首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   26篇
  免费   0篇
化学   19篇
数学   5篇
物理学   2篇
  2020年   1篇
  2018年   1篇
  2017年   2篇
  2015年   3篇
  2014年   1篇
  2013年   1篇
  2012年   1篇
  2010年   3篇
  2008年   7篇
  2007年   3篇
  2006年   1篇
  2002年   2篇
排序方式: 共有26条查询结果,搜索用时 46 毫秒
1.
3-Aroyl-1H-pyrrolo[2,1-c][1,4]benzoxazine-1,2,4-triones reacted with 5,5-dimethylcyclohexane-1,3-dione to give 3′-aroyl-4′-hydroxy-1′-(2-hydroxyphenyl)-6,6-dimethyl-6,7-dihydrospiro[1-benzofuran-3,2′-pyrrole]-2,4,5′(1′H,5H)-triones. The crystalline and molecular structures of 3′-benzoyl-4′-hydroxy-1′-(2-hydroxyphenyl)-6,6-dimethyl-6,7-dihydrospiro[1-benzofuran-3,2′-pyrrole]-2,4,5′(1′H,5H)-trione were determined by X-ray analysis.  相似文献   
2.
The possibility of application of the ion-associated complex formed between the anionic chelate cobalt(II)-4-(2-thiazolylazo) resorcinol (TAR) with the cation of 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-2H-tetrazolium bromide (MTT) for extraction-spectrophotometric determination of cobalt in the form of an ion associate in Vitamin B12 was studied. The liquid–liquid extraction system Co(II)-TAR-MTT-H2O-CHCl3 was applied. This system was chosen by our previous research of the ion associates of the cobalt by spectrophotometric investigation of fourteen different liquid–liquid extraction systems, containing azo derivatives of resorcinol (TAR or 4-(2-pyridylazo) resorcinol (PAR)) and mono or ditetrazolium salts. Based on the obtained results, a sensitive, relatively simple, convenient and inexpensive method for determination of cobalt in the form of an ion associate in Vitamin B12 was developed. The proposed method can be implemented for biological, medical and pharmaceutical samples containing cobalamin (Vitamin B12).  相似文献   
3.
The formation of an ion-associated complex between the anionic chelate of Mo(VI)–3,5-dinitrocatehol (3,5-DNC) and the cation of 3-(2-naphthyl)-2,5-diphenyl-2H-tetrazolium chloride (TV) in the liquid–liquid extraction system Mo(VI)–3,5-DNC–TV–H2O–CHCl3 was studied by spectrophotometry. The optimum conditions for the complex formation and extraction of the ion-associated complex were established. The effect of co-existing ions and reagents on the process of complex formation was investigated under optimum extraction conditions. The validity of Beer’s law was checked and some analytical characteristics were calculated. The association process in aqueous phase and the extraction equilibria were investigated and quantitatively characterized. The following key constants of the processes were calculated: association constant, distribution constant, extraction constant and recovery factor. The molar ratio of the reagents was determined by independent methods. Based on this, a reaction scheme, a general formula and a structure of the complex were suggested.  相似文献   
4.
5.
Portfolio risk estimation in volatile markets requires employing fat-tailed models for financial returns combined with copula functions to capture asymmetries in dependence and an appropriate downside risk measure. In this survey, we discuss how these three essential components can be combined together in a Monte Carlo based framework for risk estimation and risk capital allocation with the average value-at-risk measure (AVaR). AVaR is the average loss provided that the loss is larger than a predefined value-at-risk level. We consider in some detail the AVaR calculation and estimation and investigate the stochastic stability.  相似文献   
6.
7.
The precursors with a low manganese content ≤ 0.07% Mn were synthesized by spontaneous crystallization from Zn2+, Mn2+ and C2O4 2−-containing solutions. The initial ratio Zn2+:C2O4 2− = 1:1 and 1:2 influences the morphology and prevailing orientations of the crystallites in the oxalate samples. The presence of such small Mn content in the samples does not change the morphology or size of the crystals. The ZnO and Mn/ZnO oxides with manganese content from 0.51×10−2 to 15.1×10−2 Wt % are obtained after thermal decomposition of the oxalates. The oxides preserved the morphology of the precursors. The catalytic tests show that the pure ZnO has a poor activity for CO oxidation reaction. Its doping with Mn promotes the catalytic activity (up from twice to five times) in spite of the very low contents of the dopants. The observed increase of the activity depends on both dopant concentration and Zn2+:C2O4 2− ratio, probably due to the different mechanism of the manganese inclusion and different morphology of the oxides. The catalysts of the 1:2 series are more active in CO oxidation reaction.   相似文献   
8.
9.
3-Aroyl-1H-pyrrolo[2,1-c][1,4]benzoxazine-1,2,4-triones react with methyl 4-aryl-2-arylamino-4-oxobut-2-enoate to give substituted methyl 7-aryl-4,9-bis(aroyl)-3-hydroxy-1-(2-hydroxyphenyl)-2,6-dioxo-1,7-diazaspiro[4.4]nona-3,8-diene-8-carboxylates which undergo thermal cyclization to methyl 9-aroyl-4,7-diaryl-1-(2-hydroxyphenyl)-2,3,8-trioxo-2,3,7,8-tetrahydro-1H,6H-6,8a-methanopyrrolo[2,3-e][1,3]oxazepine-6-carboxylates. The crystalline and molecular structures of methyl 9-benzoyl-1-(2-hydroxyphenyl)-2,3,8-trioxo-4,7-diphenyl-2,3,7,8-tetrahydro-1H,6H-6,8a-methanopyrrolo[2,3-e][1,3]oxazepine-6-carboxylate was studied by X-ray analysis. Original Russian Text ? N.L. Racheva, Z.G. Aliev, A.N. Maslivets, 2008, published in Zhurnal Organicheskoi Khimii, 2008, Vol. 44, No. 8, pp. 1197–1201. For communication LX, see [1].  相似文献   
10.
The main purpose of this article is to present a new numerical procedure that can be used to implement a variety of different interest rate models. The new approach allows to construct no-arbitrage models for the term structure, where the stochastic process driving the rates is infinitely divisible, as in the cases of pure-diffusion and jump-diffusion mean reverting models. The new method determines a unique fully specified hexanomial tree, consistent with risk neutral probabilities. A simple forward recursive procedure solves for the entire tree. The proposed lattice model, which generalized the Hull and White [37] single-factor model, is relatively simple, computational efficient and can fit any initial term structure observed in the market. Numerical experiments demonstrate how the jump-diffusion mean reverting model is particularly suited to describe the European money market rates behavior. Interest rates controlled by the monetary authorities behave as if they are jump processes and the term structure, at short maturity, is contingent upon the levels of these official rates.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号