空调制冷专业实验室建设探索

结合高等职业教育空调制冷专业实验室建设的实际情况,阐述了建设制冷专业实验室的必要性;根据制冷专业的特点和人才培养目标,分析了现有制冷专业实验室存在的一些问题,提出了具有建设性的意见;并对实验室进一步建设提出了规划方案,同时对现有的专业实验室提出了改进措施。     

水相中可见光曙红Y催化合成异喹啉酮衍生物

建立了一种简单实用的在水相中可见光下2-卤代-N-苯基苯甲酰胺与二苯乙炔为原料,室温条件下,采用便宜、易处理且环境友好的曙红Y作光催化剂,催化反应获得较好收率的一系列的异喹啉酮类产物,生成相应的目标产物最高产率可达到86％,为异喹啉酮类化合物的合成提供了一种简便经济的方法.     

金属丝切变模量测量实验中扭转角度和摆长影响的研究

通过测定扭摆在不同摆长和不同扭转角度下金属丝的切变模量和长方体铁块的转动惯量,研究了扭转角度和摆长对实验结果的影响,结果表明,摆长和扭转角度大于某一数值时,可以保证较好的实验测量精度和合理的实验时间。     

Adsorption dynamics of double-stranded DNA on a graphene oxide surface with both large unoxidized and oxidized regions

The adsorption dynamics of double-stranded DNA (dsDNA) molecules on a graphene oxide (GO) surface are important for applications of DNA/GO functional structures in biosensors, biomedicine and materials science. In this work, molecular dynamics simulations were used to examine the adsorption of different length dsDNA molecules (from 4 bp to 24 bp) on the GO surface. The dsDNA molecules could be adsorbed on the GO surface through the terminal bases and stand on the GO surface. For short dsDNA (4 bp) molecules, the double-helix structure was partially or totally broken and the adsorption dynamics was affected by the structural fluctuation of short dsDNA and the distribution of the oxidized groups on the GO surface. For long dsDNA molecules (from 8 bp to 24 bp) adsorption is stable. By nonlinear fitting of the contact angle between the axis of the dsDNA molecule and the GO surface, we found that a dsDNA molecule adsorbed on a GO surface has the chance of orienting parallel to the GO surface if the length of the dsDNA molecule is longer than 54 bp. We attributed this behavior to the flexibility of dsDNA molecules. With increasing length, the flexibility of dsDNA molecules also increases, and this increasing flexibility gives an adsorbed dsDNA molecule more chance of reaching the GO surface with the free terminal. This work provides a whole picture of adsorption of dsDNA molecules on the GO surface and should be of benefit for the design of DNA/GO based biosensors.     

Influence of atomic force microscope (AFM) probe shape on adhesion force measured in humidity environment

In micro-manipulation, the adhesion force has very important influence on behaviors of micro-objects. Here, a theoretical study on the effects of humidity on the adhesion force is presented between atomic force microscope （AFM） tips and substrate. The analysis shows that the precise tip geometry plays a critical role on humidity depen- dence of the adhesion force, which is the dominant factor in manipulating micro-objects in AFM experiments. For a blunt （paraboloid） tip, the adhesion force versus humidity curves tends to the apparent contrast （peak-to-valley corrugation） with a broad range. This paper demonstrates that the abrupt change of the adhesion force has high correla- tion with probe curvatures, which is mediated by coordinates of solid-liquid-vapor contact lines （triple point） on the probe profiles. The study provides insights for further under- standing nanoscale adhesion forces and the way to choose probe shapes in manipulating micro-objects in AFM experiments.     

由覆杯实验引申的压强问题研究

针对覆杯实验中杯内留有空气仍能支撑水柱的实验进行了定量的分析和推导,通过理论和实验分析总结出了该实验现象出现的原因,并就要重复实现本实验的条件进行了总结.     

高纯度(>98%)三芳基-2-硼酸的合成

以卤代芳烃为原料,经硼酸化反应和Suzuki偶联反应合成了一系列三芳基-2-硼酸化合物,收率67.4%~70.1%,纯度均98%,其结构经1H NMR和元素分析确证。