Anilinolysis of O‐butyl phenyl phosphonochloridothioate in acetonitrile: Synthesis,characterization, kinetic study,and reaction mechanism

This paper describes a simple optimized method for the synthesis of O‐butyl phenyl phosphonochloridothioate ( 4 ) under mild conditions. The target compounds were characterized by ¹H‐nuclear magnetic resonance (NMR), ¹³C‐NMR, and ³¹P‐NMR spectroscopy, as well as mass spectroscopy. The apparent structure of 4 was confirmed by optimization using the B3LYP/6‐311 + G(d,p) level in the Gaussian 09 program in acetonitrile. The nucleophilic substitution reactions of 4 with X‐anilines (XC₆H₄NH₂) and deuterated X‐anilines (XC₆H₄ND₂) were investigated kinetically in acetonitrile at 55.0°C. The free energy relationship with X in the anilines looked biphasic concave upwards with a break region between X = H and X = 3‐MeO, giving large negative ρ_X and small positive β_X values. The deuterium kinetic isotope effects were secondary inverse (k_H/k_D < 1: 0.789‐0.995) and the magnitudes, (k_H/k_D), increased when the nucleophiles were changed from weakly basic to strongly basic anilines. A concerted S_N2 mechanism is proposed on the basis of the selectivity parameters and the variation trend of the deuterium kinetic isotope effects with X.     

M(o)bius不变的Qp空间:结果、技巧和问题

本文是关于Mobius不变的Qp函数空间方面的综述文章，给出了近10年来有关Qp函数空间的若干结果、技巧和问题。     

由4-氯-6-[2-(吡嗪-2-基亚甲基)肼基]嘧啶构筑的一维银配合物及其抗氧化和抑菌性能

由4-氯-6-[2-(吡嗪-2-基亚甲基)肼基]嘧啶(HL)和硝酸银合成了一维链状配位聚合物[Ag(C_(10)H_9N_6Cl)(NO_3)]_n(1)。在配合物1中,中心Ag离子与来自配体吡嗪环上的N5原子及另一配体上的N1、N4、N6原子进行配位,形成了锯齿形的一维链状结构。此外,锯齿形一维链通过N—H…O和N—H…N氢键相互作用及π-π堆积形成了三维的超分子结构。研究结果表明,与配体HL相比配合物1对超氧负离子和羟基自由基具有更强的自由基清除效能;配合物1对不同细菌的抗菌效果也优于配体HL。     

硫氰酸铵树脂相分光光度法同时测定天然水中微量铁和钴

研究了在Ｔｗｅｅｎ－８０存在的酸性介质中，Ｆｅ（Ⅲ）和Ｃｏ（Ⅱ）与ＳＣＮ＾－形成稳定的有色络阴离子与阴树脂交换吸附，有色络合物富集显色于树脂组上，进行树脂组分光光度集显色于树脂相上，进行树脂相分光光度法同时测定铁和钴的实验条件，Ｆｅ（Ⅲ）和Ｃｏ（Ⅱ）树脂具有色络合物最大吸收波长λｍａｘ分别为４９０ｎｍ和６３０ｎｍ，摩尔吸光系数，ε为２．４×１０＾５Ｌ．ｍｏｌ＾－１．ｃｍ＾－１和２．１×１０＾５Ｌ．     

Hardy－Littlewood Theorems in Mixed Norm Spaces on Bounded Symmetric Domain of C~n

Ｈａｒｄｙ－ＬｉｔｔｌｅｗｏｏｄＴｈｅｏｒｅｍｓｉｎＭｉｘｅｄＮｏｒｍＳｐａｃｅｓｏｎＢｏｕｎｄｅｄＳｙｍｍｅｔｒｉｃＤｏｍａｉｎｏｆＣ~ｎ￥（乌兰哈斯）ＷｕｌａｎＨａｓｉ（ＤｅｐａｒｔｍｅｎｔｏｆＭａｔｈｅｍａｔｉｃｓ，ＩｎｎｅｒＭｏｎｇｏｌｉａＮ?..     

混合范数空间中函数的Taylor系数

本文研究了混合范数空间Ｈ（ｐ，ｑ，ａ）中解析函数ｆ的Ｔａｙｌｏｒ系数，对０＜ｐ≤２，０＜ｑ＜∞，ａ＞０和２≤ｐ＜∞，０＜ｑ＜∞，ａ＞０两种情形，分别给出了ｆ属于Ｈ（ｐ，ｑ，ａ）的必要条件和充分条件。用上述结果我们还得到了几个关于混合范数空间的乘子定理，这些结果也推广了Ｈａｒｄｙ和Ｌｉｔｔｌｅｗｏｏｄ关于Ｈ＾ｐ空间的相应结论。     

Investigation on the output energy characteristic of optical limiting based on stimulated Brillouin scattering

Stimulated Brillouin scattering (SBS) featuring sub-nanosecond response time takes place at a high power threshold, which enables its application at a high power density. When the intensity of input light excesses the SBS threshold, strong SBS process takes place through SBS medium, leading to a quick energy transfer from pump to the Stokes and thereby an optical limiting characteristic in the output energy. In this paper, the correlation between SBS output energy and input power density is numerically simulated and validated in the Nd: YAG Q-switch laser system. The results indicate that not only the output energy exhibits an optical limiting characteristic, but also the clamped value of output energy can be controlled by changing the medium or the focal length.     

Lipschitz spaces and Q_K type spaces

If f(z) =Σ∞ n=0 anzn and g(z) =Σ∞n=0bnzn for functions f, g are analytic in the unit disc, the Hadamard products of f and g is defined by f * g = ∞ n=0 a n b n z n . In this paper, the Lipschitz spaces Λ(s, α) and QK type spaces are studied in terms of the Hadamard products.