Nucleation and growth of Cu onto polycrystalline Pt electrode from acidic CuSO4 solution in the presence of H2SeO3

The early stages of Cu electrodeposition onto Pt(poly) have been investigated in 0.5 M H₂SO₄ + 0.01 M CuSO₄ solution without or with H₂SeO₃ when a molar concentration ratio [Cu(II)]/[Se(IV)] ≥ 2×10² using electrochemical and ex situ AFM techniques. The overpotential deposition of Cu has been performed onto a Pt surface precovered independently with Cu in amount close to an equivalent monolayer. Chronoamperometric results have been shown to follow an instantaneous 3D nucleation and diffusion-controlled growth model. The values of diffusion coefficient D for Cu²⁺, number of nuclei N and average nuclei radius r _av have been calculated. In the local regions of the surface, the separate large agglomerates composed of the different diameter clusters have been revealed in both cases, but, in the presence of the H₂SeO₃, they attained a distinct chain-like configuration. Some morphological characteristics have been reported.     

Limit theorems in the space of analytic functions for the Hurwitz zeta-function with an algebraic irrational parameter

We prove a limit theorem in the space of analytic functions for the Hurwitz zeta-function with algebraic irrational parameter.     

Limit theorems for the Mellin transform of the fourth power of the Riemann zeta-function

We prove limit theorems in the sense of weak convergence of probability measures on the complex plane as well as in the space of analytic functions for the Mellin transform of {ie88-01}     

A hybrid method for multidimensional scaling using city-block distances

The problem of multidimensional scaling with city-block distances in the embedding space is reduced to a two level optimization problem consisting of a combinatorial problem at the upper level and a quadratic programming problem at the lower level. A hybrid method is proposed combining randomized search for the upper level problem with a standard quadratic programming algorithm for the lower level problem. Several algorithms for the combinatorial problem have been tested and an evolutionary global search algorithm has been proved most suitable. An experimental code of the proposed hybrid multidimensional scaling algorithm is developed and tested using several test problems of two- and three-dimensional scaling.     

Universality of the Riemann zeta-function

In 1975, S.M. Voronin proved the universality of the Riemann zeta-function ζ(s). This means that every non-vanishing analytic function can be approximated uniformly on compact subsets of the critical strip by shifts ζ(s+iτ). In the paper, we consider the functions F(ζ(s)) which are universal in the Voronin sense.     

A hybrid global optimization algorithm for non-linear least squares regression

A hybrid global optimization algorithm is proposed aimed at the class of objective functions with properties typical of the problems of non-linear least squares regression. Three components of hybridization are considered: simplicial partition of the feasible region, indicating and excluding vicinities of the main local minimizers from global search, and computing the indicated local minima by means of an efficient local descent algorithm. The performance of the algorithm is tested using a collection of non-linear least squares problems evaluated by other authors as difficult global optimization problems.     

Approximation by generalized shifts of the Riemann zeta-function in short intervals

The Ramanujan Journal - We use the elliptic regulator to prove an identity between the Mahler measures of a genus 3 polynomial family and of a genus 1 polynomial family that was initially...     

New β-carotene-xylan complexes: preparation and characterization

Cellulose - The study aimed to propose a new system based on xylan for β-carotene delivery into aqueous environments. The xylan fraction of low molecular weight of...