全文获取类型
收费全文 | 2523篇 |
免费 | 113篇 |
国内免费 | 7篇 |
专业分类
化学 | 1846篇 |
晶体学 | 7篇 |
力学 | 40篇 |
数学 | 447篇 |
物理学 | 303篇 |
出版年
2023年 | 21篇 |
2022年 | 17篇 |
2021年 | 68篇 |
2020年 | 71篇 |
2019年 | 76篇 |
2018年 | 38篇 |
2017年 | 42篇 |
2016年 | 108篇 |
2015年 | 97篇 |
2014年 | 105篇 |
2013年 | 167篇 |
2012年 | 196篇 |
2011年 | 201篇 |
2010年 | 153篇 |
2009年 | 110篇 |
2008年 | 161篇 |
2007年 | 140篇 |
2006年 | 120篇 |
2005年 | 130篇 |
2004年 | 116篇 |
2003年 | 94篇 |
2002年 | 73篇 |
2001年 | 24篇 |
2000年 | 26篇 |
1999年 | 23篇 |
1998年 | 27篇 |
1997年 | 30篇 |
1996年 | 28篇 |
1995年 | 23篇 |
1994年 | 23篇 |
1993年 | 18篇 |
1992年 | 21篇 |
1991年 | 8篇 |
1990年 | 6篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 10篇 |
1986年 | 9篇 |
1985年 | 8篇 |
1983年 | 5篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1976年 | 6篇 |
1975年 | 3篇 |
1974年 | 5篇 |
1973年 | 2篇 |
1970年 | 2篇 |
排序方式: 共有2643条查询结果,搜索用时 15 毫秒
1.
Gatto Claudia C. Chagas Marcio A. S. Lima Iariane J. Mello Andrade Francyelli Silva Hugo D. Abrantes Gabrielly R. Lacerda Elisângela P. S. 《Transition Metal Chemistry》2019,44(4):329-340
Transition Metal Chemistry - The present study reports the synthesis and crystal structures of Cu(II) complexes with pyridoxal S-allyldithiocarbazate (H2L1) and pyridoxal thiosemicarbazones... 相似文献
2.
3.
A Stable Porphyrin Functionalized Graphite Electrode Used at the Oxygen Evolution Reaction Potential
Gianlorenzo Bussetti Roberto Bernasconi Claudia Filoni Luca Magagnin Alberto Bossi Franco Ciccacci Lamberto Duò 《Electroanalysis》2022,34(7):1227-1236
Many researches have been devoted to rechargeable power generators that can store (but also release) energy. This availability is ensured through (e. g.) the oxygen evolution reaction (OER). However, (i) large values of the overpotentials and (ii) a progressive detriment of the anode (graphite) electrode limit the ultimate device. In view of enhancing the electrode performances, graphite was protected by following different strategies, which oblige to follow precise preparation protocols. Here, we prove that a thin layer of free-base porphyrin molecules is able to protect the underneath graphite electrode from detriment even if many (about 100) electrochemical cycles are performed. 相似文献
4.
Gusenbauer Claudia Peter Karolina Cabane Etienne Konnerth Johannes 《Cellulose (London, England)》2022,29(2):763-776
Cellulose - Chemical force microcopy, a variation of atomic force microscopy, opened the door to visualize chemical nano-properties of various materials in their natural state. The key function of... 相似文献
5.
Physisorption and chemisorption of hydrogen on solid-state materials are two fundamentally different interactions, both of which display advantages and drawbacks for hydrogen storage. It has been hypothesised that their combination by merging two classes of materials showing different sorption behaviour towards hydrogen in the same composite may synergistically combine their desirable properties. As representatives of such composites, palladium nanoparticles, nanoclusters, and single atoms have been encapsulated in a metal-organic framework matrix, embedded, or immobilised in its pores, respectively. In this minireview, we review advances on the understanding and potential applications of the combination of Pd with metal-organic framework matrices through the analysis of the nanocomposite materials’ interaction with hydrogen and sorption properties. 相似文献
6.
Almeida Carolane M. de Carvalho João G. M. Fujimori Mahmi França Eduardo L. Honorio-França Adenilda C. Parreira Renato L. T. Orenha Renato P. Gatto Claudia C. 《Structural chemistry》2020,31(5):2093-2103
Structural Chemistry - The current work reports the synthesis and structural investigation of three novel complexes with 2-acetyl-pyridine-N(4)-phenylthiosemicarbazone (HL1), [Ni(L1)Cl] (1),... 相似文献
7.
8.
Claudia Poloni Marc C. A. Stuart Pieter van der Meulen Wiktor Szymanski Ben L. Feringa 《Chemical science》2015,6(12):7311-7318
The external photocontrol over peptide folding, by the incorporation of molecular photoswitches into their structure, provides a powerful tool to study biological processes. However, it is limited so far to switches that exhibit only a rather limited geometrical change upon photoisomerization and that show thermal instability of the photoisomer. Here we describe the use of an overcrowded alkene photoswitch to control a model β-hairpin peptide. This photoresponsive unit undergoes a large conformational change and has two thermally stable isomers which has major influence on the secondary structure and the aggregation of the peptide, permitting the phototriggered formation of amyloid-like fibrils. 相似文献
9.
Lorenzo Milli Dr. Nicola Zanna Andrea Merlettini Matteo Di Giosia Dr. Matteo Calvaresi Prof. Maria Letizia Focarete Prof. Claudia Tomasini 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(34):12106-12112
We present herein the preparation of four different hydrogels based on the pseudopeptide gelator Fmoc‐l ‐Phe‐d ‐Oxd‐OH (Fmoc=fluorenylmethyloxycarbonyl), either by changing the gelator concentration or adding graphene oxide (GO) to the water solution. The hydrogels have been analysed by rheological studies that demonstrated that pure hydrogels are slightly stronger compared to GO‐loaded hydrogels. Then the hydrogels efficiency to trap the cationic methylene blue (MB) and anionic eosin Y (EY) dyes has been analyzed. MB is efficiently trapped by both the pure hydrogel and the GO‐loaded hydrogel through π–π interactions and electrostatic interactions. In contrast, the removal of the anionic EY is achieved in less satisfactory yields, due to the unfavourable electrostatic interactions between the dye, the gelator and GO. 相似文献
10.