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排序方式: 共有199条查询结果,搜索用时 218 毫秒
1.
The context of molecular structronics (from “molecular structure” and “electronics”) is that of molecular-level electrochemical storage of energy of sustainable origin (wind, solar). Due to its discontinuous availability, storage of this energy is a key issue. The targeted type of storage relies on implementing “electron reservoirs” within the structronic molecules by electrochemically forming dedicated chemical bonds according to non-catalytic processes. Reservoir bonds are therefore integral parts of the molecular backbone of structronic assemblies. When filled, electron reservoirs manifest themselves in the form of elongated covalent bonds that are to be cleaved for electron releasing (discharging) on demand. The scope of this short review is limited to pyridinium electrophores as particularly suited building blocks for the development of structronics. 相似文献
2.
Oscillatory rheological experiments at different temperatures and over a wide range of frequencies have been used to investigate
the gelation process and, more particularly, the sol–gel transition of various poly(vinyl chloride) (PVC) plastisols. The
sol–gel transition process was found to be universal with respect to the temperature and solid volume fraction according to
the similarity of the fractal structure in PVC plastisols. The variation of the gel time (t
gel) with temperature for any composition of PVC plastisols was predicted from the Dickinson’s model (E. Dickinson, J Chem Soc
Faraday Trans, 93:111–114, 1997). Dynamic viscoelastic properties of PVC plastisols have also been studied as a function of
temperature that allowed us to follow the gelation process of various plastisols. Thus, the influence of the type and concentration
of PVC resins in gelation process was investigated. The variation of the complex shear modulus at a constant frequency was
depicted by a master curve regarding the dependence of the moduli on PVC concentrations. 相似文献
3.
C. Chevennement-Roux T. Dreher P. Alliot E. Aubry J.-P. Lainé L. Jézéquel 《Experimental Mechanics》2007,47(2):201-210
The optimization of wiper systems under various conditions and the creation of a product which is as robust as possible are
the main objectives for an equipment supplier. However, in certain conditions, instabilities can appear and generate wiping
defects due to the rubber-glass contact. To improve wiping quality and to reduce the number of test stages for design, this
study proposes a wiper system modeling method. The wiper system is represented by a rigid blade holder on which a rubber blade
is fitted. This rigid blade system is used on a flat test bench at constant wiping velocity. The model is based on modal synthesis
methods and will be validated through comparison with experimental tests under various conditions. The right correlation obtained
allows the same modelling method to be applied to the new generation of flexible wiper blades which take account of the degree
of freedom of the wiper blade flexions. So, a new computation tool will be developed and validated through experimentation
on a specific test bench. 相似文献
4.
Ilkka Ojanperä Samuel Mesihää Ilpo Rasanen Anna Pelander Raimo A. Ketola 《Analytical and bioanalytical chemistry》2016,408(13):3395-3400
5.
Luigi Lain Prof. Dr. Harri Lönnberg Dr. Tuomas Lönnberg 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(37):12424-12434
A dinucleoside‐3′,5′‐phosphodiester model, 5′‐amino‐4′‐aminomethyl‐5′‐deoxyuridylyl‐3′,5′‐thymidine, incorporating two aminomethyl functions in the 4′‐position of the 3′‐linked nucleoside has been prepared and its hydrolytic reactions studied over a wide pH range. The amino functions were found to accelerate the cleavage and isomerization of the phosphodiester linkage in both protonated and neutral form. When present in protonated form, the cleavage of the 3′,5′‐phosphodiester linkage and its isomerization to a 2′,5′‐linkage are pH‐independent and 50–80 times as fast as the corresponding reactions of uridylyl‐3′,5′‐uridine (3′,5′‐UpU). The cleavage of the resulting 2′,5′‐isomer is also accelerated, albeit less than with the 3′,5′‐isomer, whereas isomerization back to the 3′,5′‐diester is not enhanced. When the amino groups are deprotonated, the cleavage reactions of both isomers are again pH‐independent and up to 1000‐fold faster than the pH‐independent cleavage of UpU. Interestingly, the 2′‐ to 3′‐isomerization is now much faster than its reverse reaction. The mechanisms of these reactions are discussed. The rate accelerations are largely accounted for by electrostatic and hydrogen‐bonding interactions of the protonated amino groups with the phosphorane intermediate. 相似文献
6.
7.
J. Huub Adriaanse Sven H.C. Askes Yorrick van Bree Stefan van Oudheusden Eelke D. van den Bos Esref Günay Ilpo Mutikainen Urho Turpeinen Gerard A. van Albada Jaap G. Haasnoot Jan Reedijk 《Polyhedron》2009,28(14):3143-3149
A variety of new coordination compounds with transition-metal salts and the ligand trimethyl[1,2,4]triazolo[1,5-a]pyrimidine (abbreviated as tmtp) is described, together with several of their 3D crystal structures and spectroscopic and magnetic properties. The compounds were selected based on the coordination ability of the counterion, halide, nitrate, sulfate, thiocyanate and perchlorate. The formed coordination compounds and their coordination numbers were found to be strongly dependent on both the cation and the used counter-anion. The several compounds studied have the following structural formulae: [CuCl2(tmtp)2], [CuBr2(tmtp)2], [ZnBr2(tmtp)2], [Cu(NO3)2(tmtp)2], [CuSO4(tmtp)2]2(H2O)(MeOH), [Cu(H2O)(NCS)2(tmtp)2], [Zn(NCS)2(tmtp)2], [Cd(NCS)2(tmtp)2] and [M(H2O)2(tmtp)4](BF4)2, in which M = Co, Ni, Zn.The new coordination compounds have been further characterized by NMR, (far-)IR and LF spectra, as well as by C, H, N element analyses, and EPR spectra for the Cu(II) compounds. The coordination around the metal varies from 4 (Zn, Cu), via 5 (Cu) to 6 (for Co, Cu and Cd). The anions usually complete the coordination sphere; only the Co and Zn compounds with the tetrafluoridoborate anions have no coordinated anions, but water ligands complete the octahedral coordination sphere. In the 5-coordinated [Cu(H2O)(NCS)2(tmtp)2] water completes the square pyramid geometry. 相似文献
8.
9.
Gerard A. van Albada Maarten G. van der Horst Ilpo Mutikainen Urho Turpeinen Jan Reedijk 《Journal of chemical crystallography》2009,39(5):358-363
Abstract The synthesis and full structural characterisation is described of 3 dinuclear-based Cu(II) compounds bridged by methoxide
anions, and flexible linear bis(pyrimidine)-α,ω-diaminoalkane ligands. The structures are dinuclear based in all cases, in
which the bis(pyrimidine)diaminoalkane ligand chelates to 2 Cu(II) ions in the same dinuclear unit (N–C–C–C–C–C–N linker),
or to two different dinuclear units (with the short N–C–C–N linker), thereby generating a polymeric chain. The magnetic exchange
in the compounds is dominated by the alkoxido-bridged ligands, which generate a very strong antiferromagnetic coupling between
the Cu(II) ions, resulting in diamagnetism at room temperature and below, and EPR silent behaviour.
Index Abstract Dinuclear-based Cu(II) compounds with pyrimidine-based chelating ligands flexible linear bis(pyrimidine)-α,ω-diaminoalkane
ligands are described, bridged by methoxide anions. The structures are dinuclear based in all cases, with the ligand chelating
to 2 Cu(II) ions in the same dinuclear unit (N–C–C–C–C–C–N linker), or to 2 different dinuclear units (with short N–C–C–N
linkers). The very strong antiferromagnetic magnetic exchange in all compounds is caused by the alkoxido-bridged ligands.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
10.
Gerard A. van Albada Ilpo Mutikainen Urho Turpeinen Jan Reedijk 《Journal of chemical crystallography》2001,31(2):75-79
The first high-spin iron(III) compound with the ligand 2,2-bipyridine-1,1-dioxide (abbreviated as bpdo) is reported. The compound [Fe(bpdo)3](ClO4)3(CH3CN)2 crystallizes in the space group P
, with a = 11.767(3), b = 13.166(4), c = 15.951(4) Å, = 104.62(3), = 101.66(3), = 112.14(3)°, and Z = 2. The Fe(III) atom is octahedrally surrounded by six oxygen atoms of three bpdo ligands. In the far-infrared region the Fe—O vibration is observed at 411 cm–1. The magnetic susceptibility reveals a of 6.04 ± 0.04 BM in the 10–280 K region, typical of high-spin Fe(III). 相似文献