Theoretical study on the mechanism for the excited-state double proton transfer process of an asymmetric Schiff base ligand

Excited-state double proton transfer (ESDPT) in the 1-[(2-hydroxy-3-methoxy-benzylidene)-hydrazonomethyl]-naphthalen-2-ol (HYDRAVH₂) ligand was studied by the density functional theory and time-dependent density functional theory method. The analysis of frontier molecular orbitals, infrared spectra, and non-covalent interactions have cross-validated that the asymmetric structure has an influence on the proton transfer, which makes the proton transfer ability of the two hydrogen protons different. The potential energy surfaces in both S₀ and S₁ states were scanned with varying O-H bond lengths. The results of potential energy surface analysis adequately proved that the HYDRAVH₂ can undergo the ESDPT process in the S₁ state and the double proton transfer process is a stepwise proton transfer mechanism. Our work can pave the way towards the design and synthesis of new molecules.     

CdS/Si nanofilm heterojunctions based on amorphous silicon films:Fabrication,structures,and electrical properties

Shortening the distance between the depletion region and the electrodes to reduce the trapped probability of carriers is a useful approach for improving the performance of heterojunction.The CdS/Si nanofilm heterojunctions are fabricated by using the radio frequency magnetron sputtering method to deposit the amorphous silicon nanofilms and Cd S nanofilms on the ITO glass in turn.The relation of current density to applied voltage(I-V)shows the obvious rectification effect.From the analysis of the double logarithm I-V curve it follows that below~2.73 V the electron behaviors obey the Ohmic mechanism and above~2.73 V the electron behaviors conform to the space charge limited current(SCLC)mechanism.In the SCLC region part of the traps between the Fermi level and conduction band are occupied,and with the increase of voltage most of the traps are occupied.It is believed that Cd S/Si nanofilm heterojunction is a potential candidate in the field of nano electronic and optoelectronic devices by optimizing its fabricating procedure.     

Measurements of the Cross-sections of Produced Short-Lived Nuclei Induced by Neutrons around 14 MeV on Isotopes of Tungsten

New experimental cross-section data for the180 W(n,2 n)179 mW,186 W(n,2 n)185 mW and186 W(n,p)186 Ta reactions at the neutron energies of 13.5 and 14.4 MeV are obtained by the activation technique. The neutron beams are produced by means of the3 H(d,n)4 He reaction. The gamma activities of the product nuclei are measured by a high-resolution gamma-ray spectrometer with a coaxial high-purity germanium detector. The neutron fluence is determined using the monitor reaction93 Nb(n,2 n)92 mNb. The results in the current work are discussed and compared with the measurement results found in the literature. It is shown that these higher accuracy experimental cross-section data around the neutron energy of 14 MeV agree with some previous experimental values from the literature within experimental uncertainties.     

一种新型苯并咪唑-酰腙衍生物用于比色和荧光识别F~-和AcO~-

合成出了1个新的苯并咪唑-酰腙衍生物,N'-(2-羟基-1-萘基)亚甲基-2-[2-(4-甲基苯磺酰基甲基)-1H-苯并咪唑-1-基]乙酰肼(L),并利用IR,~1H NMR,~(13)C NMR,HRMS和元素分析对其结构进行了表征.利用裸眼、紫外-可见与荧光光谱研究了L对阴离子的识别性能.研究结果表明,向化合物L的CH_3CN溶液中加入F~-,Ac O~-和H _2PO_4~-后,溶液由无色变为亮黄色.在紫外灯下(λ=365 nm),加入F~-和AcO~-后,L的溶液发射出黄色荧光.表明化合物L可作为裸眼识别F~-,AcO~-和H_2PO_4~-的探针.紫外和荧光光谱实验结果显示,探针L可高选择性和高灵敏性识别F~-和AcO~-.探针L与F~-和AcO~-的结合常数(K_a)分别为4.25×10~3和2.96×10~4 L·mol~(-1),检出限(DL)分别为3.63×10~(-7)和8.51×10~(-8) mol·L~(-1).Job曲线和密度泛函理论(DFT)计算证明,探针L与F~-/AcO~-是1∶1配位.通过~1H NMR滴定确定了探针L与F~-/Ac O~-的络合机理.实验结果表明,化合物L可作为检测F~-和AcO~-的比色和荧光探针.     

胶体金修饰电极测定鱼样中组胺的方法研究

基于胶体金修饰的玻碳电极,利用电流～时间曲线法建立了一种简便、灵敏的组胺检测方法。优化了底液的pH值和组胺的电化学测试方法及条件,考察了修饰电极的电化学性能。结果表明,组胺在胶体金修饰电极上的响应电流(-I,μA)与其浓度(c,μmol/L)在0. 1～64μmol/L范围内呈良好的线性关系,检出限为0. 033μmol/L,在带鱼和黄花鱼样品中的加标回收率分别为94. 4%～106%、91. 8%～106%,相对标准偏差分别为3. 2%、2. 5%。该法操作简单、检测速度快、成本低,适用于带鱼和黄花鱼等鱼样中组胺的测定。     

电阻率与强度性能的关联及铜合金性能分区

铜合金以低电阻率为特征,由于电阻率与强度存在着共同的微观结构机理,两者往往协同变化,而导致难以对合金进行性能的全面评估和选材.本文以Cu-Ni-Mo合金作为研究对象,以团簇结构[Mo_1-Ni_(12)]构建固溶体的近程序结构模型,解析了电阻率和强度依赖于成分的定量变化规律,并定义了拉伸强度/电阻率的值为代表合金本质特性的"强阻比",得到了完全固溶态Cu-Ni-Mo合金的强阻比为7×10~8MPa/?·m,完全析出态的强阻比为(310—490)×10~8MPa/?·m.进而应用强阻比对常用铜合金进行了性能分区,给出铜合金材料选材的依据,得出了基于Cu-(Cr, Zr, Mg, Ag, Cd)等二元基础体系的铜合金适用于高强高导应用,而基于Cu-(Be, Ni, Sn, Fe, Zn, Ti, Al)等为基础二元体系的铜合金不能实现高强高导.该强阻比为310的特征性能分界线的发现为合金性能的全面评估提供了量化依据,可指导高强高导铜合金的选材和研发.     

Er3+单掺、Er3+/Yb3+共掺杂Ca12Al14O32F2的 制备及上转换发光性质

利用高温固相法成功制备了Er~(3+)单掺、Er~(3+)/Yb~(3+)共掺杂Ca_(12)Al_(14)O_(32)F_2上转换发光样品。在980 nm激光激发下,Er~(3+)单掺和Er~(3+)/Yb~(3+)共掺杂样品均呈现出较强的绿光(528,549 nm)和较弱的红光(655 nm)发射,分别归因于Er~(3+)离子的~2H_(11/2),~4S_(3/2)→~4I_(15/2)和~4F_(9/2)→~4I_(15/2)能级跃迁。随着Er离子浓度的增加,单掺杂样品上转换发光强度先增大后减小,最佳掺杂浓度为0.8%。共掺杂Yb~(3+)后,Er~(3+)的发光强度明显增大。还原气氛下合成的样品上转换发光强度增大约两倍,可能和笼中阴离子基团变化有关。发光强度和激发光功率的关系表明所得上转换发射为双光子吸收过程,借助Er~(3+)-Yb~(3+)体系能级结构详细讨论了上转换发射的跃迁机制。     

高温环境下结构模态试验技术

由于高超声速飞行器长时间在大气层内工作会面临恶劣的气动热环境,飞行器结构地面模态试验必须考虑高温影响,但高温环境下结构模态试验远比常规试验复杂,目前仍存在很多技术难点亟待解决.本文首先对高温环境下的结构模态试验技术国内外发展现状进行了综述,详细分析了现有的高温环境下结构模态试验中的激励力与振动响应测量技术的特点及适用性,最后展望了高温环境下结构热模态试验技术的发展方向和研究重点.     

组织忘却对组织惰性的影响研究—–环境动态性与创新导向的调节作用

组织惰性是客观存在于组织机体内的消极行为表现, 对组织的可持续发展产生阻碍作用. 如何克服组织惰性、提升组织效率是组织惰性研究的关键问题. 本文主要探讨了组织忘却对组织惰性的影响作用. 以长三角地区的260个调查样本为研究对象, 对组织忘却与组织惰性的关系进行了分析, 并探讨了环境动态性、创新导向以及环境动态性和创新导向交互在两者之间的调节作用. 结果表明 组织忘却对组织惰性具有显著的负向作用, 环境动态性和创新导向均显著正向地调节了两者之间的负向作用, 环境动态性和创新导向的交互对两者之间的关系具有调节作用, 但调节作用最强的情况出现在环境动态性或创新导向单方面较强, 而非环境动态性和创新导向两者均强时.