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Analysis of human plasma metabolites across different liquid chromatography/mass spectrometry platforms: Cross‐platform transferable chemical signatures 下载免费PDF全文
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M. Gamella S. Campuzano J. Manso G. González de Rivera F. López-Colino A.J. Reviejo J.M. Pingarrón 《Analytica chimica acta》2014
A non-invasive, passive and simple to use skin surface based sensing device for determining the blood's ethanol content (BAC) by monitoring transdermal alcohol concentration (TAC) is designed and developed. The proposed prototype is based on bienzyme amperometric composite biosensors that are sensitive to the variation of ethanol concentration. The prototype correlates, through previous calibration set-up, the amperometric signal generated from ethanol in sweat with its content in blood in a short period of time. The characteristics of this sensor device permit determination of the ethanol concentration in isolated and in continuous form, giving information of the BAC of a subject either in a given moment or its evolution during long periods of time (8 h). Moreover, as the measurements are performed in a biological fluid, the evaluated individual is not able to alter the result of the analysis. The maximum limit of ethanol in blood allowed by legislation is included within the linear range of the device (0.0005–0.6 g L−1). Moreover, the device shows higher sensitivity than the breathalyzers marketed at the moment, allowing the monitoring of the ethanol content in blood to be obtained just 5 min after ingestion of the alcoholic drink. The comparison of the obtained results using the proposed device in the analysis of 40 volunteers with those provided by the gas chromatographic reference method for determination of BAC pointed out that there were no significant differences between both methods. 相似文献
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G. Astray A. Cid J. A. Manso J. C. Mejuto O. Moldes J. Morales J. Quintás 《Journal of solution chemistry》2011,40(12):2072-2081
Aggregation numbers of micelles based on N-alkylamines and mixed systems CTACl/N-alkylamines have been determined using fluorescence
techniques. The values of aggregation number are compared as a function of hydrocarbon chain length and as a function of the
molar fraction in the mixed systems. 相似文献
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S. Pessanha M.L. Carvalho M. Manso A. Guilherme A.F. Marques C.A. Perez 《Spectrochimica Acta Part B: Atomic Spectroscopy》2009,64(8):805
The pigment vermilion (HgS) was used to color the fore edge, tail and head of books. Dissemination and quantification of Hg present in the ink used to color books from XVIII and XIX centuries are reported. Mercury is a very toxic element for the human body, therefore it is extremely important to know whether Hg tends to disseminate throughout the paper or stays confined to the borders of the books with less danger for readers. Synchrotron X-ray microprobe was used to evaluate Hg dissemination from the border to the centre of the paper sheet. The diffusion pattern of Hg was compared with the results obtained by a portable X-ray fluorescence spectrometer and mean quantitative calculations were obtained by a stationary X-ray fluorescence system with triaxial geometry. The results showed high concentrations of Hg in the external regions, but no diffusion was observed for the inner parts of the paper. 相似文献
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M. Manso S. Pessanha F. Figueira S. Valadas A. Guilherme M. Afonso A. C. Rocha M. J. Oliveira I. Ribeiro M. L. Carvalho 《Analytical and bioanalytical chemistry》2009,395(7):2029-2036
The reddish-brown, brown or yellowish stains of circular or irregular shape known as foxing spots have been fully described
in conservation literature but still, this phenomenon does not find any scientific agreement since many hypotheses have been
raised concerning their origin. In this work a contribution to foxing definition not only focussed on its appearance but also
reported on its chemical information. For this purpose foxing stains present in drawings from two Portuguese artists dated
from the eighteenth to nineteenth centuries were observed under ultra-violet light and optical microscope and analysed by
three non-invasive spectroscopy techniques. The observations carried out on the stains provided information on their surface
morphology. The use of energy-dispersive X-ray fluorescence revealed a variation on the elemental content between foxing and
paper region. Although the results from X-ray diffraction analysis showed no signs of cellulose degradation in foxing stains,
Fourier-transformed infrared analysis revealed the presence of oxide groups. Both the information on the chemical nature and
surface morphology of the stains achieved in this study will contribute to increase foxing formation information and develop
future protocols for conservation purposes. 相似文献
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R. Arnaldi R. Averbeck K. Banicz J. Castor B. Chaurand C. Cicalo A. Colla P. Cortese S. Damjanovic A. David A. De Falco A. Devaux A. Drees L. Ducroux H. En’yo A. Ferretti M. Floris A. Foerster P. Force N. Guettet A. Guichard H. Gulkanian J. Heuser M. Keil L. Kluberg J. Lozano C. Lourenço F. Manso A. Masoni P. Martins A. Neves H. Ohnishi C. Oppedisano P. Parracho P. Pillot G. Puddu E. Radermacher P. Ramalhete P. Rosinsky E. Scomparin J. Seixas S. Serci R. Shahoyan P. Sonderegger H.J. Specht R. Tieulent G. Usai R. Veenhof H.K. Wöhri 《The European Physical Journal C - Particles and Fields》2007,49(1):235-241
The NA60 experiment at the CERN SPS has studied low-mass muon pairs in 158 A GeV In–In collisions. A strong excess of pairs
is observed above the yield expected from neutral meson decays. The unprecedented sample size close to 400000 events and the
good mass resolution of about 2% made it possible to isolate the excess by subtraction of the decay sources. The shape of
the resulting mass spectrum shows some non-trivial centrality dependence, but is largely consistent with a dominant contribution
from π+π-→ϱ→μ+μ- annihilation. The associated ϱ spectral function exhibits considerable broadening, but essentially no shift in mass. The
pT-differential mass spectra show the excess to be much stronger at low pT than at high pT. The results are compared to theoretical model predictions; they tend to rule out models linking hadron masses directly to
the chiral condensate.
PACS 25.75.-q; 12.38.Mh; 13.85.Qk 相似文献
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Arnaldi R Banicz K Castor J Chaurand B Cicalò C Colla A Cortese P Damjanovic S David A de Falco A Devaux A Ducroux L En'yo H Fargeix J Ferretti A Floris M Förster A Force P Guettet N Guichard A Gulkanian H Heuser JM Keil M Kluberg L Lourenço C Lozano J Manso F Martins P Masoni A Neves A Ohnishi H Oppedisano C Parracho P Pillot P Poghosyan T Puddu G Radermacher E Ramalhete P Rosinsky P Scomparin E Seixas J Serci S Shahoyan R Sonderegger P Specht HJ Tieulent R Usai G Veenhof R 《Physical review letters》2007,99(13):132302
The NA60 experiment studies muon pair production at the CERN Super Proton Synchrotron. In this Letter we report on a precision measurement of J/psi in In-In collisions. We have studied the J/psi centrality distribution, and we have compared it with the one expected if absorption in cold nuclear matter were the only active suppression mechanism. For collisions involving more than approximately 80 participant nucleons, we find that an extra suppression is present. This result is in qualitative agreement with previous Pb-Pb measurements by the NA50 experiment, but no theoretical explanation is presently able to coherently describe both results. 相似文献
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R. Arnaldi K. Banicz K. Borer J. Castor B. Chaurand W. Chen C. Cicalò A. Colla P. Cortese S. Damjanovic A. David A. de Falco A. Devaux L. Ducroux H. En’yo J. Fargeix A. Ferretti M. Floris A. F?rster P. Force N. Guettet A. Guichard H. Gulkanyan J. Heuser M. Keil L. Kluberg Z. Li C. Louren?o J. Lozano F. Manso P. Martins A. Masoni A. Neves H. Ohnishi C. Oppedisano P. Parracho P. Pillot T. Poghosyan G. Puddu E. Radermacher P. Ramalhete P. Rosinsky E. Scomparin J. Seixas S. Serci R. Shahoyan P. Sonderegger H. J. Specht R. Tieulent A. Uras G. Usai R. Veenhof H. K. W?hri 《The European Physical Journal C - Particles and Fields》2009,64(1):1-18
The NA60 experiment has measured muon pair production in In–In collisions at 158 AGeV at the CERN SPS. This paper presents a high statistics measurement of φ→μ μ meson production. Differential spectra, yields, mass and width are measured as a function of centrality and compared to previous measurements in other colliding systems at the same energy. The width of the rapidity distribution is found to be constant as a function of centrality, compatible with previous results. The decay muon polar angle distribution is measured in several reference frames. No evidence of polarization is found as a function of transverse momentum and centrality. The analysis of the p T spectra shows that the φ has a small radial flow, implying a weak coupling to the medium. The T eff parameter measured in In–In collisions suggests that the high value observed in Pb–Pb in the kaon channel is difficult to reconcile with radial flow alone. The absolute yield is compared to results in Pb–Pb collisions: though significantly smaller than measured by NA50 in the muon channel, it is found to exceed the NA49 and CERES data in the kaon channel at any centrality. The mass and width are found to be compatible with the PDG values at any centrality and at any p T : no evidence for in-medium modifications is observed. 相似文献