全文获取类型
收费全文 | 4500篇 |
免费 | 134篇 |
国内免费 | 22篇 |
专业分类
化学 | 2932篇 |
晶体学 | 20篇 |
力学 | 140篇 |
数学 | 664篇 |
物理学 | 900篇 |
出版年
2023年 | 28篇 |
2022年 | 37篇 |
2021年 | 89篇 |
2020年 | 71篇 |
2019年 | 92篇 |
2018年 | 61篇 |
2017年 | 71篇 |
2016年 | 189篇 |
2015年 | 107篇 |
2014年 | 156篇 |
2013年 | 257篇 |
2012年 | 298篇 |
2011年 | 341篇 |
2010年 | 208篇 |
2009年 | 197篇 |
2008年 | 287篇 |
2007年 | 297篇 |
2006年 | 237篇 |
2005年 | 259篇 |
2004年 | 216篇 |
2003年 | 179篇 |
2002年 | 140篇 |
2001年 | 42篇 |
2000年 | 45篇 |
1999年 | 37篇 |
1998年 | 38篇 |
1997年 | 35篇 |
1996年 | 54篇 |
1995年 | 47篇 |
1994年 | 46篇 |
1993年 | 31篇 |
1992年 | 22篇 |
1991年 | 28篇 |
1990年 | 32篇 |
1989年 | 35篇 |
1988年 | 23篇 |
1987年 | 23篇 |
1986年 | 17篇 |
1985年 | 25篇 |
1984年 | 39篇 |
1983年 | 19篇 |
1982年 | 24篇 |
1981年 | 30篇 |
1980年 | 27篇 |
1979年 | 20篇 |
1978年 | 20篇 |
1977年 | 14篇 |
1975年 | 15篇 |
1974年 | 7篇 |
1970年 | 7篇 |
排序方式: 共有4656条查询结果,搜索用时 15 毫秒
1.
2.
The paper presents an interphase cohesive zone model (CZM) incorporating stress multi-axiality devised to capture, by simplified micro-modeling, the influence of the in-plane strain and stress state in the mechanical response of the CZM. Moreover, the model is able to account for the Poisson-related effect in the interphase, which can play an important role in the modeling of heterogeneous masonry elements. From the constitutive point of view, the proposed formulation couples damage and friction by addressing a smooth transition from a quasi-brittle response to a residual frictional behavior described by a Coulomb law with unilateral contact. As in-plane stresses are accounted for, damage activation and evolution are governed by a Drucker–Prager law with linear softening. A predictor-corrector procedure based on a backward Euler scheme is detailed for integrating the nonlinear evolutive problem together with the related tangent operator which consistently linearizes the algorithmic strategy. This framework is embedded into a kinematically-enriched finite element interphase formulation incorporating stress multi-axiality. The modeling features of the resulting numerical tool are tested both at the local level, for the typical interphase point, and in meso-structural tests consisting of brick-mortar triplets, investigating the capability of the proposed model and numerical procedure to simulate the brick-mortar decohesion mechanism during confined slip tests. 相似文献
3.
Cristina B Corcino Roberto B Corcino István Mező José L Ramírez 《Proceedings Mathematical Sciences》2018,128(3):27
In the present article, we study three families of polynomials associated with the r-Whitney numbers of the second kind. They are the r-Dowling polynomials, r-Whitney–Fubini polynomials and the r-Eulerian–Fubini polynomials. Then we derive several combinatorial results by using algebraic arguments (Rota’s method), combinatorial arguments (set partitions) and asymptotic methods. 相似文献
4.
Particularly-shaped silver nanostructures are successfully applied in many scientific fields, such as nanotechnology, catalysis, (nano)engineering, optoelectronics, and sensing. In recent years, the production of shape-controlled silver-based nanostructures and the knowledge around this topic has grown significantly. Hence, on the basis of the most recent results reported in the literature, a critical analysis around the driving forces behind the synthesis of such nanostructures are proposed herein, pointing out the important role of surface-regulating agents in driving crystalline growth by favoring (or opposing) development along specific directions. Additionally, growth mechanisms of the different morphologies considered here are discussed in depth, and critical points highlighted. 相似文献
5.
A Stable Porphyrin Functionalized Graphite Electrode Used at the Oxygen Evolution Reaction Potential
Gianlorenzo Bussetti Roberto Bernasconi Claudia Filoni Luca Magagnin Alberto Bossi Franco Ciccacci Lamberto Duò 《Electroanalysis》2022,34(7):1227-1236
Many researches have been devoted to rechargeable power generators that can store (but also release) energy. This availability is ensured through (e. g.) the oxygen evolution reaction (OER). However, (i) large values of the overpotentials and (ii) a progressive detriment of the anode (graphite) electrode limit the ultimate device. In view of enhancing the electrode performances, graphite was protected by following different strategies, which oblige to follow precise preparation protocols. Here, we prove that a thin layer of free-base porphyrin molecules is able to protect the underneath graphite electrode from detriment even if many (about 100) electrochemical cycles are performed. 相似文献
6.
Martins Marina Roberto Johann Gracielle Palú Fernando da Silva Edson Antonio 《Journal of Thermal Analysis and Calorimetry》2022,147(13):7411-7420
Journal of Thermal Analysis and Calorimetry - Due to the huge variety of therapeutic properties found in plant leaves, many of these are widely used in traditional medicine. Among these plants,... 相似文献
7.
8.
Dr. Andy Hernández Montoto Dr. Antoni Llopis-Lorente Mónica Gorbe José M. Terrés Dr. Roberto Cao-Milán Dr. Borja Díaz de Greñu Dr. María Alfonso Dr. Javier Ibañez Prof. María D. Marcos Dr. Mar Orzáez Dr. Reynaldo Villalonga Prof. Ramón Martínez-Máñez Dr. Félix Sancenón 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(36):8471-8478
Janus gold nanostar–mesoporous silica nanoparticle ( AuNSt–MSNP ) nanodevices able to release an entrapped payload upon irradiation with near infrared (NIR) light were prepared and characterized. The AuNSt surface was functionalized with a thiolated photolabile molecule ( 5 ), whereas the mesoporous silica face was loaded with a model drug (doxorubicin) and capped with proton-responsive benzimidazole-β-cyclodextrin supramolecular gatekeepers ( N 1 ). Upon irradiation with NIR-light, the photolabile compound 5 photodissociated, resulting in the formation of succinic acid, which induced the opening of the gatekeeper and cargo delivery. In the overall mechanism, the gold surface acts as a photochemical transducer capable of transforming the NIR-light input into a chemical messenger (succinic acid) that opens the supramolecular nanovalve. The prepared hybrid nanoparticles were non-cytotoxic to HeLa cells, until they were irradiated with a NIR laser, which led to intracellular doxorubicin release and hyperthermia. This induced a remarkable reduction in HeLa cells viability. 相似文献
9.
Maroni Fabio Bruni Pantaleone Suzuki Naoki Aihara Yuichi Croce Fausto 《Journal of Solid State Electrochemistry》2019,23(6):1697-1703
Journal of Solid State Electrochemistry - All-solid-state batteries represent the next generation of electrochemical energy storage systems. A tin-carbon nanocomposite material is prepared by the... 相似文献
10.
Dr. Lara Martinez-Fernandez Dr. Krishna Gavvala Dr. Rajans Sharma Prof. Pascal Didier Dr. Ludovic Richert Dr. Javier Segarra Martì Dr. Mattia Mori Prof. Yves Mely Dr. Roberto Improta 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(30):7375-7386
Thienoguanosine (thG) is an isomorphic analogue of guanosine with promising potentialities as fluorescent DNA label. As a free probe in protic solvents, thG exists in two tautomeric forms, identified as the H1, being the only one observed in nonprotic solvents, and H3 keto–amino tautomers. We herein investigate the photophysics of thG in solvents of different polarity, from water to dioxane, by combining time-resolved fluorescence with PCM/TD-DFT and CASSCF calculations. Fluorescence lifetimes of 14.5–20.5 and 7–13 ns were observed for the H1 and H3 tautomers, respectively, in the tested solvents. In methanol and ethanol, an additional fluorescent decay lifetime (≈3 ns) at the blue emission side (λ≈430 nm) as well as a 0.5 ns component with negative amplitude at the red edge of the spectrum, typical of an excited-state reaction, were observed. Our computational analysis explains the solvent effects observed on the tautomeric equilibrium. The main radiative and nonradiative deactivation routes have been mapped by PCM/TD-DFT calculations in solution and CASSCF in the gas phase. The most easily accessible conical intersection, involving an out-of plane motion of the sulfur atom in the five-membered ring of thG, is separated by a sizeable energy barrier (≥0.4 eV) from the minimum of the spectroscopic state, which explains the large experimental fluorescence quantum yield. 相似文献