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1.
To improve our understanding of the combustion characteristics of propyne, new experimental data for ignition delay times (IDTs), pyrolysis speciation profiles and flame speed measurements are presented in this study. IDTs for propyne ignition were obtained at equivalence ratios of 0.5, 1.0, and 2.0 in ‘air’ at pressures of 10 and 30 bar, over a wide range of temperatures (690–1460 K) using a rapid compression machine and a high-pressure shock tube. Moreover, experiments were performed in a single-pulse shock tube to study propyne pyrolysis at 2 bar pressure and in the temperature range 1000–1600 K. In addition, laminar flame speeds of propyne were studied at an unburned gas temperature of 373 K and at 1 and 2 bar for a range of equivalence ratios. A detailed chemical kinetic model is provided to describe the pyrolytic and combustion characteristics of propyne across this wide-ranging set of experimental data. This new mechanism shows significant improvements in the predictions for the IDTs, fuel pyrolysis and flame speeds for propyne compared to AramcoMech3.0. The improvement in fuel reactivity predictions in the new mechanism is due to the inclusion of the propyne + H?2 reaction system along with ?H radical addition to the triple bonds of propyne and subsequent reactions.  相似文献   
2.
Annals of Global Analysis and Geometry - In this paper, we show that any convex affine domain with a nonempty limit set on the boundary under the action of the identity component of the...  相似文献   
3.
Waterproof light-emitting perovskite–polymer composite microparticles are synthesized by a continuous one-step microfluidic reactor, which enables in situ production of metal halide perovskite nanoparticles (MHP-NPs) by the ligand-assisted reprecipitation process (LARP) and the encapsulation of MHP-NPs by UV cross-linking polymerization in the microfluidic channel. Successful encapsulation of MHP-NPs in polymer microparticles is attributed to the co-dispersion of an LARP solution and UV polymerizable solution in an aqueous continuous phase within the microfluidic channel, in which N,N-dimethylformamide, in co-dispersion droplets, is continuously extracted to the aqueous medium upon UV polymerization. MHP-NPs–polymer composite microparticles show enhanced stability against air and moisture.  相似文献   
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5.
Studying the complex quantum dynamics of interacting many-body systems is one of the most challenging areas in modern physics. Here, we use machine learning (ML) models to identify the symmetrized base states of interacting Rydberg atoms of various atom numbers (up to six) and geometric configurations. To obtain the data set for training the ML classifiers, we generate Rydberg excitation probability profiles that simulate experimental data by utilizing Lindblad equations that incorporate laser intensities and phase noise. Then, we classify the data sets using support vector machines (SVMs) and random forest classifiers (RFCs). With these ML models, we achieve high accuracy of up to 100% for data sets containing only a few hundred samples, especially for the closed atom configurations such as the pentagonal (five atoms) and hexagonal (six atoms) systems. The results demonstrate that computationally cost-effective ML models can be used in the identification of Rydberg atom configurations.  相似文献   
6.
Annals of Global Analysis and Geometry - We study harmonic maps from a 3-manifold with boundary to $$\mathbb {S}^1$$ and prove a special case of Gromov dihedral rigidity of three-dimensional cubes...  相似文献   
7.
Journal of Radioanalytical and Nuclear Chemistry - CaCO3 powder containing C-14, which has a long half-life, is generated from the treatment process of spent activated carbons from the air cleaning...  相似文献   
8.
The effects of the ball-to-powder diameter ratio (BPDR) and the shape of the powder particles on EDEM simulation results and time in the planetary ball mill was investigated. BPDR was varied from 1 to 40/3 by changing the powder particle diameter from 8 to 0.6 ?mm. The size and shape of the powder particles do not give a significant change in both the ball motion pattern and simulation results when BPDR is over 20/3. It can be assumed that the kinetic energy of the ball has nothing to do with the size and shape of the powder particle. The simulation time and data size increase exponentially as BPDR increases. The effect of change of the powder particle shape on the calculated data size is not significant, but the more complicated its shape, the longer the simulation time, which is linearly related to the number of spheres composing a particle.  相似文献   
9.
Pd-based catalysts are the most widely used for CO oxidation because of their outstanding catalytic activity and thermal stability. However, fundamental understanding of the detailed catalytic processes occurring on Pd-based catalysts under realistic conditions is still lacking. In this study, we investigated CO oxidation on metallic Pd clusters supported on Al2O3 and SiO2. High-angle annular dark-field scanning transmission electron microscopy revealed the formation of similar-sized Pd clusters on Al2O3 and SiO2. In contrast, CO chemisorption analysis indicated a gradual change in the dispersion of Pd (from 0.79 to 0.2) on Pd/Al2O3 and a marginal change in the dispersion (from 0.4 to 0.24) on Pd/SiO2 as the Pd loading increased from 0.27 to 5.5 wt %; these changes were attributed to differences in the metal-support interactions. Diffuse reflectance infrared Fourier-transform spectroscopy revealed that fewer a-top CO species were present in Pd supported on Al2O3 than those in Pd supported on SiO2, which is related to the morphological differences in the metallic Pd clusters on these two supports. Despite the different dispersion profiles and surface characteristics of Pd, O2 titration demonstrated that linearly bound CO (with an infrared signal at 2090 cm−1) reacted first with oxygen in the case of CO-saturated Pd on Al2O3 and SiO2, which suggests that a-top CO on the terrace site plays an important role in CO oxidation. The experimental observations were corroborated by periodic density functional calculations, which confirmed that CO oxidation on the (111) terrace sites is most plausible, both kinetically and thermodynamically, compared to that on the edge or corner sites. This study will deepen the fundamental understanding of the effect of Pd clusters on CO oxidation under reaction conditions.  相似文献   
10.
The requirement of green and sustainable materials to prepare heterogeneous catalysts has intensified for practical reasons over the past few decades. Carbohydrates are possibly the most plentiful and renewable organic materials in nature with inimitable physiochemical properties, plausible low-cost and large-scale production, and sustainability features could be exploited in the generation of nanostructured heterogeneous catalysts. This review article outlines the organic transformations catalyzed by diverse carbohydrate-based nanostructured catalysts in greener and environmentally friendly processes. Selected examples are highlighted for a variety of organic reactions exploiting the proposed catalysts’ reactivity and reusability, and interactions with the intrinsic nature of the applied carbohydrate supports; advantages and speculated challenges of the introduced catalysts are deliberated as well.  相似文献   
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