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排序方式: 共有694条查询结果,搜索用时 234 毫秒
1.
Asadollah Zarif Farhad Amarloo Faeze Pourazimi Najmeh Kaftani Zahra Rostamabadi Ebrahim 《Journal of fluorescence》2022,32(5):1639-1650
Journal of Fluorescence - Malachite green (MG) is a dye that has been presented to use as photosensitizers for photodynamic therapy (PDT). Nonlinear absorption coefficient (β) and nonlinear... 相似文献
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Sarrafi Yaghoub Mehrasbi Ebrahim Mashalchi Seyyedeh Zohreh 《Research on Chemical Intermediates》2021,47(4):1729-1741
Research on Chemical Intermediates - MCM-41-SO3H, ordered mesoporous silica material MCM-41 with covalently anchored sulfonic acid groups, was used as a solid acid catalyst for the convenient,... 相似文献
5.
In recent years ionic liquids (ILs) have attracted much interest because of their widespread use in various fields. Several trimerization and oligomerization catalysts have been evaluated in ILs with different organic–inorganic hybrid structures. High catalytic activity and selectivity, easy product separation, and recycling of the catalyst are the advantages of a biphasic catalyst system compared to the homogeneous catalysts. In this study, the influence of IL counter-anions on activity and selectivity of the ethylene trimerization catalysts based on Cr-SNS-R was investigated. All synthesized materials were characterized using Fourier-transform infrared spectroscopy, 1H NMR, 13C NMR, UV–Vis. spectroscopy, thin-layer chromatography, and elemental analysis (CHNS). In ethylene trimerization reaction, the dodecyl substituent in the SNS ligand exhibited better activity and selectivity than the butyl substituent. The results revealed that the presence of BF4− as a counter-anion in the IL led to an increase in activity and selectivity compared to Br− and I− counter-anions. It was found that the BF4− counter-anion plays a conclusive role in the development of 1-hexene activity and selectivity to a maximum amount of 71,132 g1-C6/(gCr × h) and more than 99%, respectively. Finally, the catalyst was reused thrice without losing its 1-hexene selectivity. 相似文献
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A good photocatalyst with high efficiency can be synthesized easily using eco-friendly materials and processes. Our synthesized samples exhibit all of the aforementioned features. In this work, manganese co-doped ZnO at different weight percentages (3, 6, 9, and 15 wt.%) with and without 1.5 wt.% aluminum was synthesized by hydrothermal method, and their photocatalytic activity in aqueous solutions of methyl orange (MO) was investigated under visible light. The structural and optical properties of the samples were characterized using X-ray powder diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray analysis, and diffuse reflectance spectroscopy. In this work, Mn2+ ions in the 9%Mn/ZnO sample and Mn2+, Al3+ ions in the (9%Mn, 1.5%Al)/ZnO sample calcined at 800 °C were replaced instead with some Zn2+ ions in hexagonal wurtzite structures of ZnO. These structures were found next to each other in the form of a hexagonal shape that created 3D-hexagonal-like ZnO nanostructures. Finally, nanoparticles (NPs) and nano hexagonal-like ZnO nanostructures were, respectively, dispersed on the surface of 3D-hexagonal-like structure of 9%Mn/ZnO and (9%Mn, 1.5%Al)/ZnO. Diffuse reflectance spectroscopy analysis showed that the (9%Mn, 1.5%Al)/ZnO sample had more light absorption than 9%Mn/ZnO. However, contrary to our expectations, the 9%Mn/ZnO sample had better decolorization efficiency (94%) after 60 min under visible light, which could be attributed to a significant increase in the level of recombination by the aluminum ions. 相似文献
7.
Saba Hemmati Mohammad Yousefi Mirmehdi Hashemi Salehi Mahdis Amiri Malak Hekmati 《应用有机金属化学》2020,34(8):e5653
This paper develops a green method for in situ decorated of palladium nanoparticles over Fe3O4 nanoparticles, by utilizing Strawberry fruit extract and ultrasound irradiations, with no use of any toxic reducing agent. The structure's characterization is represented via diverse analytical methods such as FT-IR, FE-SEM, TEM, WDX, ICP, EDS and XXPS. Catalytic efficiency of magnetic Fe3O4@Strawberry/Pd nanocatalyst is investigated in production of different biphenyls with good turnover frequencies (TOF) and turnover numbers (TON) through Suzuki coupling reactions. Furthermore, the catalyst could be recovered and reused 7 runs without considerable palladium leaching or alteration in its performance. 相似文献
8.
Esmail Vessally Akram Hosseinian Ladan Edjlali Ebrahim Ghorbani-Kalhor Rahim Hosseinzadeh-Khanmiri 《Journal of the Iranian Chemical Society》2017,14(11):2339-2353
Indole derivatives are an important class of heterocycle found in a large number of natural products and synthetic pharmaceuticals. Given the low cost and easy availability of N-propargyl anilines, synthesis of indole cores from these versatile structural motifs has attracted a lot of attention in the past decade. In this review, we summarize the most representative and interesting reports on this rapidly advancing area, with special emphasis on mechanistic aspects of the reactions. 相似文献
9.
Rezvan Salehi 《Numerical Algorithms》2017,74(4):1145-1168
In this paper, a meshless collocation method is considered to solve the multi-term time fractional diffusion-wave equation in two dimensions. The moving least squares reproducing kernel particle approximation is employed to construct the shape functions for spatial approximation. Also, the Caputo’s time fractional derivatives are approximated by a scheme of order O(τ 3?α ), 1< α < 2. Stability and convergence of the proposed scheme are discussed. Some numerical examples are given to confirm the efficiency and reliability of the proposed method. 相似文献
10.
N. Mahdavi-Amiri F. Salehi Sadaghiani 《4OR: A Quarterly Journal of Operations Research》2017,15(3):303-326
Recently, Luc defined a dual program for a multiple objective linear program. The dual problem is also a multiple objective linear problem and the weak duality and strong duality theorems for these primal and dual problems have been established. Here, we use these results to prove some relationships between multiple objective linear primal and dual problems. We extend the available results on single objective linear primal and dual problems to multiple objective linear primal and dual problems. Complementary slackness conditions for efficient solutions, and conditions for the existence of weakly efficient solution sets and existence of strictly primal and dual feasible points are established. We show that primal-dual (weakly) efficient solutions satisfying strictly complementary conditions exist. Furthermore, we consider Isermann’s and Kolumban’s dual problems and establish conditions for the existence of strictly primal and dual feasible points. We show the existence of primal-dual feasible points satisfying strictly complementary conditions for Isermann’s dual problem. Also, we give an alternative proof to establish necessary conditions for weakly efficient solutions of multiple objective programs, assuming the Kuhn–Tucker (KT) constraint qualification. We also provide a new condition to ensure the KT constraint qualification. 相似文献