[Co(en)_3][Fe(CN)_6]·H_2O的磁性研究

合成了氰根桥联配合物[Co(en)3][Fe(CN)6]·H2O,使用元素分析、红外光谱等对配合物进行了表征。首次通过对该配合物的磁化率测定表明金属离子通过氰根传递弱反铁磁作用,计算求得分子磁体有效磁距μeff的实验值与理论值。并根据Curie-Weiss定律拟合获得居里常数C=0.45968emu·K/mol,顺磁居里温度θ=-8.23117K。     

余代数上余倾斜余模的结构

研究了余代数上余倾斜余模的结构特征,证明了每个余倾斜余模都可以写成不可分解的两两非同构的余模的直和形式,每个余倾斜余模包含所有的内射不可分解模作为直和项.最后构造了余倾斜余模的两个例子.     

A Mossbauer study of the magnetic coupling in iron phosphorous trisulfides

The polycrystalline sample of layered compound FePS_3 has been investigated by using M?ssbauer spectroscopy (12K to 300K), magnetic susceptibility measurements, x-ray diffraction and FTIR spectroscopy. The antiferromagnetic order exists below T_N=120.5±1K. The M?ssbauer spectra below T_N indicate that the magnetization axis is perpendicular to the layer of FePS_3, and the divalent iron cations are in their high spin configurations. By fitting the hyperfine field parameters near the Néel temperature, we obtain information on the nature of magnetic interactions in the material. The results show that the magnetic coupling can be treated by the two-dimensional Ising model, and it can be interpreted on the basis of a crystal-field effect.     

Moessbauer Investigation of the Ferromagnetic Coupling in Copper-Iron Polycyanides

One of the Prussian blue analogs, molecular magnet Cu3^Ⅲ [Fe^Ⅲ (CN)6]2.11.6H2 O, was investigated by Moessbauer spectroscopy. It was found that transition temperature was around Tc = 18.5 K from paramagnetic phase to ferromagnetic phase. The β value of the critical exponent is around 0.338 at magnetic ordering temperature.Therefore, the ferromagnetic coupling interaction of Cu-Fe cyanide could be clearly explained by spin wave theory.     

研究热流体的13速格子Bhatnagar-Gross-Krook模型

采用13速六方格子BhatnagarGrossKrook模型研究热流体力学.在根据Fourier热导定律确定局域平衡分布函数的系数时,可引入参数k,使热导系数λ=(2ρ+9k)(τ-12),切粘滞系数与热导系数之比的Prandtl数不再局限于常数1/2,从而扩大了模型的应用范围该模型可用于高雷诺数的热流体的模拟. 关键词：     

基于九速四方格子模型的二维对流扩散方程格子Boltzmann方法模拟

用九速正方格子模型给出了二维对流扩散方程的格子Boltzmann方法。由对流扩散方程的对流系数和扩散系数确定了局域平衡分布函数的系数。计算机模拟结果与理论结果吻合很好。     

基于九速四方格子模型的二维对流扩散方程格子Boltzmann方法模拟

用九带正方格子模型给出了二维对流扩散方程的格子Ｂｏｌｔｚｎａｎｎ方法,由对流扩散方程的对流系数的扩散系数确定了局域平衡分布函数的系数。计算机模拟结果与理论结果吻合很好。     

γ辐射多层组合屏蔽设计的仿真研究——Monte Carlo方法模拟

运用蒙特卡罗(Monte Carlo)方法,模拟研究七种γ辐射非均匀屏蔽组合(碳-硫,硼-硅,硅-铅,硫-铝,锂-铝,铝-铅,锂-铁)的防护性能,通过编写MCNP程序来计算防护屏蔽的透射率,并对比各种组合方法的优劣,进而确定最佳方案。同时对非均匀防护屏蔽模拟与理论、实验三者进行比较分析,说明三者结论的一致性,也说明了所用M-C方法来模拟组合屏蔽(非均匀屏蔽)的可行性和设计多层组合屏蔽设计的实际意义。     

钛合金插铣过程温度场的数学建模与有限元分析

从金属切削理论出发分析了钛合金插铣过程的切削热产生机理,推导出工件的热传导方程式,并在此基础上建立钛合金插铣的数学模型,应用Galerkin有限元方法对工件的热传导方程进行推导计算,随后利用Matlab进行数值模拟,最终得到工件稳定后温度分布图.通过数值计算结果与实验结果对比,验证了有限元模型具有可靠和高精度优点.对钛合金插铣过程加工参数的优化和刀具的设计提供了重要参考依据.     

Spin-glass state and ferromagnetic order in Cu(II)－Fe(III) cyanides

The static and dynamic magnetic properties of a Prussian blue analogue, molecular magnet Cu^Ⅱ_{3}[Fe^Ⅲ(CN)_6]_2·3NH_3·6H_2O were investigated in detail. The H dependence of the linear AC susceptibility, the irreversibility in the field-cooled (FC)/zero-field-cooled (ZFC) magnetization (M_{FC}/M_{ZFC}) and the relaxation of M_{ZFC} suggest that the magnetic system can be visualized as containing a ferromagnetic cluster of spin below T_C, mixed with small spin-glass clusters formed below temperature T_g less than T_C. The observed magnetic properties are explained with a ferromagnetic-spin-glass phase model. The magnetic ordering of the sample occurs below 19.8K.