Weitere Messungen zur Anisotropie der intermolekularen Wechselwirkung durch Streuung von Molekülen in definiertem Quantenzustand

The interaction between diatomic molecules and rare gas atoms can be described by the realistic, though simplified potentialV=?[(r_m/r)¹²(1 +q₁₂P₂(cosθ))?2(r_m/r)⁶(1+q₆P₂(cosθ))] The determination of the parameters?, r _m andq ₆has been treated in the two previous parts of this series. The present final paper describes the determination of the anisotropy parameter in the repulsive part of the potential, q₁₂, for the system CsF-He. Whileq ₆ could be derived using only the dependence of the total scattering cross section on the molecular rotational state, the determination ofq ₁₂ requires, in addition, knowledge of the velocity dependence. The comparison of the experimental data for CsF in the rotational states ¦J, M〉=¦1, 1〉 and ¦1, 0〉 with cross sections calculated by means of the “high energy” approximation yields the result:q ₁₂=0.9±0.2. The validity of the “high energy” approximation in the velocity range covered by the experiment is discussed.     

Observation of the atomic Ramsauer—townsend effect in 4He4He scattering

Measurement of the total scattering cross section for ⁴He⁴He at very low energies are presented. The measurements have resolved the atomic Ramsauer—Townsend effect.     

A Proof of the Local Borg–Marchenko Theorem

In [2], [5] a “local” version of a basic uniqueness theorem in inverse spectral theory is given. This paper gives a simple proof of this theorem. Received: 6 November 2000 / Accepted: 8 November 2000     

Velocity dependence of atomic friction

Sliding friction between the tip of a friction force microscope and NaCl(100) was studied to deduce the velocity dependence of friction forces on the atomic scale. A logarithmic dependence of the mean friction force is revealed at low velocities. The experimental data are interpreted in terms of a modified Tomlinson model which is based on reaction rate theory.     

Bemerkung zur Bestimmung der van der Waals-Konstanten aus Streuquerschnitten

The attempt has been made by several authors to clear up the discrepancy between van der Waals constants determined from scattering cross sections for thermal energies and theoretical values using measured oscillator strengths. The present paper discusses three sources of error not accounted for properly in the earlier work. The appropriate corrections discussed in this paper lead to a satisfactory agreement between experiment and theory.