全文获取类型
收费全文 | 7359篇 |
免费 | 247篇 |
国内免费 | 27篇 |
专业分类
化学 | 4371篇 |
晶体学 | 26篇 |
力学 | 178篇 |
数学 | 1259篇 |
物理学 | 1799篇 |
出版年
2023年 | 40篇 |
2021年 | 48篇 |
2020年 | 92篇 |
2019年 | 95篇 |
2018年 | 85篇 |
2017年 | 73篇 |
2016年 | 176篇 |
2015年 | 156篇 |
2014年 | 212篇 |
2013年 | 323篇 |
2012年 | 412篇 |
2011年 | 482篇 |
2010年 | 248篇 |
2009年 | 229篇 |
2008年 | 403篇 |
2007年 | 459篇 |
2006年 | 430篇 |
2005年 | 408篇 |
2004年 | 340篇 |
2003年 | 255篇 |
2002年 | 244篇 |
2001年 | 167篇 |
2000年 | 123篇 |
1999年 | 81篇 |
1998年 | 51篇 |
1997年 | 85篇 |
1996年 | 82篇 |
1995年 | 87篇 |
1994年 | 69篇 |
1993年 | 68篇 |
1992年 | 69篇 |
1991年 | 48篇 |
1990年 | 54篇 |
1989年 | 46篇 |
1988年 | 50篇 |
1987年 | 43篇 |
1986年 | 64篇 |
1985年 | 75篇 |
1984年 | 80篇 |
1983年 | 74篇 |
1982年 | 87篇 |
1981年 | 77篇 |
1980年 | 69篇 |
1979年 | 72篇 |
1978年 | 83篇 |
1977年 | 75篇 |
1976年 | 52篇 |
1975年 | 57篇 |
1974年 | 65篇 |
1973年 | 70篇 |
排序方式: 共有7633条查询结果,搜索用时 31 毫秒
1.
Sørbye Sigrunn H. Nicolau Pedro G. Rue Håvard 《Statistical Inference for Stochastic Processes》2022,25(3):577-598
Statistical Inference for Stochastic Processes - The class of autoregressive (AR) processes is extensively used to model temporal dependence in observed time series. Such models are easily... 相似文献
2.
3.
Michael Meier Dr. Lei Ji Dr. Jörn Nitsch Dr. Ivo Krummenacher Andrea Deißenberger Dr. Dominic Auerhammer Dr. Marius Schäfer Prof. Dr. Todd B. Marder Prof. Dr. Holger Braunschweig 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(18):4707-4712
A novel thiophene-bridged donor–acceptor system was synthesized with a carbazole as donor and a borole as acceptor unit. The borole group was successfully installed via the tin–boron exchange reaction of 1,1-dimethyl-2,3,4,5-tetraphenylstannole with 9-(5-(dibromoboryl)thiophen-2-yl)carbazole. The effect of the borole on the optoelectronic properties of the donor–acceptor system was explored by spectroscopic (UV/Vis and fluorescence spectroscopy), electrochemical (cyclic voltammetry) and theoretical (TD-DFT) methods as well as by modifying its structure. The corresponding donor–acceptor compound bearing the widely employed dimesitylboryl acceptor group was also synthesized for comparison. 相似文献
4.
Dr. Mick Hornum Julie Stendevad Dr. Pawan K. Sharma Dr. Pawan Kumar Rasmus B. Nielsen Dr. Michael Petersen Dr. Poul Nielsen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(30):7387-7395
Nucleotides that contain two nucleobases (double-headed nucleotides) have the potential to condense the information of two separate nucleotides into one. This presupposes that both bases must successfully pair with a cognate strand. Here, double-headed nucleotides that feature cytosine, guanine, thymine, adenine, hypoxanthine, and diaminopurine linked to the C2′-position of an arabinose scaffold were developed and examined in full detail. These monomeric units were efficiently prepared by convergent synthesis and incorporated into DNA oligonucleotides by means of the automated phosphoramidite method. Their pairing efficiency was assessed by UV-based melting-temperature analysis in several contexts and extensive molecular dynamics studies. Altogether, the results show that these double-headed nucleotides have a well-defined structure and invariably behave as functional dinucleotide mimics in DNA duplexes. 相似文献
5.
Alexandru Vlasceanu Dr. Søren L. Broman Anne S. Hansen Anders B. Skov Prof. Dr. Martina Cacciarini Prof. Dr. Anders Kadziola Prof. Dr. Henrik G. Kjaergaard Prof. Dr. Kurt V. Mikkelsen Prof. Dr. Mogens Brøndsted Nielsen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(31):10796-10800
The conversion and efficient storage of solar energy is recognized to hold significant potential with regard to future energy solutions. Molecular solar thermal batteries based on photochromic systems exemplify one possible technology able to harness and apply this potential. Herein is described the synthesis of a macrocycle based on a dimer of the dihydroazulene/vinylheptafulvene (DHA/VHF) photo/thermal couple. By taking advantage of conformational strain, this DHA–DHA macrocycle presents an improved ability to absorb and store incident light energy in chemical bonds (VHF–VHF). A stepwise energy release over two sequential ring‐closing reactions (VHF→DHA) combines the advantages of an initially fast discharge, hypothetically addressing immediate energy consumption needs, followed by a slow process for consistent, long‐term use. This exemplifies another step forward in the molecular engineering and design of functional organic materials towards solar thermal energy storage and release. 相似文献
6.
A (di)graph is supereulerian if it contains a spanning eulerian sub(di)graph. This property is a relaxation of hamiltonicity. Inspired by this analogy with hamiltonian cycles and by similar results in supereulerian graph theory, we analyze a number of sufficient Ore type conditions for a digraph to be supereulerian. Furthermore, we study the following conjecture due to Thomassé and the first author: if the arc‐connectivity of a digraph is not smaller than its independence number, then the digraph is supereulerian. As a support for this conjecture we prove it for digraphs that are semicomplete multipartite or quasitransitive and verify the analogous statement for undirected graphs. 相似文献
7.
Inside Back Cover: The Nature of Activated Non‐classical Hydrogen Bonds: A Case Study on Acetylcholinesterase–Ligand Complexes (Chem. Eur. J. 8/2016) 下载免费PDF全文
8.
9.
10.