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排序方式: 共有162条查询结果,搜索用时 15 毫秒
1.
Enno Aeissen Aaron R. von Seggern Dr. Marc Schmidtmann Prof. Dr. Jens Christoffers 《European journal of organic chemistry》2023,26(14):e202300180
Cyclopenta-, benzo-, and cyclohepta[b]-annulated azepane scaffolds were prepared in two steps from optically active cyclic α-allyl-β-oxoesters. The first step was ruthenium-catalyzed olefin cross metathesis with acrylonitrile. The second step was palladium-catalyzed dihydrogenation which consists of three consecutive processes: The hydrogenation of the C−C double and C−N triple bonds was followed by the reductive amination via the iminium ion formed in situ from the primary amino function and the endocyclic carbonyl group. This last step gave, stereoselectively, the annulated azepanes with relative trans-configuration. The amino function and the ester group define two points for further diversification of the scaffolds. The trifluoroacetyl derivatives allowed to establish the enantiopurity of the products to be 97–98 % ee by GLC on a chiral phase. The relative trans-configurations and in one case also the absolute (R,R)-configuration was established by X-ray crystallography. 相似文献
2.
We investigate minimum vertex degree conditions for 3-uniform hypergraphs which ensure the existence of loose Hamilton cycles. A loose Hamilton cycle is a spanning cycle in which only consecutive edges intersect and these intersections consist of precisely one vertex. 相似文献
3.
Dirk Schlüter Florian Kleemiss Dr. Malte Fugel Dr. Enno Lork Prof. Dr. Kunihisa Sugimoto PD Dr. Simon Grabowsky Prof. Dr. Jeffrey R. Harmer Dr. Matthias Vogt 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(6):1335-1343
Derivatives of 1,2-dithienylethene (DTE) have superb photochromic properties due to an efficient reversible photocyclization reaction of their hexatriene structure and, thus, have application potential in materials for optoelectronics and (multi-responsive) molecular switches. Transition-metal complexes bearing switchable DTE motifs commonly incorporate their coordination site rather distant from the hexatriene system. In this work the redox active ligand 1,2-bis(2,5-dimethylthiophen-3-yl)ethane-1,2-dione is described, which reacts with [V(TMEDA)2Cl2] to give a rare non-oxido vanadium(IV) species 3(M,M/P,P) . This blue complex has two bidentate en-diolato ligands which chelate the VIV center and give rise to two five-membered metallacycles with the adjacent hexatriene DTE backbone bearing axial chirality. Upon irradiation with UVA light or prolonged heating in solution, the blue compound 3(M,M/P,P) converts into the purple atropisomer 4(para,M/para,P) . Both complexes were isolated and structurally characterized by single-crystal X-ray diffraction analysis (using lab source and synchrotron radiation). The antiparallel configuration (M or P helicity) present in both 3(M,M/P,P) and 4(para,M/para,P) is a prerequisite for (reversible) 6π cyclization reactions. A CW EPR spectroscopic study reveals the metalloradical character for 3(M,M/P,P) and 4(para,M/para,P) and indicates dynamic reversible cyclization of the DTE backbone in complex 3(M,M/P,P) at ambient temperature in solution. 相似文献
4.
Chaolumen Hiroki Enno Dr. Michihisa Murata Prof. Dr. Atsushi Wakamiya Prof. Dr. Yasujiro Murata 《化学:亚洲杂志》2014,9(11):3136-3140
Perylene bisimides (PBIs) are fascinating dyes with various potential applications. To study the effects of introducing a dibenzo‐fused structure to the perylene moiety, π‐extended PBI derivatives with a dibenzo‐fused structure at both of the a and f bonds were synthesized. The twisted structure was characterized by X‐ray crystal structure analysis. In the cyclic voltammograms, the dibenzo[a,f]‐fused PBI showed a reversible oxidation wave at much less positive potential, relative to a dibenzo[a,o]‐fused PBI derivative. These data indicated that two ring fusions at both sides of a naphthalene moiety, which construct a tetracene core, effectively raise the HOMO level compared to fusion of one ring at each naphthalene moiety (two anthracene cores). The dibenzo[a,f]‐fused PBI derivative showed an absorption band at 735 nm with a shoulder band reaching 900 nm. 相似文献
5.
How Many Molecules are Required to Obtain a Steady Faradaic Current from Mediated Electron Transfer at a Single Nanoparticle on a Supporting Surface? 下载免费PDF全文
Enno Kätelhön Kay J. Krause Prof. Dr. Bernhard Wolfrum Prof. Dr. Richard G. Compton 《Chemphyschem》2014,15(5):872-875
We investigate the chronoamperometric noise characteristics of electron‐transfer reactions occurring on single nanoparticles (NPs) and assemblies of well‐separated NPs on a supporting surface. To this end, we combine a formerly described expression for the steady‐state current of a single particle with the shot‐noise model and derive an expression for the signal‐to‐noise ratio as a function of bulk concentration and particle radius. Our findings are supported by random‐walk simulations, which closely match the analytical results. 相似文献
6.
Chemically synthesized single‐crystalline gold microplates have been attracting increasing interest because of their potential as high‐quality gold films for nanotechnology. We present the growth of tens of nanometers thick and tens of micrometers large single‐crystalline gold plates directly on solid substrates by solution‐phase synthesis. Compared to microplates deposited on substrates from dispersion phase, substrate‐grown plates exhibit significantly higher quality by avoiding severe small‐particle contamination and aggregation. Substrate‐grown gold plates also open new perspectives to study the growth mechanism via step‐growth and observation cycles of a large number of individual plates. Growth models are proposed to interpret the evolution of thickness, area and shape of the plates. It is found that the plate surface remains smooth after regrowth, implying the applicability of regrowth for producing giant plates as well as unique single‐crystalline nano‐structures. 相似文献
7.
We prove general uniqueness results for radial solutions of linear and nonlinear equations involving the fractional Laplacian (?Δ)s with s ? (0,1) for any space dimensions N ≥ 1. By extending a monotonicity formula found by Cabré and Sire , we show that the linear equation has at most one radial and bounded solution vanishing at infinity, provided that the potential V is radial and nondecreasing. In particular, this result implies that all radial eigenvalues of the corresponding fractional Schrödinger operator H = (?Δ)s + V are simple. Furthermore, by combining these findings on linear equations with topological bounds for a related problem on the upper half‐space , we show uniqueness and nondegeneracy of ground state solutions for the nonlinear equation for arbitrary space dimensions N ≥ 1 and all admissible exponents α > 0. This generalizes the nondegeneracy and uniqueness result for dimension N = 1 recently obtained by the first two authors and, in particular, the uniqueness result for solitary waves of the Benjamin‐Ono equation found by Amick and Toland .© 2016 Wiley Periodicals, Inc. 相似文献
8.
Maurizio Roczen Enno Malguth Martin Schade Andreas Schöpke Abdelazize Laades Michael Blech Orman Gref Thomas Barthel Jan Amaru Töfflinger Manfred Schmidt Hartmut S. Leipner Lars Korte Bernd Rech 《Journal of Non》2012,358(17):2253-2256
Two different growth mechanisms are compared for the fabrication of Si/SiO2 nanostructures on crystalline silicon (c-Si) to be used as hetero-emitter in high-efficiency solar cells: (1) The decomposition of substoichiometric amorphous SiOx (a-SiOx) films with 0 < x < 1.3 and (2) the dewetting of thin amorphous silicon (a-Si) layers.The grown layers are investigated with regard to their structural properties, their passivation quality for c-Si wafer substrates and their electrical properties in order to evaluate their suitability as a nanodot hetero-emitter. While by layer decomposition, no passivating nanodots could be formed, the dewetting process allows fabricating nanodot passivation layers at temperatures as low as 600 °C. The series resistance through Ag/[Si-nanodots in SiO2]/c-Si/Al structures for dewetting is similar to nanostructured silicon rich SiOx films. Still, a nanodot hetero-emitter which exhibits both a satisfying passivation of the substrate and induces a high band bending by doping at the same time could not be fabricated yet. 相似文献
9.
10.
Raivo Stern Ivo Heinmaa Enno Joon Alexander A. Tsirlin Hiroyuki Nakamura Tsuyoshi Kimura 《Applied magnetic resonance》2014,45(11):1253-1260
We present low-temperature (low-T, sub-liquid-N2) high-speed high-resolution 29Si solid-state (cryoMAS) nuclear magnetic resonance studies on a model 2D-BEC quantum magnet BaCuSi2O6, known also as Han Purple. We observe broadened 29Si lines below the well-established 100 K structural phase transition confirming the existence of inhomogeneities at low temperatures. Interestingly, the low-T spectra of \({\mathrm{BaCuSi}}_{2}{\mathrm{O}}_{6}\) closely resemble those of the novel compound Ba2CoSi2O6Cl2 taken at room temperature. This suggests that the Co compound features structural modulations or inhomogeneities already at room temperature. The low-T crystal structure and magnetism of \({\mathrm{BaCuSi}}_{2}{\mathrm{O}}_{6}\) are more complex than previously believed, and deserve further investigation. 相似文献