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1.
Solid particles in Earth’s atmosphere, such as polystyrene beads, are an important factor affecting the processes of absorption and scattering of light in the atmosphere. These processes affect on the solar energy transfer in the Earth’s atmosphere, consequently they have influence on the regional and global climate changes and atmospheric visibility. In particular, great interest to study the scattering properties of small particles compared with wavelength, because of such particles experience low gravitational settlement and may have long time of life in the atmosphere. When scattering particle is much smaller than the wavelength of the scattered or absorbed light, this is the case of Rayleigh scattering. Scattering properties of these particles (such as intensity and the degree of linear polarization) at the Rayleigh scattering are simply derived from electromagnetic Maxwell’s equations. But when the particles are large enough to be comparable with the wavelength, the deviations from Rayleigh scattering law are observed. One of the clear manifestations of such deviations is the recently discovered quasi-Rayleigh polarization leap of monodisperse spherical particles. This quasi-Rayleigh polarization leap allows remote sensing of the sizes of distant particles, based on the spectral position of quasi-Rayleigh polarization leap at different phase angles of observation. In this paper, we studied the effect of the non-sphericity of a scattering polystyrene particle on the magnitude and position of the quasi-Rayleigh polarization leap. It is established that the non-sphericity shifts the position of the quasi-Rayleigh polarization leap shorter wavelengths. It is shown that for non-sphericity of particles makes the quasi-Rayleigh polarization leap becomes less pronounced. Moreover, it was found, that increasing of the phase angle and degree of non-sphericity shift the quasi-Rayleigh polarization leap position to shorter wavelength. However, in the case of not very elongated particles, the quasi-Rayleigh polarization leap is quite well manifested. Therefore, this method is suitable for remote sensing not only the size, but also the degree of non-sphericity of the scattering particles. A simple formula has been obtained for polystyrene beads that relates the degree of non-sphericity of a particle with the wavelength and phase angles at which the quasi-Rayleigh polarization leap is observed.  相似文献   
2.
The energy spectra of three types of two-dimensional potentials(we will call them‘Davidson-like potentials’(DLPs)),characterized by four minima separated by barriers,are investigated.The predictions for spectra and wave functions are obtained by using the nine-point finite-difference method.For these potentials,with the existence of a single configuration,a transition of spectra,as a function of barrier height,is covered from tunneling splitting modes to fluctuations phenomena,with equal peaks wave functions,crossing to the spectra of purely anharmonic oscillator potentials(AOPs).A different type of phase transition occurs when two(or more)configurations coexist.With the change of the parameters,a transition of spectra is covered from coexistence phenomena of two distinct quantum tunneling modes to fluctuations phenomena,with unequal peaks wave functions,crossing to the spectra of purely AOPs.Using DLPs,a particular application of the coherent quadropole-octupole model to describe energy bands with alternating parity of the nuclei100Mo,146,148Nd,148,150Sm,220Ra,220,222Rn,and220,222Th is presented.The global parametrization of the model for the selected nuclei is achieved.  相似文献   
3.
Applied Mathematics and Mechanics - Mechanical models of residually stressed fibre-reinforced solids, which do not resist bending, have been developed in the literature. However, in some residually...  相似文献   
4.
We investigate the impact of Ni insertion on the structural,optical,and magnetic properties of Ba0.8La0.2Fe12-xNixO19hexaferrites(Ni substituted La-BaM hexaferrites).Samples were prepared using the conventional co-precipitation method and sintered at 1000℃for 4 hours to assist the crystallization process.An analysis of the structure of the samples was carried out using an x-ray diffraction(XRD)spectrometer.The M-type hexagonal structure of all the samples was confirmed using XRD spectra.The lattice parameters a and c were found to be in the ranges of 5.8925±0.001 nm–5.8952±0.001 nm and 23.2123±0.001 nm–23.2219±0.001 nm,respectively.The M-type hexagonal nature of the prepared samples was also indicated by the presence of corresponding FT-IR bands and Raman modes in the FT-IR and Raman spectra,respectively.EDX results confirmed the successful synthesis of the samples according to the required stoichiometric ratio.A UV-vis spectrometer was used to record the absorption spectra of the prepared samples in the wavelength range of 200 nm–1100 nm.The optical energy bandgap of the samples was found to be in the range of 1.21 eV–3.39 eV.The M–H loops of the samples were measured at room temperature at an applied magnetic field range of 0 kOe–60 kOe.A high saturation magnetization of 99.92 emu/g was recorded in the sample with x=0 at a microwave operating frequency of 22.2 GHz.This high value of saturation magnetization is due to the substitution of La3+ions at the spin-up(12k,2a,and 2b)sites.The Ni substitution is proven to be a potential candidate for the tuning of the optical and magnetic parameters of M-type hexaferrites.Therefore,we suggest that the prepared samples are suitable for use in magneto-optic applications.  相似文献   
5.
建立了超高效液相色谱-质谱联用法同时测定细胞内4种吡啶核苷酸辅酶(烟酰胺腺嘌呤二核苷酸(NAD+)和烟酰胺腺嘌呤二核苷酸磷酸(NADP+)以及它们的还原态(NADH和NADPH))的方法。样品经甲醇低温快速提取后,在新型混合模式Atlantis PREMIER BEH C18AX色谱柱上分离,10 mmol/L甲酸铵-乙腈作为流动相在8 min内完成梯度洗脱分离,采用质谱多反应检测(MRM)模式,负离子[M-H]扫描检测。对于4种吡啶核苷酸辅酶,本方法均在较宽浓度范围内呈良好线性关系,检出限和定量限分别在0.03~0.30 pmol和0.06~1.20 pmol范围内;检测准确度在92.7%~107.6%之间,相对标准偏差在1.98%~7.57%之间。该方法操作简便、分析快速、准确度高、灵敏度好,适用于人和微生物等多种细胞样品中吡啶核苷酸辅酶的快速定量测定,为细胞生理代谢研究提供可靠的技术支持。  相似文献   
6.
Carbyne is an infinitely long linear chain of carbon atoms with sp1 hybridization and the truly one-dimensional allotrope of carbon. While obtaining freestanding carbyne is still an open challenge, the study of confined carbyne, linear chains of carbon encapsulated in carbon nanotubes, provides a pathway to explore carbyne and its remarkable properties in a well-defined environment. In this review, we discuss the basics and recent advances in studying single confined carbyne chains by Raman spectroscopy, which is their primary spectroscopic characterization method. We highlight where single carbyne chain studies are needed to advance our understanding of confined carbyne as a material system and provide an overview of the open questions that need to be addressed and of those aspects currently under debate.  相似文献   
7.
Over the last decade, numerous research efforts have been devoted to pillar[n]arenes since their debut.The popularity of pillararenes is a reflection of current research trend in supramolecular and macrocyclic chemistry in general. Among the vast applications(such as chemosensors, drug delivery, transmembrance channels, and separation) of pillararenes, their utilization in catalysis is a relatively less explored area.However, soaring attention has been paid by researchers in recent years and thi...  相似文献   
8.
($1-x$)MnFe$_{2}$O$_{4}$ (MFO)/$x$ZnMn$_{2}$O$_{4}$ (ZMO) ($x=0$, 0.2, 0.5, 0.8, and 1.0) nanocomposite samples were prepared using co-precipitation procedure. The phase percentage, cell parameters, and crystallite size of MFO and ZMO phases in each nanocomposite sample were calculated using Rietveld refinement procedure. The x-ray diffraction (XRD) analysis and Fourier-transform infrared spectroscopy techniques established the variation in the lattice parameters of each phase are due to permutation of all cations among the octahedral and tetrahedral sites of MFO and ZMO. The different oxidation states of different ions in all samples were determined using x-ray photoelectron spectroscopy (XPS) technique. The variation in absorbance of the nanocomposite samples with composition parameter ($x$) is dependent on the wavelength region. The optical bandgap of the nanocomposite samples is decreased as the content of ZMO phase increased. The effect of alloying on the refractive index, extinction coefficient, dielectric constant, optical conductivity, and the nonlinear optical behaviors of all samples were studied in detail. The nanocomposite sample $x=0.5$ disclosed upgraded optical parameters with the highest refractive index, optical conductivity, and PL intensity, which nominate it to be functional in various application fields.  相似文献   
9.
Daohan Ge 《中国物理 B》2022,31(4):44102-044102
A new type of device consisting of a lithium niobate film coupled with a distributed Bragg reflector (DBR) was theoretically proposed to explore and release Bloch surface waves for applications in sensing and detection. The film and grating made of lithium niobate (LiNbO3) were placed on both sides of the DBR and a concentrated electromagnetic field was formed at the film layer. By adjusting the spatial incidence angle of the incident light, two detection and analysis modes were obtained, including surface diffraction detection and guided Bloch detection. Surface diffraction detection was used to detect the gas molecule concentrations, while guided Bloch detection was applied for the concentration detection of biomolecule-modulated biological solutions. According to the drift of the Fano curve, the average sensor sensitivities from the analysis of the two modes were 1560 °/RIU and 1161 °/RIU, and the maximum detection sensitivity reached 2320 °/RIU and 2200 °/RIU, respectively. This study revealed the potential application of LiNbO3 as a tunable material when combined with DBR to construct a new type of biosensor, which offered broad application prospects in Bloch surface wave biosensors.  相似文献   
10.
We give some sufficient conditions for the nonnegativity of immanants of square submatrices of Catalan-Stieltjes matrices and their corresponding Hankel matrices. To obtain these sufficient conditions, we construct new planar networks with a recursive nature for Catalan-Stieltjes matrices. As applications, we provide a unified way to produce inequalities for many combinatorial polynomials, such as the Eulerian polynomials, Schröder polynomials, and Narayana polynomials.  相似文献   
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