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排序方式: 共有172条查询结果,搜索用时 15 毫秒
1.
Hong Chengming Wang Xiaojun Pan Zhigang Zhang Yifan 《Journal of Thermal Analysis and Calorimetry》2015,120(1):427-438
Journal of Thermal Analysis and Calorimetry - The saturated aliphatic binary carboxylic acid, including succinic acid, adipic acid and sebacic acid, were used to improve the curing process of... 相似文献
2.
Ziwei Xu Hongwei Dong Dr. Wanmiao Gu Dr. Zhen He Fengming Jin Dr. Chengming Wang Dr. Qing You Prof. Dr. Jin Li Prof. Dr. Haiteng Deng Dr. Lingwen Liao Dr. Dong Chen Prof. Dr. Jun Yang Prof. Dr. Zhikun Wu 《Angewandte Chemie (International ed. in English)》2023,62(39):e202308441
Lattice tuning at the ≈1 nm scale is fascinating and challenging; for instance, lattice compression at such a minuscule scale has not been observed. The lattice compression might also bring about some unusual properties, which waits to be verified. Through ligand induction, we herein achieve the lattice compression in a ≈1 nm gold nanocluster for the first time, as detected by the single-crystal X-ray crystallography. In a freshly synthesized Au52(CHT)28 (CHT=S-c−C6H11) nanocluster, the lattice distance of the (110) facet is found to be compressed from 4.51 to 3.58 Å at the near end. However, the lattice distances of the (111) and (100) facets show no change in different positions. The lattice-compressed nanocluster exhibits superior electrocatalytic activity for the CO2 reduction reaction (CO2RR) compared to that exhibited by the same-sized Au52(TBBT)32 (TBBT=4-tert-butyl-benzenethiolate) nanocluster and larger Au nanocrystals without lattice variation, indicating that lattice tuning is an efficient method for tailoring the properties of metal nanoclusters. Further theoretical calculations explain the high CO2RR performance of the lattice-compressed Au52(CHT)28 and provide a correlation between its structure and catalytic activity. 相似文献
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Torsional modes within a complex molecule containing various functional groups are often strongly coupled so that the harmonic approximation and one-dimensional torsional treatment are inaccurate to evaluate their partition functions. A family of multi-structural approximation methods have been proposed and applied in recent years to deal with the torsional anharmonicity. However, these methods approximate the exact “almost periodic” potential energy as a summation of local periodic functions with symmetric barrier positions and heights. In the present theoretical study, we illustrated that the approximation is inaccurate when torsional modes present non-uniformly distributed local minima. Thereby, we proposed an improved method to reconstruct approximate potential to replace the periodic potential by using information of the local minima and their Voronoi tessellation. First, we established asymmetric barrier heights by introducing two periodicity parameters and assuming that the exact barrier positions are at the boundaries of Voronoi cells. Second, we used multiplicatively weighted Voronoi tessellation to refine the barrier heights and positions by defining a structure-related distance metric. The proposed method has been tested for a few higher-dimensional cases, all of which show promising improved accuracy. 相似文献
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6.
Yunong Li Lei Wang Jingxiang Low Di Wu Canyu Hu Wenbin Jiang Jun Ma Chengming Wang Ran Long Li Song Hangxun Xu Yujie Xiong 《中国化学快报》2020,31(1):231-234
Efficient catalytic system with low energy consumption exhibits increasing importance due to the upcoming energy crisis.Given this situation,it should be an admirable strategy for reducing energy input by effectively utilizing incident solar energy as a heat source during catalytic reactions.Herein,aza-fused7 r-conjugated microporous polymer(aza-CMP)with broad light absorption and high photothermal conversion efficiency was synthesized and utilized as a support for bimetallic AuPd nanocatalysts in light-driven benzyl alcohol oxidation.The AuPd nanoparticles anchored on aza-CMP(aza-CM P/Au_xPdy)exhibited excellent catalytic performance for benzyl alcohol oxidation under 50 mW/cm^2 light irradiation.The improved catalytic performance by the aza-CMP/Au_xPdy is attributed to the unique photothermal effect induced by aza-CMP,which can promote the catalytic benzyl alcohol oxidation occurring at Au Pd.This work presents a novel approach to effectively utilize solar energy for conventional catalytic reactions through photothermal effect. 相似文献
7.
Modeling of the Temporally and Spatially Modulated Fourier Transform Imaging Spectrometer working in orbit 总被引:1,自引:0,他引:1
Temporally and Spatially Modulated Fourier Transform Imaging Spectrometer (TSMFTIS) is a new kind of imaging spectrometer and is applicable in remote sensing. Compared with Temporally Modulated Imaging Interferometer and Spatially Modulated Imaging Interferometer, it employs immovable parts and abandons slit. Based on the analysis of its physical theory, optical principle, data gathering and processing, the mathematical model of the TSMFTIS working in orbit is proposed in this paper. The model is comprised of different function blocks, such as fore-optics, interferometer and so on. For simulation, a big remote sensing image is utilized as ground scene, and a conversion which is similar to color mode conversion from RGB to Lab is made to produce artificial spectra of various ground objects. At last, a validation experiment is performed with real-world spectra of four pieces of colorful cloths by using a commercially available spectrometer. 相似文献
8.
Bowen Li Liyan Xie Zhaowu Wang Shi Chen Hui Ren Yuliang Chen Chengming Wang Guobin Zhang Jun Jiang Chongwen Zou 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(39):13849-13854
Charge doping is an effective way to induce the metal–insulator transition (MIT) in correlated materials for many important utilizations, which is however practically limited by problem of low stability. An electron–proton co‐doping mechanism is used to achieve pronounced phase modulation of monoclinic vanadium dioxide (VO2) at room temperature. Using l ‐ascorbic acid (AA) solution to treat VO2, the ionized AA? species donate electrons to the adsorbed VO2 surface. Charges then electrostatically attract surrounding protons to penetrate, and eventually results in stable hydrogen‐doped metallic VO2. The variations of electronic structures, especially the electron occupancy of V 3d/O 2p hybrid orbitals, were examined by synchrotron characterizations and first‐principle theoretical simulations. The adsorbed molecules protect hydrogen dopants from escaping out of lattice and thereby stabilize the metallic phase for VO2. 相似文献
9.
采用牛胰岛素作为模型多肽分子, 对几种结构相近的简单多酚的抗多肽淀粉样纤维化作用进行了研究. 结果表明, 邻苯二酚和对苯二酚对胰岛素纤维化具有抑制作用, 并通过形成醌中间体对多肽链进行修饰, 与对苯醌作用类似; 而苯酚和间二苯酚在相同条件下, 既不能修饰多肽也无抑制纤维化作用. 在无氧条件下, 邻苯二酚和对苯二酚对胰岛素纤维化的抑制作用明显降低, 说明酚化合物经氧化形成的醌中间体是其抗胰岛素纤维化的主要活性结构. 相似文献