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电感耦合等离子体质谱法(ICP-MS)标准模式测定地质样品中Cu和Zn时,样品溶液中Ti在高温下易形成TiO+和 TiOH+离子产生重叠干扰,使测定值偏离真值而影响测定结果。采用氢氟酸-高氯酸-硝酸消解、王水复溶样品,通过多级在线校正46Ti16O+,消除TiO+和 TiOH+离子重叠干扰,研究了单质Ti与46Ti16O+、质荷比63、64、65、66离子间存在的关系,建立了一种电感耦合等离子体质谱(ICP-MS)法测定地质样品中Cu和Zn的分析方法。实验结果表明:单质Ti对Cu和Zn产生的干扰值与其质量浓度呈非简单的正相关性,TiO+产生的干扰离子质荷比65离子强度比63高,质荷比64离子强度比66 高; 46Ti16O+对质荷比63、66离子干扰增量值与单质Ti质量浓度变化无关;62Ni对46Ti16O+产生同量异位素重叠干扰,测定值须校正来自62Ni的贡献。ICP-MS测定地质样品中Cu和Zn时应选择测量同位素63Cu和66Zn,其检出限(n=7)分别为0.35 μg/g和0.63 μg/g。经有证标准物质验证,测定值与认定值吻合,准确度(RE)<8.6%,精密度(RSD,n=6)<5%。本方法适用于ICP-MS测定地质样品中Cu和Zn的质谱干扰消除,满足地质分析要求。 相似文献
3.
Y. Y. Shu J. E. Dowdall C. Chiu R. C. Lao 《International journal of environmental analytical chemistry》2013,93(2-4):185-194
Abstract Polychlorinated biphenyls (PCBs) are toxic, perssstent, global environmental contaminants which were formulated as complex mixtures of congeners. Many methods have been developed in the past to analyze PCB in transformer oil samples for regulatory purposes. The most important consideration in the cleanup procedure is the ability to remove the oil from the sample matrix, since trace amount of oil will interfere with the subsequent GC-MS analysis. Electron capture detection (ECD) has been the most common method for gas chromatographic analysis of PCBs because of its high sensitivity toward halogenated compounds. ECD can also respond to some non-PCB compound resulting in biased concentrations of PCB. In this work, a two-stage cleanup method, using DMSO liquid/liquid extraction and HPLC column chromatography. has been applied to two types of transformer oil. Five internal standards have been selected to show their performance in the presence of different oil matrices. The comparison of the PCB quantification at different conditions for GC-MS and GC-ECD will be demonstrated. 相似文献
4.
Liu M. Lao J. Wang H. Xu Z. Li J. Wen L. Yin Z. Luo C. Peng H. 《Russian Journal of Electrochemistry》2021,57(1):41-50
Russian Journal of Electrochemistry - A electrochemical sensor based on graphene and gold nanoparticles modified glassy carbon electrode (GCE) was developed for the determination of tyrosine (Tyr).... 相似文献
5.
Non-collinear continuous frequency doubling with relatively high conversion efficiency is demonstrated in periodically-poled
lithium niobate. It is shown that about 80% of the total second harmonic energy can be collected to one output channel by
tuning incident angle. The fractional phase-matching condition is introduced to interpret the phenomenon. These results make
it possible for direct power applications of continuous frequency doubling over the broad spectral range from the visible
to the infrared without temperature or angle tuning. 相似文献
6.
A high-speed counter-current chromatography (HSCCC) technique in a preparative scale has been applied to separate and purify cordycepin from the extract of Cordyceps militaris(L.) Link by a one-step separation. A high efficiency of HSCCC separation was achieved on a two-phase solvent system of n-hexane-n-butanol-methanol-water (23:80:30:155, v/v/v/v) by eluting the lower mobile phase at a flow rate of 2 ml/min under a revolution speed of 850 rpm. HSCCC separation of 216.2 mg crude sample (contained cordycepin at 44.7% purity after 732 cation-exchange resin clean-up) yielded 64.8 mg cordycepin with purity of 98.9% and 91.7% recovery. Identification of the target compound was performed by UV, IR, MS, (1)H NMR and (13)C NMR. 相似文献
7.
Network polymers in a rubber or a gel often contain non-uniform chain lengths. By means of dynamic Monte Carlo simulations of polymer mixtures with various compositions of two chain lengths, we investigated how the factor of polydispersity influences their strain-induced crystal nucleation. Under a high temperature and a high strain rate, the stretching of both polymers revealed that crystal nucleation is mainly accelerated by the presence of short-chain polymers; nevertheless, both polymers join together in the nucleation process. Further analysis proved that crystal nucleation is initiated from those highly stretched short segments, which are rich on the short-chain polymers. 相似文献
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A novel covert communication method of digital image is presented, based on generalized fuzzy c-means clustering (GFCM), human visual system (HVS) and discrete cosine transform (DCT). Therefore, the original image blocks are classified into two classes according to specified characteristic parameters. So one block is suited for embedding security information, but the other block is not. Hence the appropriate blocks can be selected in an image to embed the security information by selectively modifying the middle-frequency part of the original image in conjunction with HVS and DCT. Furthermore the maximal information strength is fixed based to the frequency masking. Also to improve performances of the proposed algorithm, the security information is modulated into the chaotic modulation array. The simulation results show that we can remarkably extract the hiding security information and can achieve good robustness with common signal distortion or geometric distortion and the quality of the embedded image is guaranteed. 相似文献