |
1957年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
2.
Hu Duo-Duo Gao Qian Dai Jing-Cheng Cui Ru Li Yuan-Bo Li Yuan-Ming Zhou Xiao-Guo Bian Kang-Jie Wu Bing-Bing Zhang Kai-Fan Wang Xi-Sheng Li Yan 《中国科学:化学(英文版)》2022,65(4):753-761
Science China Chemistry - A light-induced, nickel-catalyzed three-component arylsulfonation of 1,3-enynes in the absence of photocatalyst is reported. This methodology exhibited mild conditions,... 相似文献
3.
深度学习在检测领域高速发展,但受限于训练数据和计算效率,在基于嵌入式平台的边缘计算领域,尤其是实时跟踪应用中深度学习的智能化算法应用并不广泛。针对这一现象,同时为满足现阶段国产化、智能化的技术需求,提出了一种改进的孪生网络深度学习跟踪算法。在特征网络加入微调网络,解决了网络模型无法在线更新的问题,提升了跟踪的准确性;在IoUNet损失函数中加入中心距离惩罚项,解决了IoUNet当IoU相同时位置跳跃,存在收敛盲区和收敛速度慢的问题;将训练后的网络通过通道剪枝,缩减网络模型尺寸,提升了模型加载和运行的速度。在华为Atlas200NPU平台上实现了实时运行,算法准确率高达0.90(IoU>0.7),帧率达到66 Hz。 相似文献
4.
Heat dissipation is one of the most serious problems in modern integrated electronics with the continuously decreasing devices size. Large portion of the consumed power is inevitably dissipated in the form of waste heat which not only restricts the device energy-efficiency performance itself, but also leads to severe environment problems and energy crisis. Thermoelectric Seebeck effect is a green energy-recycling method, while thermoelectric Peltier effect can be employed for heat management by actively cooling overheated devices, where passive cooling by heat conduction is not sufficiently enough. However, the technological applications of thermoelectricity are limited so far by their very low conversion efficiencies and lack of deep understanding of thermoelectricity in microscopic levels. Probing and managing the thermoelectricity is therefore fundamentally important particularly in nanoscale. In this short review, we will first briefly introduce the microscopic techniques for studying nanoscale thermoelectricity, focusing mainly on scanning thermal microscopy (SThM). SThM is a powerful tool for mapping the lattice heat with nanometer spatial resolution and hence detecting the nanoscale thermal transport and dissipation processes. Then we will review recent experiments utilizing these techniques to investigate thermoelectricity in various nanomaterial systems including both (two-material) heterojunctions and (single-material) homojunctions with tailored Seebeck coefficients, and also spin Seebeck and Peltier effects in magnetic materials. Next, we will provide a perspective on the promising applications of our recently developed Scanning Noise Microscope (SNoiM) for directly probing the non-equilibrium transporting hot charges (instead of lattice heat) in thermoelectric devices. SNoiM together with SThM are expected to be able to provide more complete and comprehensive understanding to the microscopic mechanisms in thermoelectrics. Finally, we make a conclusion and outlook on the future development of microscopic studies in thermoelectrics. 相似文献
5.
6.
采用基于Compass力场的分子动力学(MD)方法,研究了惰性气体氙(Xe)和氪(Kr)在塑料闪烁体(聚乙烯基对甲苯)的平整和粗糙表面的吸附和扩散行为.由惰性气体吸附曲线的均方根位移(MSD),得到了Xe/Kr气体在聚乙烯基对甲苯表面的扩散系数.研究结果表明,Kr/Xe气体均被稳定地吸附在塑料闪烁体表面,其稳定性随着温度的升高而增加,Xe分子的吸附性强于Kr分子. Kr/Xe气体在聚乙烯基对甲苯表面具有较强的扩散性能,扩散深度随着温度与厚度的增加而增加,最大为22.865?,Kr分子扩散能力强于Xe分子.基底粗糙表面增加了两种惰性气体分子的吸附和扩散. 相似文献
7.
Fabricating n-type organic thin film transistors(OTFTs)based on small molecules via solution processing under atmospheric conditions remains challenging.Blending small molecules with polymer is an effective strategy to improve the solution processibility and air stability of the resulted devices.In this study,polystyrene was chosen to blend with n-type small molecule DPP1012-4F to enhance the continuity of the semiconductor layer and maintain a favorable edge-on stacking of semiconductors.The introduction of high-boiling point 1-chloronaphthalene as a solvent additive in the blending system can reduce the grain boundary defects in the microscopic morphology.These changes in aggregation behavior are confirmed by X-ray diffraction,atomic force microscopy and polarized optical microscopy analyses.Via bar-coating of the semiconductor layers in air,the electron mobility of the resulted OTFTs under the optimal condition is 0.73 cm2·V–1·s–1,which is amongst the highest n-type small molecule-based OTFTs with active layers prepared in air up to now.These results show a great potential of the blending strategy in industrial roll-to-roll manufacture of high-mobility n-type OTFTs. 相似文献
8.
分析方法标准验证实验得到的分析方法基本性能参数重复性限和再现性限是日常检测工作质控规范重要依据。以环境监测领域土壤、沉积物及固废样品中无机元素分析为例,考察了已颁布执行的标准文本和在生态环境部官网公开征求意见的分析方法标准中重复性限。将重复性限转化为相对偏差后,与日常检测工作中质控限值进行了比较。根据目前现行有效的平行双样测定结果相对偏差限值,方法验证数据有多大比例符合质控要求?根据方法验证结果,平行双样测定结果相对偏差限值有无改进可能?从上述两个角度进行了研究。研究结果表明:土壤、沉积物、固体废弃物中无机元素的测定,不同文献来源相同分析方法标准和不同分析方法标准,其重复性限转化得到的平行测定相对偏差合格率存在明显区别;用平行测定相对偏差限值可以快速判断标准文本中的重复性限是否合理,审核方法验证数据质量是否满足要求。基于已有标准文本方法验证数据,探讨了修改平行测定结果相对偏差限值可行性。 相似文献
9.
In this paper, we study homogeneous Einstein-like metrics on the compact irreducible symmetric space M, which is not isometric to a compact Lie group and has rank greater than 1. Whenever there exists a closed proper subgroup G′ of G = Isom_0(M) acting transitively on M, we find all the G′-invariant A-metrics and B-metrics on M. More precisely, we prove that G′-invariant metrics on M must be A-metrics, and G′-invariant B-metrics on M are always Einstein. 相似文献
10.
Annals of Operations Research - The main purpose of this study was to explore the impact of peace dividends on global changes in national productivity. First, this study assessed changes in... 相似文献