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排序方式: 共有153条查询结果,搜索用时 234 毫秒
1.
Reducing the noble-metal catalyst content of acid Polymer Electrolyte Membrane (PEM) water electrolyzers without compromising catalytic activity and stability is a goal of fundamental scientific interest and substantial technical importance for cost-effective hydrogen-based energy storage. This study presents nanostructured iridium nanodendrites (Ir-ND) supported on antimony doped tin oxide (ATO) as efficient and stable water splitting catalysts for PEM electrolyzers. The active Ir-ND structures exhibited superior structural and morphological properties, such as particle size and surface area compared to commercial state-of-art Ir catalysts. Supported on tailored corrosion-stable conductive oxides, the Ir-ND catalysts exhibited a more than 2-fold larger kinetic water splitting activity compared with supported Ir nanoparticles, and a more than 8-fold larger catalytic activity than commercial Ir blacks. In single-cell PEM electrolyzer tests, the Ir-ND/ATO outperformed commercial Ir catalysts more than 2-fold at technological current densities of 1.5 A cm–2 at a mere 1.80 V cell voltage, while showing excellent durability under constant current conditions. We conclude that Ir-ND/ATO catalysts have the potential to substantially reduce the required noble metal loading, while maintaining their catalytic performance, both in idealized three-electrode set ups and in the real electrolyzer device environments.  相似文献   
2.
Journal of Radioanalytical and Nuclear Chemistry - This research aimed to authenticate the geographical origin of imported fresh apples using isotopic techniques. The results show that the...  相似文献   
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4.
The fabrication of a novel sheathless interface for capillary electrophoresis–electrospray–mass spectrometry (CE–ESI–MS) is described. A programmable CO2 laser was used to ablate small channels in the walls of a polyimide capillary near the terminus. Subsequent exposure of the channel region to a cellulose acetate solution followed by drying resulted in the formation of an electrically conductive semi-permeable membrane. Application of an appropriate voltage to the reservoir resulted in the simultaneous establishment of an electrical connection for CE and ESI. Interface viability was demonstrated by conducting a CE separation of a peptide mixture, with detection accomplished via positive ion mode ESI–MS. For the peptide Val-Tyr-Val, a limit of detection of 0.1 femtomole (S/N 3) was achieved using single reaction monitoring. Attributes of the interface include structural robustness, ease of fabrication, minimal interface dead volume, and the ability to alter post-separation analyte ionization status by use of appropriate buffers in the interface reservoir.  相似文献   
5.
Magnesium batteries, like lithium-ion batteries, with higher abundance and similar efficiency, have drawn great interest for large-scale applications such as electric vehicles, grid energy storage and many more. On the other hand, the use of organic electrode materials allows high energy-performance, metal-free, environmentally friendly, versatile, lightweight, and economically efficient magnesium storage devices. In particular, the structural diversity and the simple activity of organic molecules make redox properties, and hence battery efficiency, easy to monitor. While organic magnesium batteries still in their infancy, this field becomes more and more promising because significant results were reported. To summarize the achievements in studies on organic cathodes for magnesium systems, their synthesis is discussed, combined with electrode design to provide the basis for controlling the electrochemical properties. Moreover, the techniques to synthesize organic materials with high-yield are mentioned. Finally, potential problems and prospects are explored to further improve organic cathodes.  相似文献   
6.
We prove some Picone-type identities and inequalities for a class of first-order nonlinear dynamic systems and derive various weighted inequalities of Wirtinger type and Hardy type on time scales. As applications we study oscillatory and related properties of these systems including Reid's roundabout theorem on disconjugacy, Sturm's separation and comparison theorems, as well as a variational method in the oscillation theory.  相似文献   
7.
Two acridones, paratrimerins C (1) and D (2), and two coumarins, paratrimerins E (3) and F (4), were isolated from the CHCl3 and EtOAc extracts of Paramignya trimera (Rutaceae), together with twelve known compounds (516). Their structures were elucidated on the basis of spectroscopic data. All isolated compounds possessed significant α-glucosidase inhibitory activity in a concentration-dependent manner, and showed more potent inhibitory activity, with IC50 values ranging from 14.6 to 112.2 μM, than the positive control acarbose (IC50, 214.5 μM). The biosynthesis of the isolated coumarins and acridones was proposed.  相似文献   
8.
We introduce a notion of CS-Rickart module being a modular analog of the ACS-ring concept. We describe the rings over which each finitely generated projective module is CS-Rickart module. The presented results yield the known results related to Rickart modules and semihereditary rings.  相似文献   
9.
Summary It is shown that the kinematics of the flow of a general viscoelastic fluid in a wedge, one plate of which is being stretched at a rate proportional to the distance from the wedge apex, is Newtonian in character. Existence proof is given when non-Newtonian effects are slight. Furthermore, the stress field is multivalued at the wedge apex and the pressure field is logarithmically singular there. The strength of this singularity increases with the Weissenberg number.  相似文献   
10.
It is shown that a similarity solution to the Rayieigh flow problem for a generalized Newtonian fluid exists if the fluid boundary (y=0) is given a velocityU(t) t 1/2. Furthermore, if the fluid is of the power-law type then similarity solutions exist ifU(t) t (orU(t) e t), where is any real number.
Zusammenfassung Eine Methode wird aufgezeigt, wonach eine Ähnlichkeitslösung für das Rayleigh Strömungsproblem für eine allgemeine Newtonische Flüssigkeit besteht, falls der Flüssigkeitsgrenze (y=0) eine GeschwindigkeitU (t) t 1/2 zugeordnet wird. Für Flüssigkeiten von Potenz-Gesetz-Charakter gibt es außerdem Ähnlichkeitslösungen, fallsU(t) t (orU(t) e t) gilt, wobei eine beliebige reelle Zahl darstellt.
  相似文献   
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