(Ni0.8Zn0.2Fe2O4)epoxy-PZT双层膜中的磁电效应

讨论了Ni_0.8Zn_0.2Fe₂O₄ (NZFO)与锆钛酸铅(PZT)的双层膜结构样品的磁电(ME)效应.NZFO粉料由溶胶-凝胶法制成，再经900℃热压，并高温烧结.在该双层膜中测量到了很强的磁电相互作用.发现横向的磁电效应比纵向效应大一个数量级，并且随NZFO烧结温度的提高而增加.当烧结温度从950℃上升到1380℃时，横向ME电压系数(α_E)的最大值变化范围为25.6 mV Am^-2≤α_E≤199.6 mV Am^-2.理论分析显示NZFO-PZT双层膜样品中ME效应源于NZFO与PZT之间相对良好的磁电耦合. 关键词： 镍铁氧体 PZT 热压法 ME效应     

Membrane introduction mass spectrometry

An overview of membrane introduction mass spectrometry (MIMS) is presented and comparisons are made with other direct sample introduction techniques. Special attention is given to the unique advantages and the limitations of newer variants on the MIMS technique, including affinity MIMS, reverse-phase and trap MIMS. The salient features of the interfaces used in MIMS are summarized and the various membrane materials commonly used are delineated. The applicability of MIMS is illustrated via discussion of

1. (i) bioreactor monitoring (represented by yeast fermentation),

2. (ii) environmental monitoring (illustrated by analysis of contaminated ground water samples) and

3. (iii) on-line chemical reaction monitoring (exemplified by the photolysis of aryl esters).

The applicability of MIMS to the analysis of environmental samples, including complex mixtures in water, air and soil, is noted.     

Vortices in Bose-Einstein condensates: A review of the experimental results

Rotating dilute Bose-Einstein condensates (BEC) of alkali atoms offer a testing ground for theories of vortices in weakly interacting superfluids. In a rotating super-fluid, quantised vortices, with a vorticity h/m, form above a critical velocity. Such vortices have been generated in BEC of alkali atoms by different techniques such as (a) wave function engineering of a two-component BEC, (b) decay of solitons, (c) rotation of a thermal cloud before cooling it below the condensation temperature, (d) stirring with an ‘optical’ spoon, (e) rotating a deformation in the anisotropic trap in which the condensate is trapped and (f) by creating Berry phase by adiabatically reversing the axial magnetic field. Since the core of a vortex is a fraction of a micrometer in diameter, it cannot be directly imaged optically. The condensate with vortices is allowed to ballistically expand till the size increases by one order before the vortices are imaged. Surface wave spectroscopy and the change in aspect ratio of a rotating cloud are the other techniques used. Studies have been made on the creation and dynamics of single vortex and on systems with more than a hundred vortices. Results have been obtained on vortex nucleation, stability of vortex structures, nature of the vortex lattice and defects in such a lattice. Important results are: (a) evidence exists that vortex nucleation takes place by a surface mode instability; but this is not the only mechanism; (b) the vortex lattice is perfectly triangular right up to the edge; (c) in the initial stages of rotation of the cloud a tangled web of vortices is seen; it takes a few hundred milliseconds before the vortices arrange themselves in a lattice; this time appears to be independent of temperature; (d) the decay of vortices appears to arise from the transfer of energy to the rotating thermal component and is dependent on temperature; (e) defects in the lattices such as dislocations and grain boundaries are seen; (f) transverse oscillations (Tkachenko modes) of the vortex lattice have been observed; and (g) giant vortices have been produced. These will be discussed.     

Does an all-sulphur analogue of heptamolybdate exist?

The complexes [MoX₄]²⁻ (M = Mo; X = O or S) exist as the monomeric tetrahedral species in aqueous alkaline solutions. Acidification of tetraoxomolybdate results in the condensation of the tetrahedral units via a series of polyoxomolybdates leading to the ultimate formation of the trioxide MoO₃. Heptamolybdate [Mo₇O₂₄]⁶⁻ is the first major polyanion of the acidification reaction. In contrast, acidification of tetrathiomolybdates leads to the formation of amorphous molybdenum trisulphide via a dinuclear Mo(V) complex. The formation of the dinuclear Mo(V) complex precludes the formation of any higher nuclearity Mo(VI)-S complexes in aqueous solution. Thus it is shown that the all-sulphur analogue of heptamolybdate [M0₇S₂₄]⁶⁻ does not exist in alkaline medium and also cannot be isolated from aqueous acidic medium     

Photonic crystals--a step towards integrated circuits for photonics.

The field of photonic crystals has, over the past few years, received dramatically increased attention. Photonic crystals are artificially engineered structures that exhibit a periodic variation in one, two, or three dimensions of the dielectric constant, with a period of the order of the pertinent light wavelength. Such structures in three dimensions should exhibit properties similar to solid-state electronic crystals, such as bandgaps, in other words wavelength regions where light cannot propagate in any direction. By introducing defects into the periodic arrangement, the photonic crystals exhibit properties analogous to those of solid-state crystals. The basic feature of a photonic bandgap was indeed experimentally demonstrated in the beginning of the 1990s, and sparked a large interest in, and in many ways revitalized, photonics research. There are several reasons for this attention. One is that photonic crystals, in their own right, offer a proliferation of challenging research tasks, involving a multitude of disciplines, such as electromagnetic theory, nanofabrication, semi-conductor technology, materials science, biotechnology, to name a few. Another reason is given by the somewhat more down-to-earth expectations that photonics crystals will create unique opportunities for novel devices and applications, and contribute to solving some of the issues that have plagued photonics such as large physical sizes, comparatively low functionality, and high costs. Herein, we will treat some basics of photonic crystal structures and discuss the state-of-the-art in fabrication as well give some examples of devices with unique properties, due to the use of photonic crystals. We will also point out some of the problems that still remain to be solved, and give a view on where photonic crystals currently stand.