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1.
磨盘材料和温度对TC11合金磨损行为的影响   总被引:2,自引:2,他引:0  
对TC11合金与两种不同硬度的GCr15和W6Mo5Cr4V2在25、400和600℃对摩时的磨损行为进行了研究.利用SEM、EDS以及XRD等对试样磨面和剖面的形貌、成分及结构进行了观察与分析.结果表明:TC11合金与三种不同硬度的磨盘对摩后,在25℃,磨损率均随载荷的增加而增加,且磨损率较高,磨损表面呈现黏着和犁沟特征,磨损机理为黏着磨损与磨粒磨损;在400℃,合金与低硬度GCr15对摩时,磨损表面被黑色光滑氧化物所覆盖,磨损机理为氧化轻微磨损;与高硬度GCr15对摩时,在50和150 N,磨损表面呈现黑色光滑氧化物和犁沟特征,磨损机理为氧化轻微磨损和磨粒磨损;在250 N,磨损机理为黏着磨损与磨粒磨损;与W6Mo5Cr4V2对摩时,磨损表面呈现犁沟特征,磨损机理为磨粒磨损;在600℃,TC11合金的磨损率均较低,且与两种不同硬度GCr15对摩后的磨损率均低于与W6Mo5Cr4V2对摩的磨损率,磨损机理均为氧化轻微磨损.在25和600℃,磨盘材料对合金的磨损率具有不同的影响,但不影响合金的磨损机理;在400℃,磨盘材料既影响磨损率也影响磨损机理.  相似文献   
2.
We show that the eigenfunctions of Kohn-Sham equations can be decomposed as ■ = F ψ, where F depends on the Coulomb potential only and is locally Lipschitz, while ψ has better regularity than ■.  相似文献   
3.
In the pH 7.4 Na2HPO4‐NaH2PO4 buffer solution, the cationic surfactant (CS) interacted with nanogold particles (NG) to form NG aggregations (NGA) that resulted in its color changing from wine red to blue‐violet. NG has a strong catalysis on the formic acid‐phosphomolybdic acid (PMo) colored reaction, but that of the NGA catalysis is weak. With the increase of CS concentration, the NGA increased and the NG decreased, the catalysis decreased and the absorption value at 700 nm decreased linearly. The concentrations of 6.25–250 nmol/L tetradecyl dimethyl benzyl ammonium chloride (TDBAC), 0.625–250 nmol/L cetyltrimethyl ammonium bromide (CTMAB) and 12.5–500 nmol·L?1 dodecyldimethylbenzyl ammonium chloride (DDBAC) had good linear responses to the decreased absorption value (ΔA700 nm), with molar absorption coefficients of 2.2×106, 2.1×106 and 9×105 L·mol?1·cm?1 respectively. This method was simple, highly sensitive and low‐cost.  相似文献   
4.
软体驱动器是构建智能软体机器人的基石。然而,由于软体驱动器具有非线性、耦合和不确定性等复杂的特性,如何对其进行有效建模与控制是目前极需解决的难题。以一种由三支单腔双向弯曲软驱动器构成的软体微手为研究对象,对其进行了鲁棒非线性控制设计研究。首先,进行了鲁棒非线性控制系统的总体结构设计分析。其次,对如何设计算子控制器、跟踪控制器、算子观测器实现其对软体微手的弯曲角度和力进行控制进行了分析和讨论。接着,分析和研究了鲁棒稳定和跟踪条件。最后,通过基于实验数据的仿真验证了所提方案的可行性和有效性。  相似文献   
5.
The AucoreAgshell (Au@Ag) nanoparticles in size of 30 nm were prepared using 10 nm gold nanoparticles as seeds at 90°C, and were purified by high-speed centrifugation to remove the excess trisodium citrate to obtain Au@Ag nanoprobe. In the medium of pH 4.0 acetate buffer solution—7.2 μmol/L H2O2–67 μmol/L Fe(II), Au@Ag nanoparticles exhibited a resonance scattering (RS) peak at 538 nm. Upon addition of Catalase (Ct), the system produced hydroxyl radical that oxidized the Au@Ag nanoprobe to form the AuAg nanoparticles with partly bare nanogold. Those AuAg nanoparticles aggregated to large nanoclusters that led to the RS peak wavelength red-shift and its RS peak intensity enhanced. The catalase activity (C) is linear to the enhanced RS intensity (ΔI) in the range of 6 to 2,800 U/L, with regression equation of ΔI = 0.168 C-0.2, the correlation coefficient of 0.9952, and detection limit of 2.8 U/L. This method was applied to the detection of serum samples, and the results were agreement with that of the spectrophotometry. A new catalytic mechanism of catalase was proposed with oxywater principle that was agreement with the results of resonance scattering spectroscopy, absorption spectrophotometry, transmission electron microscopy and laser scattering.  相似文献   
6.
In this paper, some local and parallel discretizations and adaptive finite element algorithms are proposed and analyzed for nonlinear elliptic boundary value problems in both two and three dimensions. The main technique is to use a standard finite element discretization on a coarse grid to approximate low frequencies and then to apply some linearized discretization on a fine grid to correct the resulted residual (which contains mostly high frequencies) by some local/parallel procedures. The theoretical tools for analyzing these methods are some local a priori and a posteriori error estimates for finite element solutions on general shape-regular grids that are also obtained in this paper.  相似文献   
7.
8.
We give here an overview of the orbital-free density functional theory that is used for modeling atoms and molecules.We review typical approximations to the kinetic energy,exchange-correlation corrections to the kinetic and Hartree energies, and constructions of the pseudopotentials.We discuss numerical discretizations for the orbital-free methods and include several numerical results for illustrations.  相似文献   
9.
用15 nm的纳米金标记羊抗人铜蓝蛋白抗体(GCP)可获得铜蓝蛋白(CP)纳米金探针(AuGCP). 在pH 7.8柠檬酸-磷酸氢二钠缓冲溶液中, CP与AuGCP发生特异性结合生成胶体金免疫复合物. 离心分离后, 离心液中的AuGCP可作为酒石酸铜(C4H4O6Cu)-葡萄糖反应体系的催化剂, 生成的Cu2O微粒在620 nm处有一共振散射峰. 在选定条件下, 620 nm处共振散射信号降低值△I620 nm与铜蓝蛋白浓度cCP在0.18~45 ng/mL范围内存在良好线性关系, 回归方程为 ΔI620 nm=2.27cCP+5.05, 相关系数为0.9940, 检出限为0.14 ng/mL. 该法用于人血清中铜蓝蛋白的检测, 结果满意.  相似文献   
10.
In this paper, a two-scale higher-order finite element discretization scheme is proposed and analyzed for a Schroedinger equation on tensor product domains. With the scheme, the solution of the eigenvalue problem on a fine grid can be reduced to an eigenvalue problem on a much coarser grid together with some eigenvalue problems on partially fine grids. It is shown theoretically and numerically that the proposed two-scale higher-order scheme not only significantly reduces the number of degrees of freedom but also produces very accurate approximations.  相似文献   
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