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1.
We give a characterization of the cyclic subgroup separability and weak potency of the fundamental group of a graph of polycyclic-by-finite groups and free-by-finite groups amalgamating edge subgroups of the form × D,where h has infinite order and D is finite. 相似文献
2.
Dongyoon Shin Sabita Bhandari Marc FTesch Shannon ABonke Frédéric Jaouen Sonia Chabbra Christoph Pratsch Alexander Schnegg Anna K.Mechler 《Journal of Energy Chemistry》2022,(2)
The incorporation of Pt into an iron-nitrogen-carbon(Fe NC)catalyst for the oxygen reduction reaction(ORR)was recently shown to enhance catalyst stability without Pt directly contributing to the ORR activity.However,the mechanistic origin of this stabilisation remained obscure.It is established herein with rotating ring disc experiments that the side product,H2O2,which is known to damage FeNC catalysts,is suppressed by the presence of Pt.The formation of reactive oxygen species is additionally inhibited,independent of intrinsic H2O2 formation,as determined by electron paramagnetic resonance.Transmission electron microscopy identifies an oxidised Fe-rich layer covering the Pt particles,thus explaining the inactivity of the latter towards the ORR.These insights develop understanding of Fe NC degradation mechanisms during ORR catalysis,and crucially establish the required properties of a precious metal free protective catalyst to improve Fe NC stability in acidic media. 相似文献
3.
The characteristics of heat transfer in the three-dimensional stagnationpoint flow past a stretching/shrinking surface of the Al_2O_3-Cu/H_2O hybrid nanofluid with anisotropic slip are investigated. The partial differential equations are converted into a system of ordinary differential equations by valid similarity transformations. The simplified mathematical model is solved computationally by the bvp4c approach in the MATLAB operating system. This solving method is capable of generating more than one solutions when suitable initial guesses are proposed. The results are proven to have dual solutions, which consequently lead to the application of a stability analysis that verifies the achievability of the first solution. The findings reveal infinite values of the dual solutions at several measured parameters causing the non-appearance of the turning points and the critical values. The skin friction increases with the addition of nanoparticles, while the escalation of the anisotropic slip effect causes a reduction in the heat transfer rate. 相似文献
5.
Gustavo A.Carri 《高分子科学》2015,33(4):523-539
We revisit the Simha-Somcynsky model of polymer fluids with the purpose of developing novel theoretical and computational approaches to simplify and speed up its solution as well as the fitting of experimental data, and decrease its level of mathematical complexity. We report a novel method that allows us to solve one of the two equations of the model exactly, thus putting the level of mathematical difficulty on a par with the one of other models for polymer fluids. Moreover, we describe a computational algorithm capable of fitting all five parameters of the model in an unbiased way. The results obtained reproduce literature results and fit experimental pressure-volume-temperature and solubility parameter data for three polymers very accurately. Moreover, the new techniques allow for the investigation of the model at very low temperatures. Unexpectedly, the model predicts behaviors that could be interpreted as a glass transition, as routinely observed in dilatometry and differential scanning calorimetry, and a glass phase. We compared the predicted and experimental T g’s for cis poly(1,4-butadiene) and found an excellent quantitative agreement. 相似文献
6.
L.V.Zhukova D.D.Salimgareev A.E.Lvov A.A.Yuzhakova A.S.Korsakov D.A.Belousov K.V.Lipustin V.M.Kondrashin 《中国光学快报(英文版)》2021,(2):51-56
The article is devoted to the technology for obtaining optical ceramics of Ag Br-Tl I and Ag Br-Tl Br0.46I0.54 systems and manufacturing samples with different compositions.The new heterophase crystal ceramics are transparent without absorption windows in the spectral range from 1.0 to 60.0μm.In the ceramics’transparency spectra based on the Ag Br-Tl I and Ag Br-Tl Br0.46I0.54 systems fusibility diagrams,with an increase in the thallium halides mass fraction,as well as the replacement of the bromine ion with iodine,the maximum transparency shifts to a long infrared region. 相似文献
7.
Yunliang Liu Peiji Deng Ruqiang Wu Ramadan A. Geioushy Yaxi Li Yixian Liu Fengling Zhou Haitao Li Chenghua Sun 《Frontiers of Physics》2021,16(5):53503
The large-scale production of ammonia mainly depends on the Haber–Bosch process, which will lead to the problems of high energy consumption and carbon dioxide emission. Electrochemical nitrogen fixation is considered to be an environmental friendly and sustainable process, but its efficiency largely depends on the activity and stability of the catalyst. Therefore, it is imperative to develop highefficient electrocatalysts in the field of nitrogen reduction reaction (NRR). In this paper, we developed a BiVO4/TiO2 nanotube (BiVO4/TNT) heterojunction composite with rich oxygen vacancies as an electrocatalytic NRR catalyst. The heterojunction interface and oxygen vacancy of BiVO4/TNT can be the active site of N2 dynamic activation and proton transition. The synergistic effect of TiO2 and BiVO4 shortens the proton transport path and reduces the over potential of chemical reaction. BiVO4/TNT has high ammonia yield of 8.54 μg·h−1·cm−2 and high Faraday efficiency of 7.70% in −0.8 V vs. RHE in 0.1 M Na2SO4 solution. 相似文献
8.
The flow behavior in non-parallel walls is an important factor of any physical model including cavity flow and canals, which is applicable for diverging/converging channel. The present communication explains that the flow of the hybrid nanomaterial subjected to the convergent/divergent channel has non-parallel walls. It is assumed that the hybrid nanomaterial movement is in the porous region. A Darcy-Forchheimer medium of porosity is considered to interpret the porosity features. A useful similarity function is adopted to get the strong ordinary coupled equations. Numerical solutions are achieved through the Runge-Kutta-Fehlberg(RKF) fourth-fifth order method, and they are validated with the existing results. Physical nature of the involving constraints is reported with the help of plots. It is explored that the velocity of divergent channel decreases, and convergent channel enhances for the higher solid volume faction. Further, the presence of inertia coefficient and porosity parameter amplifies the velocity at the wall. 相似文献
9.
Ludwin A.BASILIO-HERNáNDEZ Walter CARBALLOSA Jesús LEA?OS José M.SIGARRETA 《数学学报(英文版)》2019,35(3):338-354
We introduce the differential polynomial of a graph. The differential polynomial of a graph G of order n is the polynomial B(G; x) :=∑?(G)k=-nB_k(G) x~(n+k), where B_k(G) denotes the number of vertex subsets of G with differential equal to k. We state some properties of B(G;x) and its coefficients.In particular, we compute the differential polynomial for complete, empty, path, cycle, wheel and double star graphs. We also establish some relationships between B(G; x) and the differential polynomials of graphs which result by removing, adding, and subdividing an edge from G. 相似文献
10.
In this paper certain classes of meromorphic functions in punctured unit disk are defined. Some properties including coefficient inequalities, convolution and other results are investigated. 相似文献