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1.
Ma  Ru-ru  Wu  Jie  Wu  Kexing  Pan  Xiaohong 《Nonlinear dynamics》2022,109(4):3145-3156
Nonlinear Dynamics - This paper concerns the problem of fixed-time synchronization of master–slave Lorenz systems. The adaptive control and fixed-time control strategies are successfully...  相似文献   
2.
Efficient,robust and cost-effective electrocatalysts that catalyze hydrogen evolution/oxidation reaction(HER/HOR)in alkaline media are highly demanded.Recently,single-atom catalysts(SACs)have emerged as new promising candidates;however,the rational design of supports and the optimization of coordination environment between supports and metal atoms are challenging.In this work,we successfully fabricate atomically dispersed ruthenium(Ru)species,which are strongly coordinated by N and S dual heteroatoms on holey graphene(RuSA/NSG),as an excellent bifunctional catalyst for HER/HOR.In alkaline media,the developed catalyst exhibits high catalytic performance with a low overpotential of 57.3 mV to drive a current density of 10 mA cm-1 for HER,and its mass activity is about 5.8 times higher than that of commercial Pt/C and Ru/C catalysts at an overpotential of 100 mV.Similarly,considerable HOR performance of Ru SA/NSG is verified to be superior to Pt/C and Ru/C.Furthermore,X-ray-based spectroscopy measurements and density-functional theory calculations have confirmed that,compared with Ru–N4,the tailored Ru–N4–S2 with nearby S dopants can act as more active centers to greatly accelerate the sluggish HER/HOR kinetics in alkaline media.The present work provides a new atomic-level engineering strategy to modulate catalytic activities of SACs via the coordination design using dual heteroatoms on the carbon support.  相似文献   
3.
Constructing molecular switches based on supramolecular assembly strategy is a research hotspot. In this work, we constructed an all visible-light-regulated supramolecular photo-switch based on pyridinium-modified diarylethene derivative (DTE-Me) and cucurbit[8]uril (CB[8]). CB[8] not only accelerated the photochromic process under 365 nm ultraviolet light but also shifted the absorption of open formed DTE-Me to the visible region, which led to efficient photocyclization under 450 nm visible light irradiation, while DTE-Me and DTE-Me/CB[7] remained unchanged under the same irradiating condition. Moreover, the complexation with CB[8] could induce the strong thermally activated delayed fluorescence (TADF) of guest molecular at 550 nm, which further shifted to 670 nm through two-step sequential energy transfer with sulforhodamine B (SRB) and Cy5. This energy transfer process could also be regulated with visible light, and the application for information encryption was also demonstrated. This assembly provides a convenient approach to construct all visible light-regulated TADF photo-switch.  相似文献   
4.
Supercapacitors (SCs) with high energy density and power density are a research hotspot. Herein, we report a flexible porous carbon membrane supercapacitor prepared by electrospinning polyacrylonitrile (PAN) with γ-cyclodextrin-MOF (γ-CD-MOF) and then carbonizing at 900 °C. BET results showed that the supercapacitor retained the skeleton of γ-CD, γ-CD-MOF and the pores formed by the spun-fibers, which were 0.73, 1.09 and 23–186 nm, respectively, showing a high specific surface area of 134.7 m2/g. The hierarchically porous structures ensure rapid charge transfer and ion diffusion, resulting in the PAN/γ-CD-MOF carbon electrode with a high capacity of 283.3 F/g. Moreover, the supercapacitor had a high energy density up to 17.5 Wh/kg and power density up to 6 kW/kg. Significantly, it showed excellent cycle stability with a capacitance retention of 97.5% after 6000 cycles. This work provides a supramolecular strategy to construct a flexible porous carbon membrane, which has potential for supercapacitor applications.  相似文献   
5.
Fuzzy Optimization and Decision Making - All existing methods to estimate unknown parameters in uncertain differential equations are based on difference scheme, and do not work when the time...  相似文献   
6.
In this paper, we investigate the existence of triple positive solutions of boundary value problems for high-order fractional differential equation at resonance with singularities by using the fixed point index theory and the Leggett-Williams theorem. The spectral theory and some new height functions are also employed to establish the existence of triple positive solutions. The nonlinearity involved is arbitrary fractional derivative, and permits singularity.  相似文献   
7.
Zheng  J.  Maharaj  C.  Liu  J.  Chai  H.  Liu  H.  Dear  J. P. 《Mechanics of Composite Materials》2022,58(1):125-140
Mechanics of Composite Materials - In this research, the maximum stress, Hashin, Puck, LaRC03, and Northwestern University (NU) criteria are analyzed based literature data, analytical results...  相似文献   
8.
物理教学离不开理想化模型的建构,简化的理想模型能够帮助中学生在现有知识层面的基础上,更好地理解相关知识并解决问题.但是在实际物理问题中,如果不充分考虑理想化条件,学生在解决问题时就容易产生认知矛盾,不知所措.以一个有趣的静电场问题为例,揭示理想化模型的局限性,强调"去理想化"思维习惯的重要性.探讨分析了教师如何帮助学生打破思维定势,让其对已掌握的物理知识活学活用,培养学生严谨的科学思维.  相似文献   
9.
Liu  Shao-Hua  Tian  Bo 《Nonlinear dynamics》2022,108(3):2471-2482
Nonlinear Dynamics - In this paper, a (2+1)-dimensional Caudrey–Dodd–Gibbon–Kotera–Sawada system is investigated in fluid mechanics via the symbolic computation. With the...  相似文献   
10.
We study the local stability near the maximum figure of merit for the low-dissipation cyclic refrigerator,where the irreversible dissipation occurs not only in the thermal contacts but also the adiabatic strokes.We find that the bounds of the coefficient of performance at a maximum figure of merit or maximum cooling rate in the presence of internal dissipation are identical to those in the corresponding absence of internal dissipation.Using two different scenarios,we prove the existence of a single stable steady state for the refrigerator,and clarify the role of internal dissipation on the stability of the thermodynamic steady state,showing that the speed of system evolution to the steady state decreases due to internal dissipation.  相似文献   
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