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排序方式: 共有378条查询结果,搜索用时 15 毫秒
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Cover Picture: Coordination Chemistry of N‐Heterocyclic Nitrenium‐Based Ligands (Chem. Eur. J. 19/2015) 下载免费PDF全文
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Nikita A. Kazin Nadezhda S. Demina Roman A. Irgashev Ekaterina F. Zhilina Gennady L. Rusinov 《Tetrahedron》2019,75(33):4686-4696
The effective approaches for regioselective double formylation and acetylation of 5,12-dialkyl-6,7-diaryl-substituted 5,12-dihydroindolo[3,2-a]carbazoles by their treatment with dichloromethyl methyl ether in the presence of SnCl4 or with acetyl chloride in the presence of AlCl3 to afford the 2,9-diformyl or 2,9-diacetyl derivatives, respectively, were developed. Furthermore, new 2,9-bis(2,2-dicyanovinyl) derivatives were synthesized by the Knoevenagel condensation of diformyl-containing substrates with malononitrile, when new 2,9-bis(quinoxaline-2-yl)- and 2,9-bis(benzo[g]quinoxaline-2-yl) derivatives were formed via microwave-promoted oxidation of diacetyl-containing substrates with SeO2 to the corresponding diglyoxals, followed by the reaction of these intermediates with o-phenylendiamine or 2,3-diaminonaphthalene, respectively. The basic optical and electrochemical properties of some 5,12-dihydroindolo[3,2-a]carbazoles were investigated. 相似文献
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Sergey G. Il’yasov Viktor A. Cherkashin Gennady V. Sakovich Dmitri A. Parkhomenko 《Chemical Papers》2015,69(11):1445-1453
The chemical structures of Miscanthus var. ‘Soranovskii’ lignin fractions released via extraction of lignin from the lignocellulosic feedstock using moderately heated acetone under atmospheric pressure, without acidic and alkaline catalysts, were studied. A blend of Miscanthus stems and leaves was pretreated with water under thermobaric conditions. The acetone organosolv process subsequently afforded a substance related to a lignin-like matter-acetone organosolv Miscanthus lignin (AOML). Non-destructive analytical techniques such as FTIR spectroscopy, gas chromatography-mass spectrometry, size-exclusion chromatography, and 2D NMR were used. The IR and NMR spectroscopies revealed the AOML structure to comprise all the three major types of phenylpropane units: guaiacyl (G), syringyl (S), and p-hydroxyphenyl (H). The resultant acetone-organosolv lignin exhibits good solubility in polar solvents, moderate solubility in aromatic chemicals, and is insoluble in non-polar solvents, exhibiting the physicochemical properties of a thermoplastic polymer with a softening point of 67.0°C (onset 33.0°C, endset 81.5°C). 相似文献
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Ekaterina E. Stoikova Michail I. Sorvin Dmitry N. Shurpik Herman C. Budnikov Ivan I. Stoikov Gennady A. Evtugyn 《Electroanalysis》2015,27(2):440-449
A novel potentiometric sensor based on screen‐printed carbon electrode covered with electropolymerized polyaniline (PANI) and unsubstituted pillar[5]arene as ionophore has been developed and tested in potentiometric measurements of pH and metal ions. The introduction of pillar[5]arene improved the reversibility of the pH response in the range from 2.0 to 9.0 with the slope of 45 mV/pH. Among metal cations, the response to Fe3+ and Ag+ ions was referred to PANI redox conversion whereas the signal toward Cu2+ in the range from 1.0×10?6 to 1.0×10?2 M (limit of detection (LOD) 3.0×10?7 M) to specific interaction with the macrocycle. 相似文献
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Impedimetric Detection of DNA Damage with the Sensor Based on Silver Nanoparticles and Neutral Red 下载免费PDF全文
Yury Kuzin Anna Porfireva Veronika Stepanova Vladimir Evtugyn Ivan Stoikov Gennady Evtugyn Tibor Hianik 《Electroanalysis》2015,27(12):2800-2808
Novel electrochemical DNA‐sensor based on glassy carbon electrode (GCE) modified with Ag nanoparticles, Neutral red covalently attached to its surface and native DNA adsorbed on modifier coating was developed for the estimation of DNA damage on example of model system based on Fenton reagent. As was shown, the oxidation process resulted in synchronous increase of electron transfer resistance and capacitance measured by electrochemical impedance spectroscopy (EIS). The contribution of each sensor component on the signal was specified and sensitivity estimated against similar surface coatings. The shift of EIS parameters was found to be higher than that of similar biosensors reported. The DNA sensor was tested on the estimation of antioxidant capacity of green tea infusions again the results of coulometric titration with electrogenerated bromine. 相似文献
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Dmitry A. Bratsun Alexej V. Zyuzgin Gennady F. Putin 《International Journal of Heat and Fluid Flow》2003,24(6):835-852
We study both experimentally and numerically the convective flow in a tall vertical slot with differently heated walls. The flow is investigated for the fluid with the Prandtl number Pr=26, which is large enough to ensure the traveling waves as primary instability and small enough to prevent boundary layer convection. The flow evolution is determined on the base of the visual observations, power spectra and amplitude analysis. In the numerical simulations of two- and three-dimensional flows, we accept an assumption of an infinite fluid layer. The satisfactory agreement with experiment is observed, and the sequence of convection states is discovered. It starts with a plane-parallel flow as primary solution, which becomes unstable to two counter-propagating waves. It is followed by a tertiary three-dimensional flow in the form of wavy traveling waves. As the Grashof number is increased even further, a chaotically oscillating cellular pattern consisting of the pieces of broken waves arises. The formation of a structure in the form of the vertical rolls chaotically modulated along axes concludes this complicated picture. 相似文献
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Gennady S. Mishuris Alexander B. Movchan Leonid I. Slepyan 《Journal of the mechanics and physics of solids》2009,57(12):1958-1979
We consider a Mode III lattice with an interface layer where the dynamic crack growth is caused by a localised sinusoidal wave. In the wave–fracture scenario, the ‘feeding wave’ (here also called the knife wave) delivers energy to the moving crack front, while the dissipative waves carry a part of this energy away from the front. The questions addressed here are:
- • What are the conditions of existence of the localised knife wave?
- • What is the lower bound of the amplitude of the feeding wave, which supports the crack propagation, for a given deformational fracture criterion?
- • How does the crack speed depend on the amplitude of the feeding wave?
- • What are the dissipative waves? How much energy is irradiated by these waves and what is the total dissipation?
- • What are the conditions of existence of the steady-state regime for the propagating crack?
Keywords: A. Dynamic fracture; A. Vibrations; B. Inhomogeneous material; B. Supersonic crack; C. Integral transforms 相似文献