Synthesis and X-ray crystal structure of oxamido-bridged heterobinuclear Ni(Ⅱ)-Cu(Ⅱ) complexes

The two complexes [Ni(oxen)Cu(L)2](ClO4)2.xH2O (L=2,2'-bipyridyl(bpy), 1,10-phenanthroline(phen)) have been synthesized, where oxen is N,N'-bis(2-aminoethyl)oxamido di-anion. The crystal structure of [Ni(oxen)Cu(bpy)2](ClO4)2.CH3OH has been determined by X-ray diffraction method. The crystal is triclinic system, space group P1 with a=12.179(1),b=12.298(2), c=11.476(2) A, a=97.57(1), B=97.52(1), 7=80.29(2), V=1669.04(67) A3, Z=2, Dcalcd=1.667 g/cm3. The structure has been refined to final R of 0.076 and Rw of 0.080, respectively. The complexes have an extended oxamido-bridged structure and consist of Ni(Ⅱ) ion in a square planar environment and Cu(Ⅱ) ion in a distorted octahedral environment.     

长白山地区几种红景天品种的傅里叶变换红外光谱法鉴别研究

分别用石油醚,氯仿,甲醇对长白山地区的野生和栽培高山红景天和长白红景天进行了提取,并首次对提取物进行了傅里叶变换红外光谱法测定,还用红景天块做了相应的验证研究。结果表明,长白山地区的野生和栽培高山红景天和长白红景天的红外光谱图谱有明显不同,故可用作鉴别其品种或评价其质量的一种手段。     

白灵菇多糖的提取及含量的测定

苯酚-硫酸分光光度法测定白灵菇中多糖含量。测定波长485nm,多糖换算因子f=1.59,在5.00—70.00μg/mL范围内吸光度与被测物含量呈良好的线性关系,相关系数r=0.9998,方法的回收率在96.66%—102.33%%之间,相对标准偏差RSD在2.01%—3.10%之间。测定结果表明,白灵菇中含有丰富的多糖。本法简便、准确、重现性好,可作为白灵菇多糖含量的测定方法。     

Nonlinear Squeezed States and Multiplication Rule of Nonlinear Squeezing Operators Gained via Nonlinear Coherent State Representation and IWOP Technique

Using the nonlinear coherent state representation we derive nonlinear squeezed states and the multiplication rule of nonlinear squeezing operators. We find that the symplectic matrices multiplication rule in nonlinear coherent state projection operator representation maps into the multiplication rule of successive nonlinear squeezing operators.The technique of integral within an ordered product of operators plays an essential role in deriving the multiplication rule.     

Determination of the ~(12)C(p, γ)~(13)N reaction rates fromthe ~(12)C(~7Li,~6He)~(13)N reaction

The angular distribution of the 12C(7Li,6He)13N reaction at E(7Li) = 44.0 MeV was measured at the HI-13 tandem accelerator of Beijing, China. The asymptotic normalization coefficient (ANC) of 13N → 12C + p was derived to be (1.64 ± 0.11) fm-1/2 through the distorted wave Born approximation (DWBA) analysis. The ANC was then used to deduce the astrophysical S (E) factors and reaction rates for the 12C(p,γ)13N direct capture reaction at energies of astrophysical relevance.     

A Few Remarks on Milburn Equation

After presenting the infinite operator-sum form solution to the Milburn equation dp/dt=γ（UρU^f - ρ）=γU[p, Uf], where U=e^-iH/hγ, and verifying that this equation preserves the three necessary conditions of density operators during time evolution, we prove that the yon Neumann entropy increases with time. We also point out that if A and B both obey the Milburn equation, then theproduct AB obeys （d/dt）（AB） = γU[AB, U^f]-（1/γ）（dA/dt）（dB/dt）, which violates the Milburn equation, this reflects that a pure state will evolve to a mixture in general     

动力学椭圆代数Aq,p,(^π)(∧gln)的Drinfeld流

从推广的Yang-Baxter关系"RLL=LLR*"出发,利用高秩高斯分解,得到了动力学椭圆代数Aq,p,^π(∧gln)及其对应的Drinfeld流.其中R,R*是A(1)n-1面模型对应的谱参数有一关于代数中心平移的动力学R矩阵.     

叶绿素紫外吸收特性的分析研究

鉴于光合作用对人类生存和发展的极其重要的地位,本文选取其关键载体——叶绿素进行其光谱的分析研究。在理论分析的基础上,使用WGD-8A型多功能组合光谱仪测量并分析了叶绿素的紫外吸收特性。结合实验结果和前人的研究成果,得出叶绿素在紫外波段281nm和312nm处有较强的吸收峰,紫外线对于光合作用有促进作用的结论,并提供了一种测量叶绿素含量的方法。     

Quantum Hadamard Operators and Their Decomposition Derived by Virtue of IWOP Technique

We introduce the quantum Hadamard operator in continuum state vector space and find that it can be decomposed into a single-mode squeezing operator and a position-momentum mutual transform operator. The two-mode Hadamard operator in bipartite entangled state representation is also introduced, which involves the two-mode squeezing operator and [η〉 ←→｜ξ〉 mutual transformation operator, where [η〉 and ｜ξ〉 are mutual conjugate entangled states. All the discussions are proceeded by virtue of the IWOP technique.     

Generation of Bell states via Lyapunov control on a two-qubit system with an anisotropic XY Heisenberg interaction

We demonstrate that an arbitrary Bell state can be achieved in a two qubit anisotropic Heisenberg XY chain via Lyapunov control. During the whole process, we only need to apply an external field along a given direction to a single qubit. This control strategy is effective for all initial states in the four-dimensional Hilbert space where the target state is asymptotically stable. The effects of imperfections on the fidelity for the target state such as Gaussian leakage of local control and localized dephasi...