全文获取类型
收费全文 | 534篇 |
免费 | 40篇 |
国内免费 | 4篇 |
专业分类
化学 | 362篇 |
晶体学 | 2篇 |
力学 | 17篇 |
数学 | 26篇 |
物理学 | 171篇 |
出版年
2023年 | 3篇 |
2022年 | 5篇 |
2021年 | 4篇 |
2020年 | 21篇 |
2019年 | 9篇 |
2018年 | 9篇 |
2017年 | 4篇 |
2016年 | 9篇 |
2015年 | 11篇 |
2014年 | 26篇 |
2013年 | 30篇 |
2012年 | 33篇 |
2011年 | 24篇 |
2010年 | 22篇 |
2009年 | 23篇 |
2008年 | 38篇 |
2007年 | 29篇 |
2006年 | 32篇 |
2005年 | 41篇 |
2004年 | 36篇 |
2003年 | 25篇 |
2002年 | 9篇 |
2001年 | 16篇 |
2000年 | 16篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1994年 | 8篇 |
1993年 | 6篇 |
1992年 | 11篇 |
1991年 | 7篇 |
1990年 | 5篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1985年 | 3篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1975年 | 2篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1967年 | 2篇 |
1943年 | 1篇 |
排序方式: 共有578条查询结果,搜索用时 109 毫秒
1.
Science China Chemistry - 相似文献
2.
Dr. Haoxuan Li Haifei Wen Dr. Zhijun Zhang Dr. Nan Song Prof. Ryan T. K. Kwok Prof. Jacky W. Y. Lam Prof. Lei Wang Prof. Dong Wang Prof. Ben Zhong Tang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(46):20551-20555
Using reverse thinking of the aggregation-induced emission (AIE) principle, we demonstrate an ingenious and universal protocol for amplifying molecular motions to boost photothermal efficiency of fibers. Core–shell nanofibers having the olive oil solution of AIE-active molecules as the core surrounded by PVDF-HFP shell were constructed by coaxial electrospinning. The molecularly dissolved state of AIE-active molecules allows them to freely rotate and/or vibrate in nanofibers upon photoexcitation and thus significantly elevates the proportion of non-radiative energy dissipation, affording impressive heat-generating efficiency. Photothermal evaluation shows that the core–shell nanofibers with excellent durability can reach up to 22.36 % of photothermal conversion efficiency, which is 26-fold as the non-core–shell counterpart. Such a core–shell fiber can be used for photothermal textiles and solar steam generation induced by natural sunlight with green and carbon-zero emission. 相似文献
3.
Dr. Andrea Previtali Dr. Wei He Dr. Alessandra Forni Dr. Daniele Malpicci Dr. Elena Lucenti Dr. Daniele Marinotto Prof. Lucia Carlucci Prof. Pierluigi Mercandelli Dr. Marco Aldo Ortenzi Prof. Giancarlo Terraneo Dr. Chiara Botta Prof. Ryan Tsz Kin Kwok Dr. Jacky Wing Yip Lam Prof. Ben Zhong Tang Prof. Elena Cariati 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(67):16690-16700
Organic materials with multiple emissions tunable by external stimuli represent a great challenge. TTPyr, crystallizing in different polymorphs, shows a very rich photophyisics comprising excitation-dependent fluorescence and phosphorescence at ambient conditions, and mechanochromic and thermochromic behavior. Transformation among the different species has been followed by thermal and X-ray diffraction analyses and the emissive features interpreted through structural results and DFT/TDDFT calculations. Particularly intriguing is the polymorph TTPyr(HT), serendipitously obtained at high temperature but stable also at room temperature, whose non-centrosymmetric structure guarantees an SHG efficiency 10 times higher than that of standard urea. Its crystal packing, where only the TT units are strongly rigidified by π-π stacking interactions while the Pyr moieties possess partial conformational freedom, is responsible for the observed dual fluorescence. The potentialities of TTPyr for bioimaging have been successfully established. 相似文献
4.
5.
Wai Chung Fu Zheng Wang Dr. Wesley Ting Kwok Chan Prof. Dr. Zhenyang Lin Prof. Dr. Fuk Yee Kwong 《Angewandte Chemie (International ed. in English)》2017,56(25):7166-7170
A versatile π-extension reaction was developed based on the three-component cross-coupling of aryl halides, 2-haloarylcarboxylic acids, and norbornadiene. The transformation is driven by the direction and subsequent decarboxylation of the carboxyl group, while norbornadiene serves as an ortho-C−H activator and ethylene synthon via a retro-Diels–Alder reaction. Comprehensive DFT calculations were performed to account for the catalytic intermediates. 相似文献
6.
7.
In this article, we disclose a method to fabricate polymer-stabilised azo-dye photo alignment layers for liquid crystal. The idea includes the introduction of polymer network in the alignment layer, in optimal concentration, followed by two-step irradiation. The stabilised photo-alignment layer has been explored for different aspects of the display-related parameters, viz. anchoring energy, stability for various display-related environments as a function of concentration of monomer and irradiation, residual DC and voltage holding ratio. The composite photo-alignment layer offers well-suited parameters for the liquid crystal alignment and therefore could find application in a variety of modern photonic and display devices. 相似文献
8.
We show that all meromorphic solutions of the stationary reduction of the real cubic Swift‐Hohenberg equation are elliptic or degenerate elliptic. We then obtain them all explicitly by the subequation method, and one of them appears to be a new elliptic solution. 相似文献
9.
10.
Dr. Yuanyuan Li Dr. Shunjie Liu Huwei Ni Haoke Zhang Dr. Hequn Zhang Clarence Chuah Chao Ma Prof. Kam Sing Wong Prof. Jacky W. Y. Lam Prof. Ryan T. K. Kwok Prof. Jun Qian Prof. Xuefeng Lu Prof. Ben Zhong Tang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(31):12922-12926
The traditional design strategies for highly bright solid-state luminescent materials rely on weakening the intermolecular π–π interactions, which may limit diversity when developing new materials. Herein, we propose a strategy of tuning the molecular packing mode by regioisomerization to regulate the solid-state fluorescence. TBP-e-TPA with a molecular rotor in the end position of a planar core adopts a long-range cofacial packing mode, which in the solid state is almost non-emissive. By shifting molecular rotors to the bay position, the resultant TBP-b-TPA possesses a discrete cross packing mode, giving a quantum yield of 15.6±0.2 %. These results demonstrate the relationship between the solid-state fluorescence efficiency and the molecule's packing mode. Thanks to the good photophysical properties, TBP-b-TPA nanoparticles were used for two-photon deep brain imaging. This molecular design philosophy provides a new way of designing highly bright solid-state fluorophores. 相似文献