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1.
Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface. 相似文献
2.
Zhen Xi 《中国科学:化学(英文版)》2015,(3):434-435
Redox-based post-translational modification of protein thiols has become an attractive strategy in cellular homeostasis and cell signaling.Due to the reductive end of the redox buffer network,the vicinal dithiol-containing proteins(VDPs)maintains an appropriate oxidation-reduction state of proteins through the reversible transformation from vicinal dithiols to disulfide,which is responsible for a variety of 相似文献
3.
纵向数据下广义估计方程估计 总被引:1,自引:0,他引:1
广义估计方程方法是一种最一般的参数估计方法,广泛地应用于生物统计、经济计量、医疗保险等领域.在纵向数据下,由于组间数据是相关的,为了提高估计的效率,广义估计方程方法一般需要考虑个体组内相关性.因此,大多数文献对个体组内的协方差矩阵进行参数假设,但假设的合理性及协方差矩阵估计的好坏对参数估计效率产生很大影响,同时参数假设也可能导致模型误判.针对纵向数据下广义估计方程,本文提出了改进的GMM方法和经验似然方法,并对给出的估计量建立了大样本性质.其中分块的思想,避免了对个体组内相关性结构进行假设,从这种意义上说,这种方法具有一定的稳健性.我们还通过两个模拟的例子,考察了文中提出估计量的有限样本性质. 相似文献
4.
系统竞争失效数据在工程应用中广泛存在.屏蔽数据作为它的一种特殊数据形式在工程中有着重要的作用.本文首先介绍了屏蔽数据的形式及其与常规竞争失效数据的区别,然后对串联系统或并联系统,阐述了两种分析屏蔽数据的方法(极大似然法和贝叶斯方法),最后用这两种方法分析了一个实际例子. 相似文献
5.
YBa2Fe3O8(YBFO)是具有三方钙钛矿结构的反铁磁(AFM)体,研究它的结构和磁性质对于我们认识三方钙钛矿结构具有重要作用.目前,关于固相法制备YBFO中退火温度方面的研究并不多,而控制退火温度是这种工艺中的重要环节.为制备高含量的YBa2Fe3O8,本文分别在760℃、950℃和1100℃退火温度下,采用固相... 相似文献
6.
7.
ZHOU ShanShi HU XiaoGong WU Bin LIU Li QU WeiJing GUO Rui HE Feng CAO YueLing Wu XiaoLi ZHU LingFeng SHI Xin & TAN HongLi Shanghai Astronomical Observatory Chinese Academy of Sciences Shanghai China Graduate University of Chinese Academy of Sciences Beijing Beijing Global Information Application Development Center Beijing 《中国科学:物理学 力学 天文学(英文版)》2011,(6)
Aiming at regional services,the space segment of COMPASS (Phase I) satellite navigation system is a constellation of Geostationary Earth Orbit (GEO),Inclined Geostationary Earth Orbit (IGSO) and Medium Earth Orbit (MEO) satellites.Precise orbit determination (POD) for the satellites is limited by the geographic distribution of regional tracking stations.Independent time synchronization (TS) system is developed to supplement the regional tracking network,and satellite clock errors and orbit data may be obtai... 相似文献
8.
The reaction of electrochemically generated anthradiquinone as a Michael acceptor with 2-mercaptobenzothiazole and 2- mercaptobenzoxazole,as nucleophiles in ethanol/water mixtures has been studied by means of cyclic voltammetry.Our voltammetric data indicate that produced anthradiquinone participates in Michael addition reaction with nucleophiles and via an ECEC mechanism converts to the new anthraquinonethioether derivatives.Based on an EC mechanism,the observed homogeneous rate constant of the Michael reaction of anthradiquinone with nucleophiles were estimated by comparing the experimental cyclic voltammograms with the digital simulated results. 相似文献
9.
A novel reaction of trimethylsilylated arylacetylenes with sulfonyl chlorides was performed in the presence of silver nitrate or triflate.Conjugated vinyl sulfones as dramatic products were obtained in moderate yields and with Z-selectivity.A free radical mechanism has been proposed to account for the formation of the products. 相似文献
10.
Let H be a finite-dimensional hereditary algebra over an algebraically closed field k and C F m be the repetitive cluster category of H with m ≥ 1. We investigate the properties of cluster tilting objects in C F m and the structure of repetitive clustertilted algebras. Moreover, we generalize Theorem 4.2 in [12] (Buan A, Marsh R, Reiten I. Cluster-tilted algebra, Trans. Amer. Math. Soc., 359(1)(2007), 323-332.) to the situation of C F m , and prove that the tilting graph KCFm of C F m is connected. 相似文献