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1.
Miguel A. González Juan José Palacios Camino R. Vela Alejandro Hernández-Arauzo 《Journal of Heuristics》2017,23(2-3):81-110
Single machine scheduling problems have many real-life applications and may be hard to solve due to the particular characteristics of some production environments. In this paper, we tackle the single machine scheduling problem with sequence-dependent setup times with the objective of minimizing the weighted tardiness. To solve this problem, we propose a scatter search algorithm which uses path relinking in its core. This algorithm is enhanced with some procedures to speed-up the neighbors’ evaluation and with some diversification and intensification techniques, the latter taking some elements from iterated local search. We conducted an experimental study across a well-known set of instances to analyze the contribution of each component to the overall performance of the algorithm, as well as to compare our proposal with the state-of-the-art metaheuristics, obtaining competitive results. We also propose a new benchmark with larger and more challenging instances and provide the first results for them. 相似文献
2.
3.
Dr. Camino Bartolomé Dr. Fernando Villafañe Dr. Jose M. Martín‐Alvarez Dr. Jesús M. Martínez‐Ilarduya Prof. Dr. Pablo Espinet 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(11):3702-3709
The X‐ray structure of the title compound [Pd(Fmes)2(tmeda)] (Fmes=2,4,6‐tris(trifluoromethyl)phenyl; tmeda=N,N,N′,N′‐tetramethylethylenediamine) shows the existence of uncommon C? H???F? C hydrogen‐bond interactions between methyl groups of the TMEDA ligand and ortho‐CF3 groups of the Fmes ligand. The 19F NMR spectra in CD2Cl2 at very low temperature (157 K) detect restricted rotation for the two ortho‐CF3 groups involved in hydrogen bonding, which might suggest that the hydrogen bond is responsible for this hindrance to rotation. However, a theoretical study of the hydrogen‐bond energy shows that it is too weak (about 7 kJ mol?1) to account for the rotational barrier observed (ΔH≠=26.8 kJ mol?1), and it is the steric hindrance associated with the puckering of the TMEDA ligand that should be held responsible for most of the rotational barrier. At higher temperatures the rotation becomes fast, which requires that the hydrogen bond is continuously being split up and restored and exists only intermittently, following the pulse of the conformational changes of TMEDA. 相似文献
4.
P. Theil-Van Nieuwenhuyse V. Bounor-Legaré P. Bardollet P. Cassagnau A. Michel L. David F. Babonneau G. Camino 《Polymer Degradation and Stability》2013
Polyamide 6 (PA6)/phosphorylated silica nanocomposites were synthesized during PA6 extrusion through in situ formation of the inorganic phase without solvent. This synthesis is based on the hydrolysis-condensation reactions of diethylphosphatoethyltriethoxysilane (SiP) as a functional inorganic precursor in combination with or without tetraethoxysilane (TEOS) dispersed in the molten PA6. This synthesis is carried out during PA 6 matrix extrusion that means at high temperature and under shear. The characterization of the in situ synthesized PA6/phosphorylated silica nanocomposites by solid 29Si Nuclear Magnetic Resonance (NMR), Small Angle X-ray Scattering (SAXS) and Transmission Electron Microscopy (TEM) coupled with Energy Dispersive X-ray spectroscopy (EDX) demonstrated the possibility to directly create in less than 5 min at 220 °C a phosphorylated silica uniformly dispersed in the PA6, i.e. in the form of well dispersed particles or aggregates of sub-micron range. The influence of silicon and phosphorus on the thermal and fire retardant behaviour was investigated by thermogravimetric analysis (TGA), cone calorimeter and UL94 tests. The fire retardant behaviour was modified with a formation of a char and a peak heat release rate (PHRR) decrease by more than 50% for the SiP based nanocomposite compared to the pure PA6. 相似文献
5.
Marconi N. Peas‐Defrutos Camino Bartolom Max García‐Melchor Pablo Espinet 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(11):3539-3543
By combining kinetic experiments, theoretical calculations, and microkinetic modeling, we show that Pf/Rf (C6F5/C6Cl2F3) exchange between [AuPf(AsPh3)] and trans‐[RhRf(CO)(AsPh3)2] does not occur by typical concerted Pf/Rf transmetalation via electron‐deficient double bridges. Instead, it involves asymmetric oxidative insertion of the RhI complex into the (Ph3As)Au?Pf bond to produce a [(Ph3As)Au?RhPfRf(CO)(AsPh3)2] intermediate, followed by isomerization and reductive elimination of [AuRf(AsPh3)]. Interesting differences were found between the LAu?Ar asymmetric oxidative insertion and the classical oxidative addition process of H2 to Vaska complexes. 相似文献
6.
Let EX(ν;{C3,…,Cn}) denote the set of graphs G of order ν that contain no cycles of length less than or equal to n which have maximum number of edges. In this paper we consider a problem posed by several authors: does G contain an n+1 cycle? We prove that the diameter of G is at most n−1, and present several results concerning the above question: the girth of G is g=n+1 if (i) ν≥n+5, diameter equal to n−1 and minimum degree at least 3; (ii) ν≥12, ν∉{15,80,170} and n=6. Moreover, if ν=15 we find an extremal graph of girth 8 obtained from a 3-regular complete bipartite graph subdividing its edges. (iii) We prove that if ν≥2n−3 and n≥7 the girth is at most 2n−5. We also show that the answer to the question is negative for ν≤n+1+⌊(n−2)/2⌋. 相似文献
7.
Ramiro Varela Camino R. Vela Jorge Puente María Sierra Inés González-Rodríguez 《Annals of Operations Research》2009,166(1):125-146
We confront a practical cutting stock problem from a production plant of plastic rolls. The problem is a variant of the well-known
one dimensional cutting stock, with particular constraints and optimization criteria defined by the experts of the company.
We start by giving a problem formulation in which optimization criteria have been considered in linear hierarchy according
to expert preferences, and then propose a heuristic solution based on a GRASP algorithm. The generation phase of this algorithm
solves a simplified version which is rather similar to the conventional one dimensional cutting stock. To do that, we propose
a Sequential Heuristic Randomized Procedure (SHRP). Then in the repairing phase, the solution of the simplified problem is
transformed into a solution to the real problem. For experimental study we have chosen a set of problem instances of com-mon
use to compare SHRP with another recent approach. Also, we show by means of examples, how our approach works over instances
taken from the real production process.
All authors are supported by MEC-FEDER Grant TIN2007-67466-C02-01 and by contract CN-05-127 of the University of Oviedo and
the company ERVISA, and by FICYT under grant BP04-021. 相似文献
8.
Renata Barbosa Tatianny S. Alves Edcleide M. Araújo Tomás. J. A. Mélo Giovanni Camino Alberto Fina Edson N. Ito 《Journal of Thermal Analysis and Calorimetry》2014,115(1):627-634
High-density polyethylene/modified bentonite clay/polar compatibilizer nanocomposites were prepared through the melt intercalation process. The clay was organophilizated using different percentages of quaternary ammonium salt 100, 125, and 150 % based cation exchange capacity of the clay. The nanocomposites were prepared in a counter-rotating twin-screw extruder and then specimens were injection molded. For the evaluation of flammability of the test system was used for burning in the horizontal position according to the norm (Underwriters Laboratories, UL94HB) and to the method of cone calorimeter. The thermal behavior of nanocomposites was evaluated by thermogravimetry and X-ray diffraction techniques, and transmission electron microscopy were used to characterize the morphology and analyze the degree of expansion of the clays prepared and the degree of exfoliation of nanocomposites. It was observed that the percentage of ammonium salt and the compatibilizer polar influence on the final properties of the systems and consequently improving the thermal stability and reducing the flammability of the matrix. 相似文献
9.
Janine Wolf Camino M. González Tanarro Michael Gütschow Joachim Sieler Bärbel Schulze 《Helvetica chimica acta》2008,91(1):35-45
The synthesis of novel triaryl‐substituted 4‐(isothiazol‐3‐yl)morpholines 7 and 8 , and 1‐(isothiazol‐3‐yl)piperazines 9 – 13 by reaction of the corresponding isothiazolium salts 5 and 6 with secondary amines in the presence of t‐BuOK in absolute THF is described. Some representatives of the isothiazoles were evaluated as inhibitors of acetylcholinesterase from Electrophorus electricus. 相似文献
10.
M. Guaita G. Camino O. Chiantore M. Revellino und L. Trossarelli 《Colloid and polymer science》1976,254(8):769
Ohne Zusammenfassung 相似文献