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1.
Hooda  Anjli  Dalal  Anuj  Nehra  Kapeesha  Singh  Sitender  Kumar  Sumit  Singh  Devender 《Journal of fluorescence》2022,32(4):1413-1424
Journal of Fluorescence - A series of europium diketonate complexes with 1-phenyl-1,3-butanedione (PBD) and 1,10-phenanthroline derivatives were synthesized and explored spectroscopically....  相似文献   
2.
Molecular Diversity - The terminal oxidases of the oxidative phosphorylation pathway play a significant role in the survival and growth of M. tuberculosis, targeting these components lead to...  相似文献   
3.
The nanofluid and porous medium together are able to fulfill the requirement of high cooling rate in many engineering problems. So, here the impact of various shapes of nanoparticles on unsteady stagnation-point flow of Cu-H2O nanofluid on a flat surface in a porous medium is examined. Moreover, the thermal radiation and viscous dissipation effects are considered. The problem governing partial differential equations are converted into self-similar coupled ordinary differential equations and those are numerically solved by the shooting method. The computed results can reveal many vital findings of practical importance. Firstly, dual solutions exist for decelerating unsteady flow and for accelerating unsteady and steady flows, the solution is unique. The presence of nanoparticles affects the existence of dual solution in decelerating unsteady flow only when the medium of the flow is a porous medium. But different shapes of nanoparticles are not disturbing the dual solution existence range, though it has a considerable impact on thermal conductivity of the mixture. Different shapes of nanoparticles act differently to enhance the heat transfer characteristics of the base fluid, i.e., the water here. On the other hand, the existence range of dual solutions becomes wider for a larger permeability parameter related to the porous medium. Regarding the cooling rate of the heated surface, it rises with the permeability parameter, shape factor (related to various shapes of Cu-nanoparticles), and radiation parameter. The surface drag force becomes stronger with the permeability parameter. Also, with growing values of nanoparticle volume fraction, the boundary layer thickness (BLT) increases and the thermal BLT becomes thicker with larger values of shape factor. For decelerating unsteady flow, the nanofluid velocity rises with permeability parameter in the case of upper branch solution and an opposite trend for the lower branch is witnessed. The thermal BLT is thicker with radiation parameter. Due to the existence of dual solutions, a linear stability analysis is made and it is concluded that the upper branch and unique solutions are stable solutions.  相似文献   
4.
Theoretical and Mathematical Physics - We discuss the gravitational collapse of a spherically symmetric perfect fluid distribution of uniformly contracting stars. In a uniformly contracting star,...  相似文献   
5.
Journal of Thermal Analysis and Calorimetry - In the case of flow boiling, the prediction of vapour fraction in the horizontal microchannel is a severe issue using the numerical technique....  相似文献   
6.
Russian Journal of General Chemistry - In the current study, some new quinoxaline linked 1,3,4-oxadiazole sulfonamide hybrids have been designed, synthesized and characterized by IR, 1H and 13C...  相似文献   
7.
Herein, we report a facile method for synthesizing MoCo-layered double hydroxide (LDH) nanosheets employing Prussian blue analog (PBA) as the precursor. The introduction of Mo in Co-LDH modulates the electronic structure, increases the number of active sites and electrochemical surface area to improve the hydrogen evolution, oxygen evolution, and overall water splitting activity. As a result, PBA-derived Mo0.25Co0.75-LDH nanosheets demonstrated 10 mA cm?2 current density at only 220 mV and 115 mV overpotentials for OER and HER, respectively. The overall water splitting was attained at 1.52 V cell voltage for 10 mA cm?2 current density.  相似文献   
8.
As the application of electrocatalyst continues to expand, envisaging the hidden mechanisms occurring at various length scale affecting the catalytic efficiency became important. To enhance the stability of electrocatalyst and reduce the cost, it is of paramount importance to reveal the active site's dynamics (using in situ techniques for getting the real-time information) which directly affect the reactions such as oxygen evolution reaction, hydrogen evolution reaction, and so on. Since such reactions are crucial for many engineering and scientific applications, in situ characterization techniques are required, which could capture such reactions happening at a different length and time scale. This article analyzes the recent progress made in the field of electrocatalyst's characterization using in situ neutron techniques. The article also paves the future path and has delineated the future challenges involved in multiscale correlative techniques (e.g., neutron techniques in the combination of synchrotron or microscopic techniques) used for getting the multiscale (atomic to micrometer range) mechanistic information about the electrocatalyst's working and degradation.  相似文献   
9.
This article studies a posteriori error analysis of fully discrete finite element approximations for semilinear parabolic optimal control problems. Based on elliptic reconstruction approach introduced earlier by Makridakis and Nochetto [25], a residual based a posteriori error estimators for the state, co-state and control variables are derived. The space discretization of the state and co-state variables is done by using the piecewise linear and continuous finite elements, whereas the piecewise constant functions are employed for the control variable. The temporal discretization is based on the backward Euler method. We derive a posteriori error estimates for the state, co-state and control variables in the $L^\infty(0,T;L^2(\Omega))$-norm. Finally, a numerical experiment is performed to illustrate the performance of the derived estimators.  相似文献   
10.
Controllable tailoring of metal-free/carbon-based nanostructures tends an encouraging way to enhance the bifunctional activity of electrodes, but a great challenge owing to the sluggish kinetics of oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Herein, a facile tempted-defects assisted fractionation strategy is presented to synthesize N, S, and O tri-doped metal-free catalyst (DE-TDAP). Due to this effective tempted-defects and heteroatoms interlinking in DE-TDAP, it delivers the lowest overpotential toward both the OER (346 mV) and HER (154 mV) at 10 mA cm?2. Remarkably, the DE-TDAP-electrode carries only a cell voltage of 1.81 V at 10 mA cm?2 for overall water splitting and long-term stability. Considerably, the density functional theory (DFT) calculation exposes that the tailored-defects in tri-doped interlinking could enhance bifunctional catalytic performance devising from lower Gibbs free energy of OER/HER intermediates on active sites. This struggle henceforth provides a perceptive understanding of the synergetic principles of heteroatom-interlinking-tailoring nanostructures in water splitting.  相似文献   
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