全文获取类型
收费全文 | 5713篇 |
免费 | 234篇 |
国内免费 | 57篇 |
专业分类
化学 | 4018篇 |
晶体学 | 47篇 |
力学 | 263篇 |
综合类 | 2篇 |
数学 | 619篇 |
物理学 | 1055篇 |
出版年
2023年 | 48篇 |
2022年 | 73篇 |
2021年 | 190篇 |
2020年 | 188篇 |
2019年 | 187篇 |
2018年 | 195篇 |
2017年 | 165篇 |
2016年 | 261篇 |
2015年 | 204篇 |
2014年 | 251篇 |
2013年 | 581篇 |
2012年 | 394篇 |
2011年 | 412篇 |
2010年 | 284篇 |
2009年 | 230篇 |
2008年 | 271篇 |
2007年 | 241篇 |
2006年 | 200篇 |
2005年 | 138篇 |
2004年 | 145篇 |
2003年 | 136篇 |
2002年 | 106篇 |
2001年 | 65篇 |
2000年 | 81篇 |
1999年 | 38篇 |
1998年 | 45篇 |
1997年 | 31篇 |
1996年 | 47篇 |
1995年 | 36篇 |
1994年 | 40篇 |
1993年 | 33篇 |
1992年 | 36篇 |
1991年 | 41篇 |
1990年 | 33篇 |
1989年 | 40篇 |
1988年 | 36篇 |
1987年 | 33篇 |
1986年 | 21篇 |
1985年 | 50篇 |
1984年 | 39篇 |
1983年 | 30篇 |
1982年 | 41篇 |
1981年 | 32篇 |
1980年 | 37篇 |
1979年 | 22篇 |
1978年 | 23篇 |
1977年 | 21篇 |
1975年 | 20篇 |
1974年 | 20篇 |
1973年 | 19篇 |
排序方式: 共有6004条查询结果,搜索用时 15 毫秒
1.
Ibrahim Musa Guy Raffin Marie Hangouet Marie Martin Albert Alcacer Nadia Zine Francesca Bellagambi Nicole Jaffrezic-Renault Abdelhamid Errachid 《Electroanalysis》2022,34(8):1338-1347
Thin-film composite of chitosan/nickel phthalocyanine (NiPc) was electrochemically deposited on the fingers of interdigitated gold electrodes, applying chronoamperometric polymerization technique. The presence of crystallized NiPc in the chitosan was confirmed by EDX and FTIR analysis. Acetone, ethanol, and methanol gas-sensing properties of the films prepared at optimum conditions were studied at atmospheric temperature, through differential measurements at an optimized frequency of 10 kHz, using a lock-in amplifier. The conductometric sensor presents the highest sensitivity of 60.2 μS.cm−1(v/v) for methanol and 700 ppm as the limit of detection. For validation, the methanol content of a commercial rubbing alcohol was determined. 相似文献
2.
Nonlinear Dynamics - This paper proposes a fractional-order reset element whose architecture allows for the suppression of nonlinear effects for a range of frequencies. Suppressing the nonlinear... 相似文献
3.
Umie F.M. Haziz Rosenani A. Haque Shun-Ze Zhan Hassan H. Abdallah Mohd R. Razali 《应用有机金属化学》2020,34(10):e5818
The synthesis and characterizations for a series of dinuclear gold (I)-di-NHC complexes, 1–8 through the trans-metalation method of their respective silver (I)-di-NHC complexes, i–viii are reported (where NHC = N-heterocyclic carbene). The successful complexation of a series of unusual non-symmetrical and symmetrical di-NHC ligands, 3,3'-(ethane-1,2-diyl)-1-alkylbenzimidazolium-1'-butylbenzimidazolium (with alkyl = methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, benzyl) with the gold (I) ions are suggested by elemental analysis, Fourier transform-infrared, 1H- and 13C-NMR data. The 13C-NMR spectra of 1–8 show a singlet sharp peak in the range of 190.00–192.00 ppm, indicating the presence of a carbene carbon that bonded to the gold (I) ion. From single crystal X-ray diffraction data, the structure of complex 6 with the formula of [di-NHC-Au (I)]2·2PF6 is obtained [where NHC = 3,3'-(ethane-1,2-diyl)-1-hexylbenzimidazolium-1'-butylbenzimidazolium]. The photophysical study in solid state of 6 displays an intense photoluminescence with a strong emission maxima, λem = 480 nm, upon excitation at 340 nm at room temperature. Interestingly, the emission maximum at 77 K shows a structural character with a strong peak at 410 nm, a medium at 433 nm and a weak at 387 nm, accompanied by a tail band to about 500 nm. 相似文献
4.
5.
Hassan E. A. M. Elabid A. E. A. Bashier E. O. Elagib T. H. H. 《Mechanics of Composite Materials》2022,58(2):261-270
Mechanics of Composite Materials - Carbon fiber (CF)/ polyamide (PA6) composites are one of the most promising thermoplastic materials for automobile applications. However, the interfacial... 相似文献
6.
JPC – Journal of Planar Chromatography – Modern TLC - The merits of chemometrics in categorizing different Egyptian olive chemovarieties based on their compositional integrity were... 相似文献
7.
Mohammad El-khateeb Hassan Abul-Futouh Hadil Alshurafa Helmar Görls Wolfgang Weigand 《应用有机金属化学》2020,34(11):e5940
Substitution of carbonyl ligands of the hydrogenase model complex [Fe2(μ-SeCH2CH(Me)CH2Se-μ)(CO)6] ( A ), by 1,1′-bis (diphenylphosphino)ferrocene (dppf), 1,2-bis (diphenylphosphino)benzene (dppbz) or 1,2-bis (diphenylphosphino)acetylene (dppac) is investigated. It is found that the reaction product depends on the diphosphine used. In the case of dppf, the product is an intramolecular bridged disubstituted complex [Fe2{μ-SeCH2CH(Me)CH2Se-μ}(CO)4{μ,κ1,κ1(P,P)-dppf}] ( 1 ), while the dppac-reaction produces an intermolecular bridged tetra-iron model [Fe2{μ-SeCH2CH(Me)CH2Se-μ}(CO)5]2{μ,κ1,κ1(P,P)-dppac} ( 2 ). However, the dppbz-reaction gives [Fe2{μ-SeCH2CH(Me)CH2Se-μ}(CO)4{κ2(P,P)-dppbz}] ( 3 ) in which the dppbz ligand is bonded to one Fe atom in a chelated manner. The newly prepared complexes ( 1 – 3 ) have been characterized by elemental analysis, IR, 1H-, 13C{H}-, 31P{H}-, 77Se{H}-NMR spectroscopy and X-ray structure determination. The electrochemical behavior of 2 and 3 , in absence and presence of acid, is described by cyclic voltammetric measurements in CH2Cl2. 相似文献
8.
Ali El-Dissouky Eslam S. Abu-Elsoud Afaf Abdel Razik Mohamed K. Awad Hammed H.A.M. Hassan Amel F. Elhusseiny 《应用有机金属化学》2020,34(11):e5953
A series of nanometer-sized spherical sulfonamide imine ligands HL 1 -HL 5 and their copper and zinc complexes were synthesized and fully characterized based on elemental analyses, spectroscopic (UV/vis, FT-IR, NMR, EPR, SEM) studies, molar conductance and thermal analyses. Furthermore, computational studies of HL 1 -HL 5 were carried out by the DFT/B3LYP method. TD-DFT, HOMO and LUMO energy values, chemical hardness, electronegativity, electrophilic index, softness, and other parameters were calculated. Screening against several pathogenic microorganisms indicated that HL 1 exhibited high activity against the tested Gram-negative bacteria relative to other analogues and the inhibition activity is greater than the standard Gentamicin. Analogously, HL 2 exhibited high potent activity against the tested Gram-positive bacteria. Copper complexes exhibited a higher potent activity than zinc analogues. Noteworthy, inhibition activity of [Cu ( L 3 )(OAc)] complex is higher than that of the standard Ampicillin. [Cu ( L 2 )(OAc)] complex displayed a similar activity of the standard bactericides and fungicides in use. The complexes showed appreciated values of MIC against bacterial strains: B. subtilis (MIC = 0.4 μg / mL), E. coli and S. pneumonia (MIC = 1.95 μg / mL) and P. aeruginosa (MIC = 7.81 μg / mL). in vitro cytotoxic activities study proved that [Cu ( L 3 )(OAc)] complex exhibited appreciable activity versus (HEPG-2); IC50 = 4.8 μg/ml, while [Cu( L 2 )(OAc)] complex showed a high activity against (MCF-7); IC50 = 6.2 μg/ml. These results could be considered as new findings of promising antitumor candidates for experimental chemotherapy. 相似文献
9.
We characterize the indecomposable transjective modules over an arbitrary cluster-tilted algebra that do not lie on a local slice, and we provide a sharp upper bound for the number of (isoclasses of) these modules. 相似文献
10.