Nanostructured Colloidal Solutions of Malachite Green Formulated: Nonlinear Optical Properties and Simulation

Journal of Fluorescence - Malachite green (MG) is a dye that has been presented to use as photosensitizers for photodynamic therapy (PDT). Nonlinear absorption coefficient (β) and nonlinear...     

MCM-41-SO3H: an efficient,reusable, heterogeneous catalyst for the one-pot,three-component synthesis of pyrano[3,2-b]pyrans

Research on Chemical Intermediates - MCM-41-SO3H, ordered mesoporous silica material MCM-41 with covalently anchored sulfonic acid groups, was used as a solid acid catalyst for the convenient,...     

Influence of ionic liquid counterions on activity and selectivity of ethylene trimerization using chromium-based catalysts in biphasic media

In recent years ionic liquids (ILs) have attracted much interest because of their widespread use in various fields. Several trimerization and oligomerization catalysts have been evaluated in ILs with different organic–inorganic hybrid structures. High catalytic activity and selectivity, easy product separation, and recycling of the catalyst are the advantages of a biphasic catalyst system compared to the homogeneous catalysts. In this study, the influence of IL counter-anions on activity and selectivity of the ethylene trimerization catalysts based on Cr-SNS-R was investigated. All synthesized materials were characterized using Fourier-transform infrared spectroscopy, ¹H NMR, ¹³C NMR, UV–Vis. spectroscopy, thin-layer chromatography, and elemental analysis (CHNS). In ethylene trimerization reaction, the dodecyl substituent in the SNS ligand exhibited better activity and selectivity than the butyl substituent. The results revealed that the presence of BF₄⁻ as a counter-anion in the IL led to an increase in activity and selectivity compared to Br⁻ and I⁻ counter-anions. It was found that the BF₄⁻ counter-anion plays a conclusive role in the development of 1-hexene activity and selectivity to a maximum amount of 71,132 g_1-C6/(g_Cr × h) and more than 99%, respectively. Finally, the catalyst was reused thrice without losing its 1-hexene selectivity.     

Intramolecular cyclization of <Emphasis Type="Italic">N</Emphasis>-propargyl anilines: a new synthetic entry into highly substituted indoles

Indole derivatives are an important class of heterocycle found in a large number of natural products and synthetic pharmaceuticals. Given the low cost and easy availability of N-propargyl anilines, synthesis of indole cores from these versatile structural motifs has attracted a lot of attention in the past decade. In this review, we summarize the most representative and interesting reports on this rapidly advancing area, with special emphasis on mechanistic aspects of the reactions.     

Electrochemical behavior of Al2O3/Al composite coated Al electrodes through surface mechanical alloying in alkaline media

The behavior of $A{l}_2{O}_3/Al$ composite coated Al electrodes fabricated by surface mechanical alloying ‘SMA’ was studied. The work was accomplished using Cyclic voltammetry and electrochemical impedance spectroscopy (EIS) techniques in alkaline media $2MKOH$ were done at room temperature. Results show hydroxyl ions accumulate on the surface due to Al deformation micro cavities filling with $A{l}_2{O}_3$ until full charge blockage reached. A barrier cover layer development causing an increase of both resistance and capacitance as it becomes more stable and thinner with exposure time increase. Migrating hydroxyl ion inside micro cavity changed its composition from Al₂O₃ to stable tetrahedral $Al{\left(OH\right)}_4^{?}$ aluminate ions. Therefore future benefits could be reached by developing such surfaces having charge accumulation that enables environmental interaction.     

Existence of solutions for k-dimensional system of multi-term fractional q-integro-differential equations under anti-periodic boundary conditions via quantum calculus

We prove the existence and uniqueness of solutions for a $k$-dimensional system of multi-term fractional $q$-integro-differential equations via anti-periodic boundary conditions by using some well-known tools of fixed point technique such as Arzelà–Ascoli theorem. We firstly give the corresponding Green function for the boundary value problem and some of its attributes. In addition to, we give a numeric method to verify the analysis for checking the existence of a solution of the system. Finally, an interesting example is presented to illustrate the results.     

Thermodynamics and Phase Transition of Topological Dilatonic Lifshitz-Like Black Holes

It is known that scalar-tensor gravity models can be studied in Einstein and Jordan frames. In this paper, a model of scalar-tensor gravity in Einstein's frame is considered to calculate the Lifshitz-like black hole solutions with different horizon topologies. Thermodynamic properties and first order van der Waals-like phase transition are studied, and it is found that the Lifshitz parameter affects the phase structure. In addition, thermal stability is investigated by using the behavior of heat capacity and various methods of geometrical thermodynamics.     

Performance enhancement of the power penalty in DWDM FSO communication using DPPM and OOK modulation

This paper presents the design and performance enhancement of the power penalty (PP) in a dense wavelength division multiplexing based on free space optical communication (FSOC) link using digital pulse position modulation (DPPM) and on–off keying (OOK) modulation. Such a system has a high performance, low cost, robust and power efficient, reliable, excessive flexibility, and higher data rate for access networks. The system performance is evaluated for an 8-channel wavelength-division-multiplexing for hybrid fiber FSOC system at 2.5 Gbps on widely accepted modulation schemes under various atmospheric turbulence (AT) regimes conditions. The performance of system is introduced in terms of PP, bit-error rate (BER), transmission distance and the average received optical power. The numerical results shows that the improvement of the PP using DPPM modulation of 0.2–3.0 dB for weak turbulence (WT) regimes for BER of 10^?6 and above 20, 25 dB for strong turbulence (ST) regimes are reported for BER of 10^?6 and 10^?9, as respectively (depending on the AT level). Further, we develop of improvement the PP caused by multiple-access interference about 6.686 dB which is predicted for target BER of 10^?9 in WT and 1 dB at target BER of 10^?6 in ST when the 8 user are active on the system of optical network units. Additionally, the optical power budget and margin losses of a system are calculated with different link length. The proposed approach of DPPM merges superiority with higher enhancement of PP about 0.8 dB for BER equal 10^?9 at FSO link length l_fso?=?2000 m compared to OOK at 1 dB for WT. An improvement of 2 dB is observed using the DPPM scheme over an OOK due to capability of detect pulses under background noise conditions with increased receiver sensitivity.