Molecular Diversity - The pandemic outbreak of the Corona viral infection has become a critical global health issue. Biophysical and structural evidence shows that spike protein possesses a high... 相似文献
The wake characteristics of a custom-designed airfoil performing pitching oscillations, heaving oscillations, and a combination of pitch and heave oscillations are compared in this study. The influence of flapping parameters are investigated at a constant Reynolds number Re\(_{c} = 2640\) and is presented for the Strouhal numbers based on the oscillation amplitude, StA, varying in the \(0.1 \leqslant {\text{S}}{{{\text{t}}}_{A}} \leqslant 0.4\) range. The generation of vorticity above and below the airfoil depends on the airfoil’s initial direction of motion and remains the same for all types of flapping oscillations investigated. The evolution of the leading-edge and trailing-edge vortices is presented. The heaving oscillations of the airfoil are found to have a greater influence on the characteristics of the leading edge vortex. The wake behind the combined pitch-heave oscillations appears to be governed by pitching oscillations below \({\text{S}}{{{\text{t}}}_{A}} = 0.24\), whereas it is driven by heaving oscillations above \({\text{S}}{{{\text{t}}}_{A}} = 0.24\). The force computations indicate that the mere existence of the reverse von Kármán street is not sufficient to develop the thrust on the airfoil. The periodic component of velocity fluctuations significantly influences the wake characteristics. The anisotropic stress field developed around the airfoil due to the periodic fluctuations of the velocity is presented. The coherent structures developed in the wake are identified using the proper orthogonal decomposition and a qualitative comparison of the structures for different flapping oscillations is presented. The energy transfer from the flapping airfoil to the fluid for different flapping oscillations is highest for heaving oscillations followed by combined pitch-heave oscillations and pitching oscillations.
We have characterized a sulfobetaine stationary phase based on 1.7 μm ethylene-bridged hybrid organic–inorganic particles, which is intended for use in hydrophilic interaction chromatography. The efficiency of a column packed with this material was determined as a function of flow rate, demonstrating a minimum reduced plate height of 2.4. The batch-to-batch reproducibility was assessed using the separation of a mixture of acids, bases, and neutrals. We compared the retention and selectivity of the hybrid sulfobetaine stationary phase to that of several benchmark materials. The hybrid sulfobetaine material gave strong retention for polar neutrals and high selectivity for methyl groups, hydroxy groups, and configurational isomers. Large differences in cation and anion retention were observed among the columns. We characterized the acid and base stability of the hybrid sulfobetaine stationary phase, using accelerated tests at pH 1.3 and 11.0, both at 70°C. The results support a recommended pH range of 2–10. We also investigated the performance of columns packed with this material for metal-sensitive analytes, comparing conventional stainless steel column hardware to hardware that incorporates hybrid surface technology to mitigate interactions with metal surfaces. Compared to the conventional columns, the hybrid surface technology columns showed a greatly improved peak shape. 相似文献
Nelumbo nucifera leaves are rich source of natural wax possessing super-hydrophobic properties. It provides protection to them from ecological turbulences and climatic wear and tear. In this study, various experiments have been conducted to observe the yield of extraction and the determination of various functional groups, which are present in natural wax, derived from Nelumbo nucifera leaves. The natural wax has been extracted from lotus leaves through non-polar (hexane) and polar (ethanol) solvent via different extraction methods. The superhydrophobic wax has been successfully extracted with hexane. Whereas, ethanol did not extract the water-repellent wax of lotus leaf. Considering the cumulative amount, i.e. (desired + undesired), the maceration shows the extraction of 2.9% (%w/w, through hexane) and 10.2% (%w/w, through ethanol), while it was found 2.5% (%w/w, cycle period 15 min) and 9.0% (%w/w, cycle period 26 min) respectively, in case of Soxhlet extraction technique. For this specific case of natural wax recovery from biomass (lotus leaf), the maceration (traditional method) resulted a little bit superior extraction yield in comparison to the Soxhlet extraction method for extraction of crude wax. In the case of non-polar solvent (hexane), an extraction yield of 1.97% (%w/w) through maceration method was observed while in the case of non-polar solvent (ethanol), an extraction yield of 1.62% (%w/w) through Soxhlet extraction was observed. The TLC analysis on both types of extracts was performed. For the detection of various hydrocarbon chains in the crude wax extracts, FTIR was also performed. Topography of wax surface and wax-coated waterproof fabric was compared through SEM. 相似文献
Herein, we report a Mott-Schottky catalyst by entrapping cobalt nanoparticles inside the N-doped graphene shell (Co@NC). The Co@NC delivered excellent oxygen evolution activity with an overpotential of merely 248 mV at a current density of 10 mA cm–2 with promising long-term stability. The importance of Co encapsulated in NC has further been demonstrated by synthesizing Co nanoparticles without NC shell. The synergy between the hexagonal close-packed (hcp) and face-centered cubic (fcc) Co plays a major role to improve the OER activity, whereas the NC shell optimizes the electronic structure, improves the electron conductivity, and offers a large number of active sites in Co@NC. The density functional theory calculations have revealed that the hcp Co has a dominant role in the surface reaction of electrocatalytic oxygen evolution, whereas the fcc phase induces the built-in electric field at the interfaces with N-doped graphene to accelerate the H+ ion transport. 相似文献
Journal of Thermal Analysis and Calorimetry - Phthalonitrile (PN) resins are high-temperature-resistant thermosetting polymers which find applications in military as well as aerospace owing to... 相似文献
Molecular Diversity - The latest global outbreak of 2019 respiratory coronavirus disease (COVID-19) is triggered by the inception of novel coronavirus SARS-CoV2. If recent events are of any... 相似文献
The Ramanujan Journal - For a positive integer $$\ell $$ , let $$b_{\ell }(n)$$ denote the number of $$\ell $$ -regular partitions of a nonnegative integer n. Motivated by some recent conjectures... 相似文献