Preparation and characterization of novel polyimide‐silica hybrids

Polyimide‐silica (PI‐SiO₂) hybrids were prepared from a novel polyimide (PI), derived from pyromellitic dianhydride (PMDA), 1,6‐bis(4‐aminophenoxy)hexane (synthesized) and 4,4′‐oxydianiline. SiO₂ networks (5–30 wt%) were generated through sol–gel process using either tetraethylorthosilicate (TEOS) or a mixture of 3‐aminopropyltriethoxysilane‐PMDA‐based coupling oligomers (APA) and TEOS. Thin, free standing hybrid films were obtained from the respective mixtures by casting and curing processes. The hybrid films were characterized using Fourier transform infrared, ²⁹Si nuclear magnetic resonance (NMR), field emission scanning electron microscopy (FE‐SEM), energy dispersive X‐ray spectrometry and atomic force microscopy (AFM) techniques. ²⁹Si NMR results provide information about formation of organically modified silicate structures that were further substantiated by FE‐SEM and AFM micrographs. Contact angle measurements and thermogravimetric thermograms reveal that the addition of APA profoundly influences surface energy, interfacial tension, thermal stability and the residual char yield of modified hybrids in comparison to those obtained by mixing only TEOS. It was found that reduced particle size, efficient dispersion and improved interphase interactions were responsible for the eventual property enhancement. Copyright © 2012 John Wiley & Sons, Ltd.     

Preparation and dispersion stability of aqueous metal oxide nanofluids for potential heat transfer applications: a review of experimental studies

Journal of Thermal Analysis and Calorimetry - Nanofluids have recently attracted attention of many researchers due to their growing potential applications in heat transfer devices. They possess...     

Quantum Spin Half Algebra and Generalized Megrelishvili Protocol for Confidentiality of Digital Images

International Journal of Theoretical Physics - Most of the enciphering structures are based on the transformation of mediums by describing the strict criteria. The presented article is based on...     

Interaction with Al and Zn induces structure formation and aggregation in natively unfolded caseins

Caseins are phosphoproteins that form the principal protein component of milk, their chief function being the transport of inorganic calcium and phosphate to the neonates. The four major members of the casein family are alpha(s1)-, alpha(s2)- (together referred to as alpha(s)-casein), beta- and kappa-casein, each having a characteristic high negative net charge as well as high hydrophobicity and preferring extended conformational states in solution. We have investigated the influence of the polyvalent metal cations Zn(II) and Al(III) on the structure of bovine caseins, using fluorescence and circular dichroic (CD) spectroscopy and light scattering. Changes in Trp and ANS fluorescence parameters (blue shifts of the emission maxima and enhancement of fluorescence intensity) and in the far-UV CD spectra of the caseins caused by the presence of both metals suggest that conformational changes are induced in them by low concentrations (20-40 microM) of the metal cations. These changes lead to formation of solvent-accessible hydrophobic clusters or cavities that, in turn, cause self-association and precipitation of caseins at higher concentration of the metals. These conclusions are supported by increased binding of ThT to the caseins, as well as enhancement of light scattering intensity, observed in presence of Al(III). The chaperonic property of alpha(s)-casein, which enables it to inhibit thermal aggregation of alcohol dehydrogenase, is shown to be partially destroyed by Zn(II)-induced structural alterations, due possibly to loss of flexibility of the natively unfolded casein chains.     

Electrophile-driven regioselective synthesis of functionalized quinolines

Highly substituted 3-iodoquinolines bearing different alkyl and aryl moieties can be synthesized in moderate to excellent yields (up to 99%) by 6-endo-dig iodocyclization of 2-tosylaminophenylprop-1-yn-3-ols with molecular iodine (I(2)) under mild conditions. The cyclization is highly regioselective and the resulting 3-iodoquinolines can be further functionalized by various coupling reactions.     

Alstonia scholaris: Struktur des Indolalkaloides Narelin

Alstonia scholaris: The structure of the indole alkaloid nareline Besides the known akuammidine, picralinal, picrinine and pseudoakuammigine a new indole alkaloid called nareline (M=352) was isolated from Alstonia scholaris R. BR. , which belongs to the plant family of Apocynaceae. Its structure 2 was deduced by single crystal X-ray diffraction. 2 represents the absolute configuration. The spectroscopic data of 2 and its derivatives (Scheme 1) as well as their chemical behavior support this structure. In biogenetic sense nareline is related to the bases akuammiline ( 4 ) and picraline ( 5 ) (Scheme 2). In contrast to those the C-atom 5 is exocyclic and represents an aldehyde group which forms together with the oxygen atom of the N (4)-hydroxylamine group a cyclic half acetale. - By oxidation (CrO₃/CH₃COOH) of 2 the oxindol derivative 19 (oxonareline) is formed which contains a cyclic acetal as a partial structure element (Scheme 4).     

Influence of chitosan and epoxy cross-linking on physical properties of binary blends

In this study, blends of chitosan (Cs) and bisphenol-F-diglycidyl ether (3.80 × 10^?3 to 3.80 × 10^?2 mol) were cast by the solution route. FT-IR results suggested that chitosan was cross-linked at terminal amino groups through diepoxide linkage. The chitosan films became less flexible and stiffer upon reaction with epoxy. Blending improved percentage elongation (31%) and toughness (10 MPa), whereas Young’s modulus (145 MPa) and tensile strength (45 MPa) were decreased. Extent of weight loss in Cs/BPFDGE was lower (15%) than that of original precursors (chitosan 33%). Moreover, blending of chitosan with BPFDGE increased water absorption properties due to generation of hydrophilic ?OH groups.     

Magnetic nanoparticles (Fe<Subscript>3</Subscript>O<Subscript>4</Subscript> &amp; Co<Subscript>3</Subscript>O<Subscript>4</Subscript>) and their applications in urea biosensing

Nanobiotechnology has opened a new and exciting opportunities for exploring urea biosensor based on magnetic nanoparticles (NPs) mainly Fe₃O₄ and Co₃O₄. These NPs have been extensively exploited to develop biosensors with stability, selectivity, reproducibility and fast response time. This review gives an overview of the development of urea biosensor based on Fe₃O₄ and Co₃O₄ for in vitro diagnostic applications along with significant improvements over the last few decades. Additionally, effort has been made to elaborate properties of magnetic nanoparticles (MNPs) in biosensing aspects. It also gives details of recent developments in hybrid nanobiocomposite based urea biosensor.     

Tractors,mass, and Weyl invariance

Deser and Nepomechie established a relationship between masslessness and rigid conformal invariance by coupling to a background metric and demanding local Weyl invariance, a method which applies neither to massive theories nor theories which rely upon gauge invariances for masslessness. We extend this method to describe massive and gauge invariant theories using Weyl invariance. The key idea is to introduce a new scalar field which is constant when evaluated at the scale corresponding to the metric of physical interest. This technique relies on being able to efficiently construct Weyl invariant theories. This is achieved using tractor calculus—a mathematical machinery designed for the study of conformal geometry. From a physics standpoint, this amounts to arranging fields in multiplets with respect to the conformal group but with novel Weyl transformation laws. Our approach gives a mechanism for generating masses from Weyl weights. Breitenlohner–Freedman stability bounds for Anti-de Sitter theories arise naturally as do direct derivations of the novel Weyl invariant theories given by Deser and Nepomechie. In constant curvature spaces, partially massless theories—which rely on the interplay between mass and gauge invariance—are also generated by our method. Another simple consequence is conformal invariance of the maximal depth partially massless theories. Detailed examples for spins s?2$s?2$ are given including tractor and component actions, on-shell and off-shell approaches and gauge invariances. For all spins s?2$s?2$ we give tractor equations of motion unifying massive, massless, and partially massless theories.