裂纹技术的基本原理与应用研究进展

本文介绍裂纹技术的基本原理及其应用。裂纹技术通过使裂纹沿给定路线扩展去达到切割材料的目的,它由魏庆同和郎福元在文[2]中首次提出。本文还概要讨论了裂纹技术中四个典型的力学问题,特别是断裂力学的逆问题。笔者希望这篇文章能够引起国内外学者对裂纹技术及其问题的关注。     

聚合物微球固载N-羟基邻苯二甲酰亚胺催化剂的制备及其催化氧化性能初探

首先采用悬浮聚合法,制备了甲基丙烯酸缩水甘油酯(GMA)和甲基丙烯酸甲酯(MMA)的交联聚合物微球(GMA/MMA),然后经过几步大分子反应在微球表面合成与固载了N-羟基邻苯二甲酰亚胺(NHPI),形成固载有NHPI的功能微球GMA/MMA-NHPI。采用红外光谱(FT-IR)及扫描电子显微镜(SEM)等方法对功能微球进行了表征。结果表明,以含环氧基团的GMA/MMA为载体,通过大分子反应可实现NHPI的合成与固载。GMA/MMA-NHPI与醋酸钴(Co(OAc)2)构成的共催化体系,在分子氧对环己烷和环己醇的氧化过程中,显示出良好的催化活性。     

聚合物微球固载的N-羟基邻苯二甲酰亚胺在分子氧氧化甲苯过程中的催化性能

以交联聚苯乙烯(CPS)微球为基质,经过几步大分子反应在微球表面合成与固载了N-羟基邻苯二甲酰亚胺(NHPI),形成固载有NHPI的聚合物微球CPS-NHPI。本文主要将CPS-NHPI与过渡金属盐组成共催化体系,用于分子氧氧化甲苯的反应,考察了该非均相催化剂的催化特性与催化氧化机理。结果表明,几种过渡金属盐中,Co(OAc)2的助催化效果最好;微球CPS-NHPI与Co(OAc)2所构成的共催化体系,在温和条件(80℃和常压氧气)下可有效地将甲苯深度氧化为苯甲酸,显现出高的催化活性(甲苯转化率达到57%)与优良的选择性(苯甲酸的选择性达到84%)。催化氧化反应遵循自由基链式反应机理。主催化剂CPS-NHPI固载的NHPI与助催化剂Co(OAc)2适宜的摩尔比为14∶1,主催化剂所含NHPI为底物的12(mol)%时,催化剂用量较为合适。固体催化剂CPS-NHPI具有良好的再循环使用性能。     

GCr15/35CrMo摩擦副的塑性接触面积对滑动磨损的影响

基于分形理论,计算了35CrMo钢试样经过压缩疲劳试验后变形区域以及和GCr15配副滑动磨损后的实际接触面积Ar、塑性接触面积Arp和塑性接触面积比率Arp/Ar,分析了塑性接触面积Arp和塑性接触面积比率Arp/Ar的变化量δArp和δArp/Ar与磨损量的关系,采用扫描电子显微镜观察了35CrMo钢试样磨损表面的形貌.结果表明:35CrMo试块经过压缩疲劳以及和GCr15配副滑动磨损后,接触面材料的剥落引起了塑性接触面积Arp和塑性接触面积比率Arp/Ar的减少,塑性接触面积比率的变化量δArp/Ar可以描述磨损量的变化,当δArp/Ar-0.5时,磨损量急剧增加.     

苜蓿草粉对金属材料磨损性能的影响

采用正交试验法在磨料磨损试验机上考察了不同粒度苜蓿草粉对45#钢和HT200灰铸铁磨损性能的影响,研究了不同载荷和转速等条件下的磨料磨损行为,采用扫描电子显微镜对其磨损表面形貌进行观察.结果表明:影响材料磨损性能的因素由大到小依次为转速、磨粒粒度和载荷;苜蓿草粉磨粒对金属材料表面的磨损为硬、软磨粒共同作用的结果;45#钢在硬磨料磨损条件下以显微切削为主要磨损机制,在软磨粒磨损条件下以多次塑性变形和低周期疲劳为主要磨损机制;HT200灰铸铁以塑性变形而产生的脆化剥落为主要磨损机制.     

SSC直线注入器RFQ腔体多物理场分析

SSC-LINAC是为兰州重离子研究装置（HIRFL）设计的直线注入器,它将U34+离子加速到1 MeV/u注入到分离扇回旋加速器（SSC）中,为冷却储存环（CSR）提供10 MeV/u的U34+。该注入器可以将SSC引出的重离子流强提高一个量级以上。SSC-LINAC由一个RFQ（Radio Frequency Quadrupole）加速器和4个DTL（drift tube linac）组成,设计频率为53.667 MHz。RFQ工作在连续波模式,设计功率30 kW,如果不能有效地冷却,高频电流在电极表面产生的热量会使RFQ的腔壁和电极发生形变,从而导致腔体频率的漂移以及加速和聚焦电场的改变。因此,为了保证连续波工作的RFQ加速器稳定运行,对水冷模式和通道设计提出了很高的要求。作者用有限元软件ANSYS对RFQ进行高频电磁场、温度场、结构应力的耦合分析,验证了冷却方案设计的可行性和可靠性。Heavy Ion Research Facility at Lanzhou(HIRFL) consists of SFC, SSC, CSRm and CSRe. A new linac injector, which will increase U34+ to 1 MeV/u, is designed for SSC to increase the beam intensity to ten times higher. The new injector, whose frequency is 53.667 MHz, is composed by a RFQ (Radio Frequency Quadrupole) cavity and four DTL(Drift Tube Linac) cavities. The RFQ cavity, whose RF power is 30 kW, is operated at CW(continuous wave) mode. The heat produced by HF (high frequency) electromagnetic will cause deformation of RFQ structure, lead to the resonant frequency shift, and reduce the focusing efficiency of the cavity. An efficient cooling system is necessary to ensure that the RFQ cavity can stably be operated at the nominal frequency. A detailed multi-physics field coupling analysis of RFQ has been finished with 3D finite elements software ANSYS. The result of the analysis shows that the water cooling system can cool the RFQ cavity fully and keep the frequency drift be in a acceptable level.     

Multi-physics analysis of the RFQ for Injector Scheme Ⅱ of C-ADS driver linac

A 162.5 MHz, 2.1 MeV radio frequency quadruples (RFQ) structure is being designed for the Injector Scheme Ⅱ of the China Accelerator Driven Sub-critical System (C-ADS) linac. The RFQ will operate in continuous wave (CW) mode as required. For the CW normal conducting machine, the heat management will be one of the most important issues, since the temperature fluctuation may cause cavity deformation and lead to the resonant frequency shift. Therefore a detailed multi-physics analysis is necessary to ensure that the cavity can stably work at the required power level. The multi-physics analysis process includes RF electromagnetic analysis, thermal analysis, mechanical analysis, and this process will be iterated for several cycles until a satisfactory solution can be found. As one of the widely accepted measures, the cooling water system is used for frequency fine tunning, so the tunning capability of the cooling water system is also studied under different conditions. The results indicate that with the cooling water system, both the temperature rise and the frequency shift can be controlled at an acceptable level.     

Multi-physics analysis of the RFQ for Injector Scheme II of C-ADS driver linac

A 162.5 MHz, 2.1 MeV radio frequency quadruples （RFQ） structure is being designed for the Injector Scheme Ⅱ of the China Accelerator Driven Sub-critical System （C-ADS） linac. The RFQ will operate in continuous wave （CW） mode as required. For the CW normal conducting machine, the heat management will be one of the most important issues, since the temperature fluctuation may cause cavity deformation and lead to the resonant frequency shift. Therefore a detailed multi-physics analysis is necessary to ensure that the cavity can stably work at the required power level. The multi-physics analysis process includes RF electromagnetic analysis, thermal analysis, mechanical analysis, and this process will be iterated for several cycles until a satisfactory solution can be found. As one of the widely accepted measures, the cooling water system is used for frequency fine tunning, so the tunning capability of the cooling water system is also studied under different conditions. The results indicate that with the cooling water system, both the temperature rise and the frequency shift can be controlled at an acceptable level.