污泥基吸附剂对亚甲基蓝和环丙沙星的吸附性能研究

亚甲基蓝和环丙沙星是水体中2种污染物, 对生态环境有潜在危害. 本文以市政剩余活性污泥为原料, 氯化锌为活化剂热解制备污泥基吸附剂, 研究盐酸酸洗浓度、氯化锌浓度、热解温度、热解时间等对污泥基吸附剂吸附水中亚甲基蓝和环丙沙星性能的影响. 结果表明 (1)污泥基吸附剂对亚甲基蓝的吸附性能随盐酸酸洗浓度的增大而增加, 对环丙沙星的吸附性能则随盐酸酸洗浓度的增大呈先降后增趋势, 两者均在1.500mol·L-1盐酸浓度下取得最优值. (2)污泥基吸附剂对亚甲基蓝和环丙沙星的吸附性能随氯化锌浓度和热解温度的增加呈先升后降趋势, 在氯化锌浓度为4.0mol·L-1、热解温度为500℃时有最优值; 随着热解时间的延长, 污泥基吸附剂对亚甲基蓝和环丙沙星的吸附性能分别在500℃热解70min和80min时有最优值. (3)污泥基吸附剂的最佳制备条件为 氯化锌4.0mol·L-1活化2h、500℃热解70min和80min、1.500mol·L-1盐酸酸洗; 以此制得的污泥基吸附剂对亚甲基蓝和环丙沙星的去除率分别为97.7%和96.4%, 平衡吸附量分别为97.9mg·g-1和3.9mg·g-1, 且污泥基吸附剂对亚甲基蓝和环丙沙星的吸附过程均符合准二级动力学方程.     

Fabric and connectivity as field descriptors for deformations in granular media

Granular materials involve microphysics across the various scales giving rise to distinct behaviours of geomaterials, such as steady states, plastic limit states, non-associativity of plastic and yield flow, as well as instability of homogeneous deformations through strain localization. Incorporating such micro-scale characteristics is one of the biggest challenges in the constitutive modelling of granular materials, especially when micro-variables may be interdependent. With this motivation, we use two micro-variables such as coordination number and fabric anisotropy computed from tessellation of the granular material to describe its state at the macroscopic level. In order to capture functional dependencies between micro-variables, the correlation between coordination number and fabric anisotropy limits is herein formulated at the particle level rather than on an average sense. This is the essence of the proposed work which investigates the evolutions of coordination number distribution (connectivity) and anisotropy (contact normal) distribution curves with deformation history and their inter-dependencies through discrete element modelling in two dimensions. These results enter as probability distribution functions into homogenization expressions during upscaling to a continuum constitutive model using tessellation as an abstract representation of the granular system. The end product is a micro-mechanically inspired continuum model with both coordination number and fabric anisotropy as underlying micro-variables incorporated into a plasticity flow rule. The derived plastic potential bears striking resemblance to cam–clay or stress–dilatancy-type yield surfaces used in soil mechanics.     

Micro–macro analysis of granular material behavior along proportional strain paths

When granular materials are subjected to proportional strain loading paths, they manifest a variety of behaviors depending on the initial void ratio of the specimen as well as the imposed dilatancy/contractancy rate. In some cases, the stress components may vanish over the duration of the test, and the specimen may progressively liquefy. To investigate this behavior, the authors have developed a kinematic approach to be deployed in two parts. First, numerical simulations are performed by means of a discrete element method. Secondly, two micromechanical models have corroborated the DEM results. The performance of these models may explain a number of microstructural mechanisms responsible for the macroscopic constitutive behavior.     

On the Irrotational Approximation to Adiabatic Chaplygin Gas Dynamic System

In this paper we mainly study the difference of the weak solutions generated by a wave front tracking algorithm for the steady adiabatic Chaplygin gas dynamic system and the steady irrotational system. Under the hypothesis that the initial data are of sufficiently small total variation, we prove that the difference between the solutions to these two systems can be bounded by the cube of the total variation of the initial perturbation.     

Hindman’s theorem and idempotent types

Motivated by a question of Di Nasso, we show that Hindman’s theorem is equivalent to the existence of idempotent types in countable complete extensions of Peano Arithmetic.     

A group of continuous self-maps on a topological groupoid

The group of bisections of groupoids plays an important role in the study of Lie groupoids. In this paper another construction is introduced. Indeed, for a topological groupoid G, the set of all continuous self-maps f on G such that (x, f(x)) is a composable pair for every \(x\in G\), is denoted by \(S_G\). We show that \(S_G\) by a natural binary operation is a monoid. \(S_G(\alpha )\), the group of units in \(S_G\) precisely consists of those \(f\in S_G\) such that the map \(x\mapsto xf(x)\) is a bijection on G. Similar to the group of bisections, \(S_G(\alpha )\) acts on G from the right and on the space of continuous self-maps on G from the left. It is proved that \(S_G(\alpha )\) with the compact- open topology inherited from C(G, G) is a left topological group. For a compact Hausdorff groupoid G it is proved that the group of bisections of \(G^2\) is isomorphic to the group \(S_G(\alpha )\) and the group of transitive bisections of G, \(Bis_T(G)\), is embedded in \(S_G(\alpha )\), where \(G^2\) is the groupoid of all composable pairs.     

Perturbations of positive semigroups on AM-spaces

We consider positive perturbations of positive semigroups on AM-spaces and prove a result which is the dual counterpart of a famous perturbation result of Desch in AL-spaces. As an application we present unbounded perturbations of the shift semigroup.     

Algebraic properties of Zappa–Szép products of semigroups and monoids

Direct, semidirect and Zappa–Szép products provide tools to decompose algebraic structures, with each being a natural generalisation of its predecessor. In this paper we examine Zappa–Szép products of monoids and semigroups and investigate generalised Greens relations \({\mathcal R}^{*},\, {\mathcal L}^{*},\, \widetilde{\mathcal {R}}_E\) and \(\widetilde{\mathcal {L}}_E\) for these Zappa–Szép products. We consider a left restriction semigroup S with semilattice of projections E and define left and right actions of S on E and E on S, respectively, to form the Zappa–Szép product \(E \bowtie S\). We further investigate properties of \(E \bowtie S\) and show that S is a retract of \(E\bowtie S\). We also find a subset T of \(E \bowtie S\) which is left restriction.     

A model-free noise removal for the interpolation method of correlation and spectral estimation from laser Doppler data

A procedure to estimate and remove the contribution of data noise to the correlation function and the power spectral density calculated from laser Doppler data with the interpolation method is introduced. In comparison with earlier approaches, the new procedure is model free and, therefore, more objective. The new procedure is proven based on experimental data taken with a laser Doppler system, where the power spectral density obtained with the interpolation method is compared directly to data from a hot-wire reference measurement.