Differential pulse anodic stripping voltammetric determination of traces of copper with a tobramycin-Nafion modified electrode.

A Nafion-modified glassy carbon electrode incorporated with tobramycin for the voltammetric stripping determination of Cu2+ has been explored. The electrode was fabricated by tobramycin containing Nafion on the glassy carbon electrode surface. The modified electrode exhibited a significantly increased sensitivity and selectivity for Cu2+ compared with a bare glassy carbon electrode and the Nafion modified electrode. Cu2+ was accumulated in HAc-NaAc buffer (pH 4.6) at a potential of -0.6 V (vs. SCE) for 300 s and then determined by differential pulse anodic stripping voltammetry. The effects of various parameters, such as the mass of Nafion, the concentration of tobramycin, the pH of the medium, the accumulation potential, the accumulation time and the scan rate, were investigated. Under the optimum conditions, a linear calibration graph was obtained in the concentration range of 1.0 x 10(-9) to 5.0 x 10(-7) mol l(-1) with a correlation coefficient of 0.9971. The relative standard deviations for eight successive determinations were 4.3 and 2.9% for 1.0 x 10(-8) and 2.0 x 10(-7) mol l(-1) Cu2+, respectively. The detection limit (three times signal to noise) was 5.0 x 10(-10) mol l(-1). A study of interfering substances was also performed, and the method was applied to the direct determination of copper in water samples, and also in analytical reagent-grade salts with satisfactory results.     

Syntheses,Structures and Photocatalytic Degradation Properties of Two Copper(Ⅱ)Coordination Polymers with Flexible Bis(imidazole)Ligand

Two copper(Ⅱ)coordination polymers{[Cu(bib)(nip)]·1.5H2O}n(1)and[Cu2(bib)(glu)2]n(2)(bib= 1,4-bis(2-methyl-imidazol-1-yl)butane,H2nip = 5-nitroisophthalic acid,...     

Growth regulation of luminescent gold nanoparticles directed from amphiphilic block copolymers:highly-controlled nanoassemblies toward tailored in-vivo transport

The understanding of amphiphilic block copolymers(ABC)in encapsulation and transport of inorganic nanomedicines is highly desired.Still,it remains limited due to the challenges in the fabrication of nanoassemblies(NAs)with highly-controlled shape and loading of nanoparticles.Herein,through growth regulation of luminescent gold nanoparticles(Au NPs)by different reductants with ABC pluronic F127 as a template,a straightforward strategy is reported for in-situ fabrication of three wellcontrolled gold NAs(Au NAs)that display tunable shapes from spherical to elongated nanostructures and controllable surface chemistry and loading of Au NPs with distinct emissions but identical individual Au NP size.The three Au NAs exhibit tailored invivo transport behaviours:those with spherical shape and more hydrophilic surface show longer blood retention with higher tumor-targeting efficiency(~25.3%injection dose/g)and excellent long-term near-infrared tumor imaging even after 96 h postinjection.These findings provide a useful guidance in designing specific nanostructures for future nanomedicine transport.     

多孔径扫描波面恢复技术的精度评定及影响因素

多孔径扫描波面恢复技术是一项新的高精度大孔径面形检测手段.本文从建立波面恢复精度的评价标准出发,结合实测结果进行讨论,并对影响精度的两个重要因素即拼接模式及拼接区大小进行分析.     

光纤激光器的偏振开关操作

本文阐述了采用光子注入法实现光纤激光器的偏振开关操作.这种新颖的全光开关器件具有极低的阈值(0.1μW).对操作机理、实验实现和器件特性.     

Multi-hybrid method for investigation of EM scattering from inhomogeneous object above a dielectric rough surface

An iterative strategy combining Kirchhoff approximation(KA) with the hybrid finite element-boundary integral(FE-BI) method is presented in this paper to study the interactions between the inhomogeneous object and the underlying rough surface.KA is applied to study scattering from underlying rough surfaces,whereas FE-BI deals with scattering from the above target.Both two methods use updated excitation sources.Huygens equivalence principle and an iterative strategy are employed to consider the multi-scattering effects.This hybrid FE-BI-KA scheme is an improved and generalized version of previous hybrid Kirchhoff approximation-method of moments(KA-MoM).This newly presented hybrid method has the following advantages:(1) the feasibility of modeling multi-scale scattering problems(large scale underlying surface and small scale target);(2) low memory requirement as in hybrid KA-MoM;(3) the ability to deal with scattering from inhomogeneous(including coated or layered) scatterers above rough surfaces.The numerical results are given to evaluate the accuracy of the multi-hybrid technique;the computing time and memory requirements consumed in specific numerical simulation of FE-BI-KA are compared with those of MoM.The convergence performance is analyzed by studying the iteration number variation caused by related parameters.Then bistatic scattering from inhomogeneous object of different configurations above dielectric Gaussian rough surface is calculated and the influences of dielectric compositions and surface roughness on the scattering pattern are discussed.     

基于手机摄像头的可见光寻书导航系统

针对在大型图书馆内寻书难的问题设计了一种基于手机摄像头的可见光寻书导航系统,该系统将LED可见光通信技术应用于图书馆内寻书导航中,并创新性的采用手机摄像头为LED可见光通信技术的接收端。配合使用自主设计的手机寻书软件,可实现图书馆内精确定位和实时导航,有效解决了寻书难的问题。     

肉桂酸合成方法的改进及其红外光谱分析

苯甲醛与乙酸酐在碳酸钾的催化下发生Perkin反应可制得肉桂酸,产率可达93%,实验过程中用萃取的方法代替水蒸汽蒸馏去除未反应的苯甲醛,简化了反应步骤,缩短了反应时间,并对产物的红外光谱进行了分析。