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0IntroductionNiobateshavemanykindsofstructures.TheseareperovskitetypeABO3(KNbO3),tungstenbronzetypeANb2O6(Ba2NaNb5O15),chainandlamellartypes犤1~11犦.SincethenewcompoundK6CrNb15O42withakindoftunnelstructureinthepotassiumniobatesystemwasfoundinourlaboratoryforthefirsttime犤12犦,wehavesynthesizedaseriesofcompoundswiththesamestructure,forexample,K6FeNb15O42,K6Ni0.67Nb15.33O42,Ba6Cr4Nb12O42andBa6Ni2.67Nb13.33O42etc.T… 相似文献
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