On Anomalous Dissipation in the Plasma of the Dusty Lunar Exosphere

JETP Letters - One of the main features of the dusty plasma compared to the conventional plasma (without charged dust particles is anomalous dissipation that is caused by the charging of dust...     

Start shock waves and the vortex structures arising in the formation of jets

Experimental studies were made of the state behind a shock wave arising in front of a pulse jet in formation, and the development of the vortex structure of the jet itself. A comparison was made of the experimental axial density distribution in the jet in the region between the front of the gas and the primary shock wave with the solutions to the problem of an expanding spherical piston and the nonself-similar problem of a point explosion. Moscow Translated from Izvestiya, Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 146–150, September–October, 1988.     

Study of three-dimensional wave structure of nonstationary gas outflow from a planar sonic nozzle

Results are reported of an experimental study of the three-dimensional structure of nonstationary gas outflow from a planar nozzle. Outflow of a heated shock wave in a nitrogen tube at different moments of time from the start of outflow (0–1 msec) in two mutually perpendicular directions is considered. A scheme for reconstructing the flow at different outflow stages is proposed. The dimensions of the Riemann wave are found to oscillate.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 1, pp. 41–45, January–February, 1976.     

Resonance Properties of a Low-Pressure Dielectric Barrier Discharge

Technical Physics - The electrical characteristics of a dielectric barrier discharge (DBD) symmetrical actuator at low pressures gave been investigated. A power source–actuator–DBD...     

Synthesis, structure, and physicochemical properties of gel-forming dextran phosphates

Dextran phosphates with the degree of substitution of 0.29–1.09 with phosphoric acid groups and of 0.14–0.83 with carbamate groups were prepared in the orthophosphoric acid-urea system. The effect of the component ratio in the esterifying mixture, temperature, and pressure in the reaction zone on the structure and physicochemical properties of dextran phosphate hydrogels and on the gel fraction yield was examined.     

Synthesis of layered metal dichalcogenides with organic cations by electrochemical reduction in suspensions

Intercalated group IVB-VIB metal disulfides and diselenides MX₂ (M = Ti, Zr, Nb, Mo) can be obtained by electrochemical reduction of the corresponding MX₂ in the presence of tetraalkylammonium salt. An original approach was used, which allowed effective reduction of these insoluble substances in the form of powders suspended in an organic solvent using the standard electrolysis technique in solutions in a one-space electrolyzer with a soluble anode. Using electron transfer mediators in the process afforded intercalated compounds with yields of 60–100%.     

Characterization of H3PO4/HNO3–NANO2 oxidized bacterial cellulose and its usage as a carrier for the controlled release of cephalexin

Biocompatibility, biodegradation, good sorption characteristics, and unique structure of highly oxidized bacterial cellulose (OBC) are of great interest for the development of new drug delivery systems. In this study, OBC with 9.6, 13.0 and 19.5% carboxyl groups for 5, 20, and 48 h of synthesis, respectively, was successfully obtained using the HNO₃/H₃PO₄–NaNO₂. The results of morphological analysis showed that with an increase in the number of carboxyl groups, OBC fibers become thicker and rougher. Fourier-transform infrared spectroscopy showed the formation of carboxyl groups in the OBC after the oxidation reaction. The crystallinity of the samples according to X-Ray diffraction analysis decreased with increasing reaction time. The immobilization of cephalexin in the polymer matrix was studied in detail, it took 120 min to achieve balance in the solution with a concentration of 1 mg/ml, and the maximum amount of a sorbed antibiotic reached 43 mg/g. The drug release in vitro at 37 °C in PBS with pH 7.4 and 2.0 was prolonged. Various models were used to describe the release mechanism, the best of which was Ritger-Peppas with a diffusion exponent value ranging from 0.743 to 0.830, which explains the drug release mainly through non-Fickian diffusional release. The cephalexin-loaded OBC showed high antimicrobial activity against Gram-negative bacteria Escherichia coli and Gram-positive bacteria Staphylococcus aureus. The structure and properties of the resulting highly oxidized cellulose make it an excellent candidate as a drug delivery carrier with prolonged antimicrobial drug release characteristics.

     

Effect of composition and structure of cobalt(II) complexes with oxyaldiminopropylaerosils on their catalytic activity in the decomposition of ozone

The composition, structure, and catalytic activity in low-temperature ozone decomposition were described for cobalt(II) complexes with oxyaldiminopropyl ligands achored to aerosil A-300 differing in the nature and position of the benzene ring substituent. The effect of the geometry of the coordination unit and electronic effects of the benzene ring substituents on the catalytic activity of the cobalt(II) complexes in ozone decomposition were established.