首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   37693篇
  免费   1518篇
  国内免费   1375篇
化学   16747篇
晶体学   342篇
力学   1786篇
综合类   114篇
数学   9975篇
物理学   11622篇
  2023年   204篇
  2022年   351篇
  2021年   364篇
  2020年   413篇
  2019年   396篇
  2018年   1496篇
  2017年   1745篇
  2016年   1141篇
  2015年   974篇
  2014年   1006篇
  2013年   1294篇
  2012年   3918篇
  2011年   3067篇
  2010年   2307篇
  2009年   2003篇
  2008年   1134篇
  2007年   1163篇
  2006年   1051篇
  2005年   4833篇
  2004年   4184篇
  2003年   2519篇
  2002年   698篇
  2001年   491篇
  2000年   307篇
  1999年   355篇
  1998年   283篇
  1997年   214篇
  1996年   201篇
  1995年   184篇
  1994年   150篇
  1993年   118篇
  1992年   248篇
  1991年   214篇
  1990年   197篇
  1989年   146篇
  1988年   135篇
  1987年   88篇
  1986年   67篇
  1985年   72篇
  1984年   44篇
  1983年   40篇
  1979年   36篇
  1976年   85篇
  1975年   38篇
  1974年   41篇
  1973年   49篇
  1972年   40篇
  1969年   38篇
  1968年   35篇
  1966年   37篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
一类多维指数分布的参数估计   总被引:2,自引:0,他引:2  
考虑生存函数为(F)(x1,x2,…,xn)=P{X1>x1,…,Xn>xn}=exp{-[n∑i=1(xi/θi)1/δ]δ}(0<xi<∞,0<δ≤ 1,0<θi<∞,i=(1,n))的一类多维指数分布,给出了它的密度函数的表示式,并讨论了它的性质.提出了相关参数δ的估计(^δ),证明了(^δ)有相合性和渐近正态性,得到了(^δ)的渐近方差σ2δ.最后还给出了若干随机模拟的结果.  相似文献   
3.
A new solvent-free sample preparation method using silver trifluoroacetate (AgTFA) was developed for the analysis of low molecular weight paraffins and microcrystalline waxes by laser desorption/ionization time-of-flight mass spectrometry (LDI-TOFMS). Experiments show that spectral quality can be enhanced by dispersing AgTFA directly in liquid paraffins without the use of additional solvents. This preparation mixture is applied directly to the MALDI probe. Solid waxes could be examined by melting prior to analysis. The method also provides sufficiently reproducible spectra that peak area ratios between mono- and bicyclic alkane peaks indicated variations in the cycloalkane content of paraffin samples. Dehydrogenation of hydrocarbons observed during the desorption/ionization process was studied by analysis of alkane standards.  相似文献   
4.
The versatile behavior of a trihydrazidophosphoradamantane allowing the synthesis of a variety of neutral, mono- or di-cationic water-soluble molecules of potential interest for biphasic catalysis is reported.  相似文献   
5.
We build a metric space which is homeomorphic to a Cantor set but cannot be realized as the attractor of an iterated function system. We give also an example of a Cantor set K in R3 such that every homeomorphism f of R3 which preserves K coincides with the identity on K.  相似文献   
6.
A criterion for the nonexplosion of solutions to semilinear evolution equations on Banach spaces is proved. The result is obtained by applying a modification of the Bihari type inequality to the case of a weakly singular nonlinear integral inequality.  相似文献   
7.
不完全信息群体决策专家权重的集结   总被引:8,自引:5,他引:3  
本文对于属性权重信息和属性效用信息都不完全的群体多属性决策问题,通过构造属性值区间和运用系统聚类分析法,对群体决策中的专家进行分类,并确定每位专家的权重.  相似文献   
8.
We consider the one-dimensional steady-state semiconductor deviceequations modelling a pnpn device. There are two relevant scalingsof the equations corresponding to small and large applied voltages.In both scalings, the semiconductor equations can be consideredas singularly perturbed. It turns out that the small-voltagescaling breaks down for current values between two saturationcurrents. In that interval, the large-voltage scaling has tobe employed. For both scalings, we derive the first-order termsof an asymptotic expansion and show that the reduced problemhas a solution. An example verifies that the current-voltagecurves obtained have the expected qualitative structure.  相似文献   
9.
Well‐defined diblock and triblock copolymers composed of poly(N‐isopropylacrylamide) (PNIPAM) and poly(ethylene oxide) (PEO) were successfully synthesized through the reversible addition–fragmentation chain transfer polymerization of N‐isopropylacrylamide (NIPAM) with PEO capped with one or two dithiobenzoyl groups as a macrotransfer agent. 1H NMR, Fourier transform infrared, and gel permeation chromatography instruments were used to characterize the block copolymers obtained. The results showed that the diblock and triblock copolymers had well‐defined structures and narrow molecular weight distributions (weight‐average molecular weight/number‐average molecular weight < 1.2), and the molecular weight of the PNIPAM block in the diblock and triblock copolymers could be controlled by the initial molar ratio of NIPAM to dithiobenzoate‐terminated PEO and the NIPAM conversion. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4873–4881, 2004  相似文献   
10.
The development during the last 15 years and the state-of-the-art in the analysis of bulk steroid hormone drugs and hormone-like structures and pharmaceutical formulations made thereof are summarized. Other steroids (sterols, bile acids, cardiac glycosides, vitamins D) as well as biological-clinical aspects and pharmacokinetic and metabolic studies are excluded from this review. The state-of-the-art is summarized based on comparisons of monographs in the latest editions of the European Pharmacopoeia, United States Pharmacopoeia and the Japanese Pharmacopoeia. This is followed by sections dealing with new developments in the methodology for the fields of spectroscopic and spectrophotometric, chromatographic, electrophoretic and hyphenated techniques as well electroanalytical methods. The review is terminated by two problem-oriented sections: examples on impurity and degradation profiling as well as enantiomeric analysis.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号