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1.
David Mercier Éric Lefèvre François Delmotte 《International Journal of Approximate Reasoning》2012,53(2):146-158
In this article, the contextual discounting of a belief function, a classical discounting generalization, is extended and its particular link with the canonical disjunctive decomposition is highlighted. A general family of correction mechanisms allowing one to weaken the information provided by a source is then introduced, as well as the dual of this family allowing one to strengthen a belief function. 相似文献
2.
Maria Lasaosa Nathanaël Delmotte Christian G. Huber Katja Melchior Elmar Heinzle Andreas Tholey 《Analytical and bioanalytical chemistry》2009,393(4):1245-1256
The separation of complex peptide mixtures in shotgun proteome analysis using a 2D separation scheme encompassing reversed-phase
× ion-pair reversed-phase (IP-RP) liquid chromatography coupled online to electrospray ion trap mass spectrometry (MS) has
been shown earlier to be superior in terms of separation efficiency and technical robustness compared to the classically used
separation scheme encompassing strong cation exchange × IP-RP-chromatography in shotgun proteome analysis. In the present
study, this novel separation scheme was coupled offline to matrix-assisted laser desorption/ionization (MALDI) time-of-flight
(TOF)/TOF-MS for the analysis of the same sample, a tryptic digest of the cytosolic proteome of the bacterium Corynebacterium glutamicum. Compared to the earlier study, the MALDI-based platform led to a significantly increased number of peptides (7,416 vs. 2,709)
and proteins (1,208 vs. 468, without single peptide-based identifications), respectively. This represents the majority of
all predicted cytosolic proteins in C. glutamicum. The high proteome coverage, as well as the large number of low-abundant proteins identified with this improved analytical
platform, pave the way for new biological studies.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
3.
F. Choueikani F. Bridou B. Lagarde E. Meltchakov F. Polack P. Mercere F. Delmotte 《Applied Physics A: Materials Science & Processing》2013,111(1):191-198
We present a comparative study of B4C/Mo and B4C/Mo2C periodic multilayer structures deposited by magnetron sputtering. The characterization was performed by grazing incidence X-ray reflectometry at two different energies and high resolution transmission electron microscopy. The experimental results indicate the existence of an interdiffusion layer at the B4C-on-Mo interface in the B4C/Mo system. Thus, the B4C/Mo multilayers were modeled by an asymmetric structure with three layers in each period. The thickness of B4C-on-Mo interfacial layer was estimated about 1.1 nm. The B4C/Mo2C multilayers present less interdiffusion and are well modeled by a symmetric structure without interfacial layers. This study shows that B4C/Mo2C structure is an interesting alternative to B4C/Mo multilayer for X-ray optic applications. 相似文献
4.
Delmotte N Kobold U Meier T Gallusser A Strancar A Huber CG 《Analytical and bioanalytical chemistry》2007,389(4):1065-1074
Immunoadsorbers based on 2.0 × 6.0 mm i.d., epoxy-bearing, methacrylate-based monolithic disks were developed in order to
target myoglobin and N-terminal pro-natriuretic peptide (NT-proBNP), two biomarkers involved in cardiovascular disease. In
both cases, antibodies were successfully coupled to the polymeric disk material. The developed immunoadsorbers permitted the
selective isolation of myoglobin and NT-proBNP from human serum. Myoglobin was successfully isolated and detected from serum
samples at concentrations down to 250 fmol μL−1. However, the affinity of the antibodies was not sufficient for the analysis of low-concentration clinical samples. Frontal
analysis of anti-NT-proBNP disks revealed the ability of the immunoadsorber to bind up to 250 pmol NT-proBNP, which is more
than sufficient for the analysis of clinical samples. Anti-NT-proBNP disks showed good stability over more than 18 months
and excellent batch-to-batch reproducibility. Moreover, anti-NT-proBNP disks permitted the isolation of NT-proBNP at concentrations
down to 750 amol μL−1 in serum, corresponding to concentrations of strongly diseased patients. Using reversed-phase trapping columns, the detection
of NT-proBNP eluted from immunoadsorbers by mass spectrometry was achieved for concentrations down to 7.8 fmol μL−1. 相似文献
5.
L. Delmotte C. Ganne-Chedeville J.M. Leban F. Pichelin 《Polymer Degradation and Stability》2008,93(2):406-412
The essential chemical modifications involving the polymeric constituents of wood in friction welding occur in the first 5-6 s slowing down or even stopping afterwards. FT-IR and CP-MAS 13C NMR of the welded area of wood have shown dehydration and an apparent increase in the crystallinity of cellulose. A certain level of hemicelluloses degradation occurs, accompanied by the generation of some furfural. Cellulose degradation is instead very slight. Both analytical techniques show an increase in the proportion of lignin in the welding interphase. A proportion of methoxy groups of lignin is de-etherified to phenolic hydroxy groups. Self-condensation of lignin occurs by internal rearrangement with the formation of Ar-Ar and Ar-CH2-Ar bridges. This progresses throughout the whole process of welding. The formation of C-O-C bridges, although stopping after 6 s welding, at the start of wood carbonisation, also appears to contribute to the increase in cross-linking of the lignin network. 相似文献
6.
7.
J. Gautier F. Delmotte F. Bridou M.F. Ravet F. Varniere M. Roulliay A. Jerome I. Vickridge 《Applied Physics A: Materials Science & Processing》2007,88(4):719-725
Scandium/silicon multilayers have been deposited by magnetron sputtering and characterized by several techniques. Experimental
peak reflectances of 0.22 and 0.37 have been measured respectively at wavelengths of 40 nm and 46 nm, for 10° incidence angle.
The corresponding theoretical values for a perfect Sc/Si structure are respectively 0.38 and 0.57. In order to explain these
differences between calculated and measured reflectivity, thin film and multilayer characterizations have been done. Effects
of multilayer imperfections on the reflectivity have been estimated independently by means of simulation. Based on these results,
a new design of Sc/Si multilayer is proposed with top layer thickness optimization. With this design, the experimental peak
reflectance reaches 0.46 at a wavelength of 46 nm.
PACS 78.67.Pt; 78.66.-W; 81.15.Cd 相似文献
8.
Philippe Bertani Jsus Raya Pierre Reinheimer Rgis Gougeon Luc Delmotte Jrme Hirschinger 《Solid state nuclear magnetic resonance》1999,13(4):255-229
19F/29Si Hartmann–Hahn continuous wave cross-polarization (CP) has been applied under fast magic-angle spinning (MAS) to a powder sample of octadecasil. Strong oscillations occur during CP on a sideband matching condition between the isolated 29Si–19F spin pairs formed by the silicons in the D4R units and the fluoride anions. The magnitude of the dipolar coupling constant was deduced directly from the line-splitting between the intense singularities of the Pake-like patterns obtained by Fourier transformation of the oscillatory polarization transfer. The corresponding Si–F internuclear distance, r=2.62±0.05 Å, is found to be in very good agreement with the X-ray crystal structure and the value of 2.69±0.04 Å recently reported from rotational echo double resonance (REDOR) and transferred echo double resonance (TEDOR) nuclear magnetic resonance (NMR) experiments. Furthermore, the CP technique is still reliable under fast MAS where both REDOR and TEDOR sequences suffer from severe artefacts due to finite pulse lengths. In octadecasil, a spinning frequency of 14 kHz is shown to be necessary for an effective suppression of 19F–19F spin diffusion. The influences of experimental missettings and radiofrequency (RF) field inhomogeneity are taken into account. 相似文献
9.
Rudolph Willem Ann Delmotte Inge De Borger Monique Biesemans Marcel Gielen Franois Kayser Edward R. T. Tiekink 《Journal of organometallic chemistry》1994,480(1-2):255-259
The synthesis of (Z)-2-methyl-3-triphenylstannyl-3-pentene-2-ol and its characterization by an X-ray diffraction study and multinuclear NMR are reported. The tin atom exhibits a distorted tetrahedral SnC4 geometry with the four Sn---C bond distances experimentally equivalent. The slight distortion from the ideal tetrahedral geometry is because of the presence of a weak intramolecular HO → Sn interaction of 3.012(3) Å which produces a loose four-membered ring. The title compound was characterized in solution by 1H, 13C and 119Sn NMR, and the persistence of the weak intramolecular HO → Sn coordination in solution was revealed by 13C and 119Sn secondary isotope multiplet of partially labelled entities (SIMPLE-NMR) experiments. 相似文献
10.
Julien Gautier Franck Delmotte Arnaud Jérome Francoise Varnière 《Optics Communications》2008,281(11):3032-3035
A two-channel mirror reflecting both Fe-IX/X (λ = 17.1 nm) and He-II (30.4 nm) resonance lines at near normal incidence has been designed, fabricated and characterized. These two passbands are often chosen in space instruments designed for the observation of the solar corona. The mirror structure used for optimization is a superposition of two periodic multilayers with three components per period. It has been designed by using optimization software with an appropriate merit function. The theoretical reflectivity for both resonance lines can reach 0.25. It is shown that, by using a set of filters, one can select either the Fe-IX/X or the He-II channel. The spectral response of the two-channel mirror has been measured on synchrotron radiation source on a large wavelength range, from 12 nm to 35 nm. Experimental reflectivity reaches 0.32 for the Fe-IX/X line and 0.19 for the He-II line. 相似文献