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1.
Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface. 相似文献
2.
Peng Zhao Juping Yang Yuming Shang Li Wang Mou Fang Jianlong Wang Xiangming He 《天然气化学杂志》2015,(2):138-144
Surface chemical modification of polyolefin separators for lithium ion batteries is attempted to reduce the thermal shrinkage, which is important for the battery energy density. In this study, we grafted organic/inorganic hybrid crosslinked networks on the separators, simply by grafting polymerization and condensation reaction. The considerable silicon-oxygen crosslinked heat-resistance networks are responsible for the reduced thermal shrinkage. The strong chemical bonds between networks and separators promise enough mechanical support even at high temperature. The shrinkage at 150 C for 30 min in the mechanical direction was 38.6% and 4.6% for the pristine and present graft-modified separators, respectively. Meanwhile, the grafting organic-inorganic hybrid crosslink networks mainly occupied part of void in the internal pores of the separators, so the thicknesses of the graft-modified separators were similar with the pristine one. The half cells prepared with the modified separators exhibited almost identical electrochemical properties to those with the commercial separators, thus proving that, in order to enhance the thermal stability of lithium ion battery, this kind of grafting-modified separators may be a better alternative to conventional silica nanoparticle layers-coated polyolefin separators. 相似文献
3.
Zhen Xi 《中国科学:化学(英文版)》2015,(3):434-435
Redox-based post-translational modification of protein thiols has become an attractive strategy in cellular homeostasis and cell signaling.Due to the reductive end of the redox buffer network,the vicinal dithiol-containing proteins(VDPs)maintains an appropriate oxidation-reduction state of proteins through the reversible transformation from vicinal dithiols to disulfide,which is responsible for a variety of 相似文献
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微机械陀螺的发展现状 总被引:24,自引:0,他引:24
随着对微电子机械系统(MEMS)的深入研究和取得的进展,属于MEMS研究内容之一的微机械陀螺,在汽车工业需求的推动下,已经成为过去几十年内广泛研究和发展的主题.微机械陀螺与传统机械式陀螺、固体陀螺、光学陀螺等相比,具有成本低、尺寸小、重量轻、可靠性高等优点,其精度正不断得到提高,应用领域也随之不断扩大.本文首先简要介绍了微机械陀螺的定义及特征、性能指标、工作原理、分类以及加工技术,随后对已出现的不同类型微机械陀螺的结构、加工方式、工作原理以及性能进行了综述,最后对微机械陀螺的商业化现状以及发展趋势进行了展望. 相似文献
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吴伟雄 《应用数学和力学(英文版)》1994,(8)
FINITEELEMENTANALYSISFORTHEUNSTEADYNEARSHORECIRCULATIONDUETOWAVE-CURRENTINTER-ACTION(I)——NUMERICALMODELWuWei-xiong(吴伟雄)(Tongj... 相似文献
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YuchengWu YongZhang LideZhang 《中国颗粒学报》2004,2(1):19-24
Nanosized palladium particles were incorporated into mesoporous silica matrix to obtain nanocomposites using the sol-gel technique. Effects of the finely dispersed metallic palladium on the microstructure and properties of the nanocomposites were investigated. By means of X-ray diffraction and optical absorption, it was found that palladium particles were 5-9 nm in diameter and their uniform dispersion in the mesoporous silica depended on both the content of the palladium and the structural features of the silica matrix. The results showed that the mixing method of preparation led to wider size distribution of the nanosized particles as compared to the immersion method, but dispersed degree was reduced. Although the incorporation of nanosized palladium particles could not substantially induce significant structural changes of the matrix, the apparent red-shifted optical absorptions for the nanocomposites were observed as compared to the parent monolithic silica, particularly with increase in palladium loading and calcination temperature. 相似文献
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