全文获取类型
收费全文 | 1535篇 |
免费 | 37篇 |
国内免费 | 5篇 |
专业分类
化学 | 1057篇 |
晶体学 | 13篇 |
力学 | 28篇 |
数学 | 269篇 |
物理学 | 210篇 |
出版年
2021年 | 14篇 |
2020年 | 25篇 |
2019年 | 15篇 |
2018年 | 12篇 |
2017年 | 8篇 |
2016年 | 24篇 |
2015年 | 27篇 |
2014年 | 36篇 |
2013年 | 67篇 |
2012年 | 84篇 |
2011年 | 95篇 |
2010年 | 58篇 |
2009年 | 39篇 |
2008年 | 72篇 |
2007年 | 63篇 |
2006年 | 78篇 |
2005年 | 84篇 |
2004年 | 72篇 |
2003年 | 63篇 |
2002年 | 53篇 |
2001年 | 11篇 |
2000年 | 13篇 |
1999年 | 13篇 |
1998年 | 11篇 |
1997年 | 13篇 |
1996年 | 15篇 |
1995年 | 15篇 |
1994年 | 18篇 |
1993年 | 34篇 |
1992年 | 23篇 |
1991年 | 18篇 |
1990年 | 20篇 |
1989年 | 13篇 |
1988年 | 12篇 |
1987年 | 11篇 |
1986年 | 15篇 |
1985年 | 8篇 |
1984年 | 14篇 |
1983年 | 22篇 |
1982年 | 26篇 |
1981年 | 17篇 |
1980年 | 22篇 |
1979年 | 22篇 |
1978年 | 21篇 |
1977年 | 13篇 |
1976年 | 15篇 |
1975年 | 13篇 |
1974年 | 15篇 |
1973年 | 17篇 |
1970年 | 9篇 |
排序方式: 共有1577条查询结果,搜索用时 15 毫秒
1.
Measurement of emerging dechloranes in human serum using modulated gas chromatography coupled to electron capture negative ionization time‐of‐flight mass spectrometry 下载免费PDF全文
2.
XPS and resistive studies on thin films of a copper(II)‐based coordination polymer deposited on functionalized interdigital electrodes 下载免费PDF全文
Michael Günthel Jörg Hübscher Rosemarie Dittrich Edwin Weber Yvonne Joseph Florian Mertens 《Journal of Polymer Science.Polymer Physics》2015,53(5):335-344
A symmetrical 2‐thiopyrimidine based molecule with an expanded π‐electron system is synthesized and used to form a self‐assembled monolayer (SAM) on gold surfaces. Utilizing chemical vapor deposition a monolayer of (3‐mercaptopropyl)triethoxysilane is formed on silicon dioxide substrates. Both of these SAM coated substrates are characterized by X‐ray photoelectron spectroscopy and the growth of a coordination polymer built up from 5,5′‐(ethyne‐1,2‐diyl)bis(2‐hydroxyacetophenone) and copper(II) on dual SAM coated transducers is studied. After the deposition procedure on interdigital electrodes the electrical properties of the polymer are investigated performing resistive measurements. A significant change of the resistance, which depends on the surrounding atmosphere, proves the sensing behavior of the synthesized coordination polymer. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 335–344 相似文献
3.
Dr. Michela Parafioriti Dr. Minghong Ni Maurice Petitou Dr. Courtney J. Mycroft-West Dr. Timothy R. Rudd Dr. Neha S. Gandhi Prof. Vito Ferro Prof. Jeremy E. Turnbull Dr. Marcelo A. Lima Dr. Mark A. Skidmore Prof. David G. Fernig Dr. Edwin A. Yates Dr. Antonella Bisio Dr. Marco Guerrini Dr. Stefano Elli 《Chemistry (Weinheim an der Bergstrasse, Germany)》2023,29(1):e202202599
Infection of host cells by SARS-CoV-2 begins with recognition by the virus S (spike) protein of cell surface heparan sulfate (HS), tethering the virus to the extracellular matrix environment, and causing the subunit S1-RBD to undergo a conformational change into the ‘open’ conformation. These two events promote the binding of S1-RBD to the angiotensin converting enzyme 2 (ACE2) receptor, a preliminary step toward viral-cell membrane fusion. Combining ligand-based NMR spectroscopy with molecular dynamics, oligosaccharide analogues were used to explore the interactions between S1-RBD of SARS CoV-2 and HS, revealing several low-specificity binding modes and previously unidentified potential sites for the binding of extended HS polysaccharide chains. The evidence for multiple binding modes also suggest that highly specific inhibitors will not be optimal against protein S but, rather, diverse HS-based structures, characterized by high affinity and including multi-valent compounds, may be required. 相似文献
4.
Dr. Franziska Kreuzer Dr. Elena Mena-Osteritz Prof. Peter Bäuerle 《European journal of organic chemistry》2023,26(27):e202300358
Dithienopyrazines are only scarcely used as building blocks in organic electronic materials. Here, we report efficient preparation and investigation of syn- and anti-dithienopyrazines, which were functionalized with triaraylamine units to provide different series of donor-acceptor-donor-type materials. The characterization of the optoelectronic properties resulted in valuable structure-property relationships and allowed for the elucidation of the influence of structural effects such as core structure (syn vs anti), type of substituents (directly arylated vs ethynylated aryl), and substitution pattern (α,α’- vs β,β’- vs fourfold substitution). Finally, first application of a dithienopyrazine derivative as model for hole-transport materials tailored for organic electronic devices has been realized. 相似文献
5.
6.
7.
Alireza Abdollahi Edwin R. van Dam Mojtaba Jazaeri 《Designs, Codes and Cryptography》2017,84(1-2):73-85
We classify the distance-regular Cayley graphs with least eigenvalue \(-2\) and diameter at most three. Besides sporadic examples, these comprise of the lattice graphs, certain triangular graphs, and line graphs of incidence graphs of certain projective planes. In addition, we classify the possible connection sets for the lattice graphs and obtain some results on the structure of distance-regular Cayley line graphs of incidence graphs of generalized polygons. 相似文献
8.
This paper describes the nonlinear, postcritical behavior of parametrically excited, shallow, cylindrical panels, which are modeled with two or four degrees of freedom. The analysis shows complicated dynamic behavior. Stable, periodic motions coexist with the trivial solution for very small values of the excitation amplitude. Moreover, a stable, chaotic attractor could be found coexisting with the trivial solution.
Sommario Si studia il comportamento postcritico nonlineare di pannelli cilindrici ribassati, soggetti ad eccitazione parametrica e modellati con due o quattro gradi di libertà. L'analisi evidenzia un comportamento dinamico complesso. Moti periodici stabili coesistono con la soluzione banale per valori molto piccoli dell'ampiezza dell'eccitazione. Un attrattore caotico stabile coesiste altresì con tale soluzione per alcuni valori della frequenza dell'eccitazione.相似文献
9.
A new sub-pixel correlation peak locating algorithm for PIV analysis is introduced. The method is theoretically consistent with the method of continuously shifting interrogation sub-windows by fractional displacements, which has proven to be an effective way to reduce the bias error associated with integer pixel aliasing, or peak-locking. However the proposed algorithm performs continuous window shifting in the spatial frequency domain using the shift property of the Fourier transform, thus it is equivalent to interpolating the original digital image with the Fourier transform reconstruction. Synthetic and real PIV images are used to test the new algorithms performance relative to that of traditional (non-iterative) peak-finding methods and other peak-locking reduction algorithms, such as the continuous window shifting technique. The resultant bias error of the proposed algorithm is smaller (by an order of magnitude in some cases), and importantly, the periodic nature of the bias error, the characteristic signature of peak-locking, is eliminated as long as the discrete particle images have been sampled at a rate greater than the Nyquist sampling frequency. Moreover, this new algorithm is shown to be computationally efficient and it converges faster than the competing algorithms. 相似文献
10.
Pantelis Bampoulis Kai Sotthewes Edwin Dollekamp Bene Poelsema 《Surface Science Reports》2018,73(6):233-264
The behavior of water in close proximity to other materials under ambient conditions is of great significance due to its importance in a broad range of daily applications and scientific research. The structure and dynamics of water at an interface or in a nanopore are often significantly different from those of its bulk counterpart. Until recently, experimental access to these interfacial water structures was difficult to realize. The advent of two-dimensional materials, especially graphene, and the availability of various scanning probe microscopies were instrumental to visualize, characterize and provide fundamental knowledge of confined water. This review article summarizes the recent experimental and theoretical progress in a better understanding of water confined between layered Van der Waals materials. These results reveal that the structure and stability of the hydrogen bonded networks are determined by the elegant balance between water-surface and water-water interactions. The water-surface interactions often lead to structures that differ significantly from the conventional bilayer model of natural ice. Here, we review the current knowledge of water adsorption in different environments and intercalation within various confinements. In addition, we extend this review to cover the influence of interfacial water on the two-dimensional material cover and summarize the use of these systems in potential novel applications. Finally, we discuss emerged issues and identify some flaws in the present understanding. 相似文献