首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1124篇
  免费   33篇
  国内免费   5篇
化学   736篇
晶体学   2篇
力学   45篇
数学   215篇
物理学   164篇
  2023年   6篇
  2019年   11篇
  2018年   15篇
  2017年   11篇
  2016年   23篇
  2015年   27篇
  2014年   26篇
  2013年   62篇
  2012年   47篇
  2011年   43篇
  2010年   27篇
  2009年   31篇
  2008年   46篇
  2007年   45篇
  2006年   39篇
  2005年   34篇
  2004年   38篇
  2003年   32篇
  2002年   41篇
  2001年   6篇
  2000年   13篇
  1999年   8篇
  1998年   10篇
  1997年   13篇
  1996年   8篇
  1995年   12篇
  1994年   11篇
  1993年   14篇
  1992年   18篇
  1991年   14篇
  1990年   20篇
  1989年   6篇
  1988年   21篇
  1987年   11篇
  1986年   11篇
  1985年   26篇
  1984年   23篇
  1983年   29篇
  1982年   21篇
  1981年   15篇
  1980年   27篇
  1979年   21篇
  1978年   24篇
  1977年   20篇
  1976年   32篇
  1975年   13篇
  1974年   13篇
  1973年   10篇
  1972年   9篇
  1971年   7篇
排序方式: 共有1162条查询结果,搜索用时 15 毫秒
1.
2.
The mechanism of lithium insertion that occurs in an iron oxyfluoride sample with a hexagonal–tungsten–bronze (HTB)-type structure was investigated by the pair distribution function. This study reveals that upon lithiation, the HTB framework collapses to yield disordered rutile and rock salt phases followed by a conversion reaction of the fluoride phase toward lithium fluoride and nanometer-sized metallic iron. The occurrence of anionic vacancies in the pristine framework was shown to strongly impact the electrochemical activity, that is, the reversible capacity scales with the content of anionic vacancies. Similar to FeOF-type electrodes, upon de-lithiation, a disordered rutile phase forms, showing that the anionic chemistry dictates the atomic arrangement of the re-oxidized phase. Finally, it was shown that the nanoscaling and structural rearrangement induced by the conversion reaction allow the in situ formation of new electrode materials with enhanced electrochemical properties.  相似文献   
3.
Azulene, acenaphthylene and fulvene derivatives exhibit important physical properties useful in materials chemistry as well as valuable biological properties. Since about two decades ago, the metal‐catalyzed functionalization of such compounds, via C?H bond activation of their 5‐membered carbocyclic ring, proved to be a very convenient method for the synthesis of a wide variety of azulene, acenaphthylene and fulvene derivatives. For such reactions, there is no need to prefunctionalize the 5‐membered carbocyclic rings. In this review, the progress in the synthesis of azulene, acenaphthylene and fulvene derivatives via metal‐catalyzed C?H bond activation of their 5‐membered carbocyclic ring are summarized.  相似文献   
4.
In many industrial manufacturing processes, the ratio of the variance to the mean of a quantity of interest is an important characteristic to ensure the quality of the processes. This ratio is called the coefficient of variation (CV). A lot of control charts have been designed for monitoring the CV of univariate quantity in the literature. However, the CV control charts for multivariate quantity have not received much attention yet. In this paper, we investigate a variable sampling interval (VSI) Shewhart control chart for monitoring multivariate CV. The time between two consecutive samples is allowed to vary according to the previous value of the multivariate CV, which will help the chart to detect the process shifts faster. The comparison with the fixed sampling interval Shewhart chart is implemented to highlight the advantage of the VSI method. Finally, an illustrative example is demonstrated on real data.  相似文献   
5.
Although significant progress has been made in the design and application of injectable hydrogels for biomedical applications, concurrent control of rheological and mechanical properties of injectable hydrogels has remained as an open challenge to the researchers. In this work, we introduce and put into practice a photo‐curable poloxamer (also known as Pluronic)/graphene oxide (Plu/GO) injectable hydrogel with well‐controlled rheological and mechanical properties. Acrylate group was anchored to hydrogel structure to endow photo‐crosslinking ability through decelerating degradation rate of poloxamer hydrogels after injection. It was found that the modified Plu remains stable in biological media for a long‐term period without significant weight loss. Rheological properties of hydrogels were also carried out as essential prerequisite for an ideal injectability via frequency sweep, flow curve, recovery, and yield stress before and after modification, signifying shear‐thinning behavior of Plu/GO hydrogels with high recoverability. The viscosity of shear‐thinning‐like hydrogels dropped at higher shear stress, which facilitated injection process. Moreover, mechanical behavior of Plu was optimized by manipulating the content of Plu, degree of modification with reactive precursor, curing, and particularly incorporation of GO without deteriorating effects on rheological behavior of Plu.  相似文献   
6.

In the quadri–dimensional space–time, the variation of Hamilton’s action is a powerful tool to study the process equations for conservative fluid media. In this framework, Hamilton’s principle allows to obtain equation of motions, equation of energy but also Rankine–Hugoniot conditions. The variational method may be a versatile key to obtain the shock-wave conditions for complex media when the equations of processes are not expressed by linear or quasi-linear differential equations.

  相似文献   
7.
8.
This article is the first in a series devoted to Kato’s Euler system arising from p-adic families of Beilinson elements in the K-theory of modular curves. It proves a p-adic Beilinson formula relating the syntomic regulator (in the sense of Coleman-de Shalit and Besser) of certain distinguished elements in the K-theory of modular curves to the special values at integer points ≥ 2 of the Mazur-Swinnerton-Dyer p-adic L-function attached to cusp forms of weight 2. When combined with the explicit relation between syntomic regulators and p-adic étale cohomology, this leads to an alternate proof of the main results of [Br2] and [Ge] which is independent of Kato’s explicit reciprocity law.  相似文献   
9.
Amination of 1,1‐dimethylhydrazine with NH2Cl or hydroxylamine‐O‐sulfonic acid yields 2,2‐dimethyltriazanium (DMTZ) chloride ( 3 ) and sulphate ( 4 ), respectively. The DMTZ cation was paired with the nitrogen‐rich anions 5‐aminotetrazolate ( 5 ), 5‐nitrotetrazolate ( 6 ), 5,5′‐azobistetrazolate ( 7 ), and azide ( 8 ), yielding a new family of energetic salts. The synthesis was carried out by metathesis reactions of salts 3 or 4 and a suitable silver or barium salt. To minimize the risks involved when using heavy metal salts, we used electrodialysis for the synthesis of azide 8 , which avoids the use of highly sensitive species. The DMTZ derivatives were characterized by IR and multinuclear NMR spectroscopy, elemental analysis, and X‐ray diffraction. Thermal stabilities were measured using DSC analysis and their sensitivities towards classical stimuli were determined using standard tests. Lastly, the relationship between hydrogen bonding in the solid state and sensitivity is discussed.  相似文献   
10.
Using three different notions of the generalized principal eigenvalue of linear second‐order elliptic operators in unbounded domains, we derive necessary and sufficient conditions for the validity of the maximum principle, as well as for the existence of positive eigenfunctions for the Dirichlet problem. Relations between these principal eigenvalues, their simplicity, and several other properties are further discussed. © 2015 Wiley Periodicals, Inc.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号