首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   160篇
  免费   8篇
化学   89篇
力学   9篇
数学   22篇
物理学   48篇
  2022年   2篇
  2021年   5篇
  2020年   5篇
  2019年   3篇
  2018年   9篇
  2017年   3篇
  2016年   9篇
  2015年   11篇
  2014年   6篇
  2013年   16篇
  2012年   16篇
  2011年   11篇
  2010年   5篇
  2009年   10篇
  2008年   6篇
  2007年   6篇
  2006年   4篇
  2005年   4篇
  2004年   2篇
  2003年   6篇
  2002年   3篇
  2001年   2篇
  2000年   1篇
  1999年   3篇
  1998年   5篇
  1997年   1篇
  1996年   1篇
  1992年   3篇
  1986年   1篇
  1984年   1篇
  1979年   1篇
  1978年   2篇
  1976年   4篇
  1975年   1篇
排序方式: 共有168条查询结果,搜索用时 15 毫秒
1.
2.
3.
Mechanochemistry has recently emerged as an environmentally friendly solventless synthesis method enabling a variety of transformations including those impracticable in solution. However, its application in the synthesis of well‐defined nanomaterials remains very limited. Here, we report a new bottom‐up mechanochemical strategy to rapid mild‐conditions synthesis of organic ligand‐coated ZnO nanocrystals (NCs) and their further host–guest modification with β‐cyclodextrin (β‐CD) leading to water‐soluble amide‐β‐CD‐coated ZnO NCs. The transformations can be achieved by either one‐pot sequential or one‐step three‐component process. The developed bottom‐up methodology is based on employing oxo‐zinc benzamidate, [Zn44‐O)(NHOCPh)6], as a predesigned molecular precursor undergoing mild solid‐state transformation to ZnO NCs in the presence of water in a rapid, clean and sustainable process.  相似文献   
4.
We prove that given a family \((G_t)\) of strictly pseudoconvex domains varying in \(\mathcal {C}^2\) topology on domains, there exists a continuously varying family of peak functions \(h_{t,\zeta }\) for all \(G_t\) at every \(\zeta \in \partial G_t\).  相似文献   
5.
In this paper we give a brief review of the pseudo-Riemannian geometry of the five-dimensional homogeneous space for the conformal group O(4, 2). Its topology is described and its relation to the conformally compactified Minkowski space is discussed. Its metric and geodesics are calculated using a generalized half-space representation. Compactification via Lie-sphere geometry is outlined. Possible applications to Jaime Keller’s START theory may follow by using its predecessor - the 5-optics of Yu. B. Rumer. The point of view of Rumer is given extensively in the last section of the paper.  相似文献   
6.
This paper presents comparative experimental studies of the morphology and elemental composition of fly ash particles from coal- and biomass-fired boilers, deposited in each stage of 3-stage electrostatic precipitators (ESPs). It was shown that fly ash morphology, its physical properties, and the percentage of elements in the fly ash taken from each stage of ESP depend on the kind of fuel. The biomass fly ash contains many irregular large particles, which are pieces of unburned wood. Bulk density of biomass fly ash is on average lower than that of coal fly ash, and drastically decreases in the second and third stages of ESP. The resistivity, measured at electric field of 4 kV/cm, of fly ash from biomass-fired boilers is much lower than that from coal, and can be below 102 Ω m, whereas from coal, except the first stage, varies in the range from 107 to 1010 Ω m. The low resistivity of coal fly ash in the first stage of ESP results from high carbon content, and of biomass is probably an effect of additional high percentage of potassium, calcium and sodium sulfates. The percentage of Si, Al, Na, Fe, and Ti in fly ash from coal-fired boilers is much higher than from biomass, and in the opposite, the percentage of Mg, K, Ca, Mn, Mo, S, Cl, and P in biomass ash exceeds that in coal fly ash. Potential detrimental effects of biomass combustion products (salts, acids, tar) leaving the boiler on the construction elements of the electrostatic precipitator, including electrodes and HV insulators have been discussed in this paper. It was concluded that the long-term effects of biomass co-firing on the electrostatic precipitator performance, including the collection efficiency, have not been sufficiently studied in the literature and these issues require further detailed investigations.  相似文献   
7.
Analysis of the thermo-mechanical behavior of electrospun thermoplastic polyurethane (TPU) block co-polymer nanofibers (glass transition temperature ∼−50 °C) is presented. Upon heating, nanofibers began to massively contract, at ∼70 °C, whereas TPU cast films started to expand. Radial wide-angle X-ray scattering (WAXS) profiles of the nanofibers and the films showed no diffraction peaks related to crystals, whereas their amorphous halo had an asymmetric shape, which can be approximated by two components, associated with hard and soft segments. During heating, noticeable changes in the contribution of these components were only observed in nanofibers. These changes, which were accompanied with an endothermic DSC peak, coinciding with the start of the nanofibers contraction, can be attributed to relaxation of an oriented stretched amorphous phase created during electrospinning. Such structure relaxation becomes possible when a portion of the hard segment clusters, forming an effective physical network, is destroyed upon heating.  相似文献   
8.
Several classical constructions illustrate the fact that the chromatic number of a graph may be arbitrarily large compared to its clique number. However, until very recently no such construction was known for intersection graphs of geometric objects in the plane. We provide a general construction that for any arc-connected compact set $X$ X in $\mathbb{R }^2$ R 2 that is not an axis-aligned rectangle and for any positive integer $k$ k produces a family $\mathcal{F }$ F of sets, each obtained by an independent horizontal and vertical scaling and translation of $X$ X , such that no three sets in $\mathcal{F }$ F pairwise intersect and $\chi (\mathcal{F })>k$ χ ( F ) > k . This provides a negative answer to a question of Gyárfás and Lehel for L-shapes. With extra conditions we also show how to construct a triangle-free family of homothetic (uniformly scaled) copies of a set with arbitrarily large chromatic number. This applies to many common shapes, like circles, square boundaries or equilateral L-shapes. Additionally, we reveal a surprising connection between coloring geometric objects in the plane and on-line coloring of intervals on the line.  相似文献   
9.
Unter Verwendung der hochauflösenden γ-Spektrometrie wurde das Verhalten von 95Zr und 95Nb in Extraitionsprozessen untersucht. Die Versuche wurden mit Tributylphosphalproben, die wir im Gleichgewicht mit wäβrigen Salpetersäurelosungen bestrahlten, durchgefuhrt. Für 95Nb wurde ein unregelmäβiges Verhalten während der Extraktionsprozesse festgestellt. Aus diesem Grunde ist zur Abschätzung der radiolytischen Zersetzung von TBP die summarische Messung der 95Zr- und 99Nb-γ-Strahlungsintensität nicht ausreichend.  相似文献   
10.
This work expands on the recent separation of the enantiomers of the C2-symmetrical bis-substituted derivatives of 1,1′-diphosphaferrocene. The effective separation of mono-substituted 1,1′-diphosphaferrocenes by the proposed method is demonstrated. The absolute configuration of the three separated components was established using X-ray diffraction. Circular dichroism spectra were collected for all of the separated compounds. The spectrum of each compound shows a characteristic curve, and the curves for the enantiomers are symmetrical. We also show that the correct absolute configuration for similar species can be assigned on the basis of the obtained data. We propose an explanation for the abnormal 1H NMR spectra of phospholyl protons in some derivatives of 1,1′-diphosphaferrocene. A density functional theory (DFT) study of the conformation, as well as circular dichroism and NMR spectra of the chosen species, is also presented.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号