Magnetohydrodynamic natural convection of hybrid nanofluid in a porous enclosure: numerical analysis of the entropy generation

Journal of Thermal Analysis and Calorimetry - The effect on the entropy production and MHD convection of the hybrid nanofluid Al2O3–Cu/water (water with Cu and Al2O3 nanoparticles) in a...     

Dirichlet product for boolean functions

Boolean functions play an important role in many symmetric cryptosystems and are crucial for their security. It is important to design boolean functions with reliable cryptographic properties such as balancedness and nonlinearity. Most of these properties are based on specific structures such as Möbius transform and Algebraic Normal Form. In this paper, we introduce the notion of Dirichlet product and use it to study the arithmetical properties of boolean functions. We show that, with the Dirichlet product, the set of boolean functions is an Abelian monoid with interesting algebraic structure. In addition, we apply the Dirichlet product to the sub-family of coincident functions and exhibit many properties satisfied by such functions.     

Analytical model for thermal resistance due to multiple moving circular contacts on a coated bodyModèle analytique pour la résistance thermique due à des contacts circulaires mobiles multiples à la surface d'un solide revêtu

The heat transfer at the interface of two solids in sliding/rolling contact depends on the constriction phenomenon which occurs at the vicinity of asperities. In order to study this problem, the micro-contacts are represented by multiple moving circular heat sources on the surface of a body. The studied body is constituted of a substrate and a surface coating. The thermal constriction resistance due to those contacts is determined analytically in this paper. The solution is developed by using the integral Fourier transforms, and it is valid regardless of the velocity and the relative contact size values. To cite this article: A. Baïri, C. R. Mecanique 331 (2003).     

Direct Evidence for Intermolecular Oxidative Addition of σ(SiSi) Bonds to Gold

Oxidative addition plays a major role in transition‐metal catalysis, but this elementary step remains very elusive in gold chemistry. It is now revealed that in the presence of GaCl₃, phosphine gold chlorides promote the oxidative addition of disilanes at low temperature. The ensuing bis(silyl) gold(III) complexes were characterized by quantitative ³¹P and ²⁹Si NMR spectroscopy. Their structures (distorted Y shape) and the reaction profile of σ(Si? Si) bond activation were analyzed by DFT calculations. These results provide evidence for the intermolecular oxidative addition of σ(Si? Si) bonds to gold and open promising perspectives for the development of new gold‐catalyzed redox transformations.     

Enhanced π‐Backdonation from Gold(I): Isolation of Original Carbonyl and Carbene Complexes

The specific electronic properties of bent o‐carborane diphosphine gold(I) fragments were exploited to obtain the first classical carbonyl complex of gold [(DPCb)AuCO]⁺ (ν(CO)=2143 cm^?1) and the diphenylcarbene complex [(DPCb)Au(CPh₂)]⁺, which is stabilized by the gold fragment rather than the carbene substituents. These two complexes were characterized by spectroscopic and crystallographic means. The [(DPCb)Au]⁺ fragment plays a major role in their stability, as substantiated by DFT calculations. The bending induced by the diphosphine ligand substantially enhances π‐backdonation and thereby allows the isolation of carbonyl and carbene complexes featuring significant π‐bond character.     

MCNP Dose Calculations in a CT Phantom for Therapeutic External Photon Beam

In this paper, we have addressed the problem of the radiation transport with the Monte Carlo N particle(MCNP) code. This is a general purpose Monte Carlo tool designed to transport neutron, photon and electron in three dimensional geometries. To examine the performance of MCNP5 code in the field of external radiotherapy, we performed the modeling of an Electron Density phantom (EDP) irradiated by photons from 60Co source. The model was used to calculate the Percent Depth Dose (PDD) at different depths in an EDP. One field size for PDD has been examined. A 60Co photons source placed at 80 cm source to surface distance (SSD). The results of calculations were compared to TPS data obtained at National Institute of Oncology of Rabat.     

Flavouring and odorant thiols from renewable natural resources by In-catalysed hydrothioacetylation and lipase-catalysed solvolysis

A chemoenzymatic access to thiol compounds, including ethyl 3-thiobutanoate, 3-thio-p-menthene and 8-thio-p-menthan-2-one, three compounds of interest in flavour and fragrance chemistry presenting various fruity notes, is proposed. It involves an indium(III)-catalysed hydrothioacetylation of renewable precursors followed by an enzymatic solvolysis of the obtained thioesters by lipases in aqueous or organic solvents.