Consolidation of composite cathodes with NCM and sulfide solid-state electrolytes by hot pressing for all-solid-state Li metal batteries

Journal of Solid State Electrochemistry - In this study, hot pressing was evaluated as a method of cell fabrication to increase the energy density of next-generation all-solid-state batteries with...     

Phosphine‐Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds

The lability of B=B, B?P, and B–halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes undergo cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.     

Phytochemical investigation on Myristica fragrans stem bark

Myristica fragrans Houtt., the source of very important spice ‘nutmeg’ used world over is native to India, Indonesia, Sri Lanka, South Africa and Southeast Asia. Phytochemical investigation of M. fragrans stem bark led to the isolation of bis-aryl dimethyl tetrahydrofuran lignans, such as grandisin [(7S,8S,7′S,8′S)-3,3′,4,4′,5,5′-hexamethoxy-7,7′,8,8′-lignan] and (7S,8S,7′R,8′R)-3,3′,4,4′,5,5′-hexamethoxy-7,7′,8,8′-lignan along with important lignans and neolignans, licarinA, licarin B, odoratisol A, (2S, 3R)-7-methoxy-3-methyl-5-((E)-prop-1-enyl)-2-(5-methoxy,3,4-methylenedioxyphenyl)-2,3-dihydrobenzofuran, elemicin, fragransin B₁, raphidecursinol B, erythro-(7S,8R)-Δ^8′-4,7-dihydroxy-3,5,3′-trimethoxy-8-O-4′-neolignan, erythro-(7S,8R)-Δ⁸′-7-hydroxy-3,4,3′,5′-tetramethoxy-8-O-4′-neolignan, surinamensin.and β-sitosterol. Structures of the 12 compounds isolated were unambiguously identified by various spectroscopic methods. The former two compounds were isolated from M. fragrans for the first time. Furthermore, the X-ray crystal structure of odoratisol A is reported in this paper for the first time.     

High Blocking Temperature of Magnetization and Giant Coercivity in the Azafullerene Tb2@C79N with a Single‐Electron Terbium–Terbium Bond

The azafullerene Tb₂@C₇₉N is found to be a single‐molecule magnet with a high 100‐s blocking temperature of magnetization of 24 K and large coercivity. Tb magnetic moments with an easy‐axis single‐ion magnetic anisotropy are strongly coupled by the unpaired spin of the single‐electron Tb?Tb bond. Relaxation of magnetization in Tb₂@C₇₉N below 15 K proceeds via quantum tunneling of magnetization with the characteristic time τ_QTM=16 462±1230 s. At higher temperature, relaxation follows the Orbach mechanism with a barrier of 757±4 K, corresponding to the excited states, in which one of the Tb spins is flipped.     

Tunable Orthogonal Reversible Covalent (TORC) Bonds: Dynamic Chemical Control over Molecular Assembly

Dynamic assembly of macromolecules in biological systems is one of the fundamental processes that facilitates life. Although such assembly most commonly uses noncovalent interactions, a set of dynamic reactions involving reversible covalent bonding is actively being exploited for the design of functional materials, bottom‐up assembly, and molecular machines. This Minireview highlights recent implementations and advancements in the area of tunable orthogonal reversible covalent (TORC) bonds for these purposes, and provides an outlook for their expansion, including the development of synthetically encoded polynucleotide mimics.     

Congruences for overpartitions with restricted odd differences

The Ramanujan Journal - In a recent work, Bringmann, Dousse, Lovejoy, and Mahlburg defined the function $$\overline{t}(n)$$ to be the number of overpartitions of weight n where (i) the difference...     

Sandwich semigroups in locally small categories I: foundations

Fix (not necessarily distinct) objects i and j of a locally small category S, and write \(S_{ij}\) for the set of all morphisms \(i\rightarrow j\). Fix a morphism \(a\in S_{ji}\), and define an operation \(\star _a\) on \(S_{ij}\) by \(x\star _ay=xay\) for all \(x,y\in S_{ij}\). Then \((S_{ij},\star _a)\) is a semigroup, known as a sandwich semigroup, and denoted by \(S_{ij}^a\). This article develops a general theory of sandwich semigroups in locally small categories. We begin with structural issues such as regularity, Green’s relations and stability, focusing on the relationships between these properties on \(S_{ij}^a\) and the whole category S. We then identify a natural condition on a, called sandwich regularity, under which the set \({\text {Reg}}(S_{ij}^a)\) of all regular elements of \(S_{ij}^a\) is a subsemigroup of \(S_{ij}^a\). Under this condition, we carefully analyse the structure of the semigroup \({\text {Reg}}(S_{ij}^a)\), relating it via pullback products to certain regular subsemigroups of \(S_{ii}\) and \(S_{jj}\), and to a certain regular sandwich monoid defined on a subset of \(S_{ji}\); among other things, this allows us to also describe the idempotent-generated subsemigroup \(\mathbb E(S_{ij}^a)\) of \(S_{ij}^a\). We also study combinatorial invariants such as the rank (minimal size of a generating set) of the semigroups \(S_{ij}^a\), \({\text {Reg}}(S_{ij}^a)\) and \(\mathbb E(S_{ij}^a)\); we give lower bounds for these ranks, and in the case of \({\text {Reg}}(S_{ij}^a)\) and \(\mathbb E(S_{ij}^a)\) show that the bounds are sharp under a certain condition we call MI-domination. Applications to concrete categories of transformations and partial transformations are given in Part II.     

Reverse Thinking of the Aggregation-Induced Emission Principle: Amplifying Molecular Motions to Boost Photothermal Efficiency of Nanofibers**

Using reverse thinking of the aggregation-induced emission (AIE) principle, we demonstrate an ingenious and universal protocol for amplifying molecular motions to boost photothermal efficiency of fibers. Core–shell nanofibers having the olive oil solution of AIE-active molecules as the core surrounded by PVDF-HFP shell were constructed by coaxial electrospinning. The molecularly dissolved state of AIE-active molecules allows them to freely rotate and/or vibrate in nanofibers upon photoexcitation and thus significantly elevates the proportion of non-radiative energy dissipation, affording impressive heat-generating efficiency. Photothermal evaluation shows that the core–shell nanofibers with excellent durability can reach up to 22.36 % of photothermal conversion efficiency, which is 26-fold as the non-core–shell counterpart. Such a core–shell fiber can be used for photothermal textiles and solar steam generation induced by natural sunlight with green and carbon-zero emission.     

Noise-induced chaotic-attractor escape route

Nonlinear Dynamics - In the present article, a combination of numerical and experimental studies is undertaken to comprehend the influence of noise on the responses of continuous-time dynamical...