Direct visualization of structural defects in 2D semiconductors

Direct visualization of the structural defects in two-dimensional (2D) semiconductors at a large scale plays a significant role in understanding their electrical/optical/magnetic properties, but is challenging. Although traditional atomic resolution imaging techniques, such as transmission electron microscopy and scanning tunneling microscopy, can directly image the structural defects, they provide only local-scale information and require complex setups. Here, we develop a simple, non-invasive wet etching method to directly visualize the structural defects in 2D semiconductors at a large scale, including both point defects and grain boundaries. Utilizing this method, we extract successfully the defects density in several different types of monolayer molybdenum disulfide samples, providing key insights into the device functions. Furthermore, the etching method we developed is anisotropic and tunable, opening up opportunities to obtain exotic edge states on demand.     

Reduced graphene oxide as saturable absorbers for erbium-doped passively mode-locked fiber laser

We demonstrate a nanosecond mode-locked erbium-doped fiber laser(EDFL)based on a reduced graphene oxide(RGO)saturable absorber(SA).The RGO SA is prepared by depositing the graphene oxide(GO)on fluorine mica through thermal reduction of GO.A scanning electron microscope(SEM),Raman spectrometer,and x-ray photoelectron spectroscopy(XPS)are adopted to analyze the RGO characteristics.The results show that the reduction degree of graphene oxide is very high.By embedding the RGO SA into the EDFL cavity,a stable mode-locked fiber laser is achieved with a central wavelength of 1567.29 nm and repetition rate of 12.66 MHz.The maximum output power and the minimum pulse duration are measured to be 18.22 mW and 1.38 ns respectively.As far as we know,the maximum output power of18.22 mW is higher than those of other nanosecond mode-locked oscillators reported.Such a nanosecond pulse duration and megahertz repetition rate make this mode-locked erbium-doped fiber laser a suitable seed oscillator for high-power applications and chirped pulse amplifications.     

有理三角Bézier曲线曲面光滑融合的构造

为了使自由曲线曲面在较为简单的条件下能够达到相对高阶的光滑拼接，并在不改变控制顶点的情况下自由调整曲线曲面的形状，构造了含多个形状参数的有理三角函数.基于该组基函数，定义了含多个形状参数的有理三角曲线曲面，并讨论了曲线曲面的光滑拼接条件.根据拼接条件，分别定义了由含多个形状参数的有理三角曲线曲面构成的分段组合曲线、分片组合曲面.这种新的曲线曲面能够自动保证组合曲线、曲面的连续性.数值实例的结果显示了该方法的有效性.     

水在HfO2(111)和(110)表面的吸附与解离

运用广义梯度近似密度泛函理论方法(GGA-PW91)结合周期平板模型, 研究水分子在二氧化铪(111)和(110)表面不同吸附位置在不同覆盖度下的吸附行为. 通过比较不同吸附位的吸附能和几何构型参数发现:(111)和(110)表面铪原子(top 位)是活性吸附位. 水分子与表面的吸附能值随覆盖度的变化影响较小. 在(111)和(110)表面, 水分子都倾向以氧端与表面铪原子相互作用. 同时也计算了羟基、氧和氢在表面的吸附, Mulliken 电荷布居, 态密度及部分频率. 结果表明, 在两种表面羟基以氧端与表面铪相互作用, 氧原子与表面铪和氧原子同时成键, 而氢原子直接与表面氧原子相互作用形成羟基. 通过过渡态搜索, 水分子在(111)和(110)表面发生解离, 反应能垒分别为9.7和17.3 kJ·mol^-1, 且放热为59.9和47.6 kJ·mol^-1.     

Using Reduced Graphene Oxide to Generate Q-Switched Pulses in Er-Doped Fiber Laser

Using the reduced graphene oxide(rGO) as a saturable absorber(SA) in an Er-doped fiber(EDF) laser cavity,we obtain the Q-switching operation. The rGO SA is prepared by depositing the GO on fluorine mica(FM) using the thermal reduction method. The modulation depth of rGO/FM is measured to be 3.2%. By incorporating the rGO/FM film into the EDF laser cavity, we obtain stable Q-switched pulses. The shortest pulse duration is3.53 μs, and the maximum single pulse energy is 48.19 nJ. The long-term stability of working is well exhibited.The experimental results show that the rGO possesses potential photonics applications.     

超薄层BCP对有机电致发光器件性能的影响

采用真空热蒸镀的方法,在常规的双层器件结构的基础上,设计了三层双异质结有机电致发光器件(OLED):indium-tin oxide(ITO)/N,N′-diphenyl-N,N′-bis(1-naphthyl)(1,1′-biphenyl)-4,4′-diamine(NPB)/2,9-dimethyl-4,7-diphenyl-1,10-phenan throline(BCP)/8-hydroxyquinoline aluminum(Alq3)/Mg∶Ag。通过对器件的电致发光(EL)光谱及器件性能的表征,研究了不同超薄层BCP的厚度对OLED器件性能的影响。结果表明,当超薄层BCP的厚度从0.1nm逐渐增加到4.0nm时,器件的EL光谱实现了绿光→蓝绿光→蓝光的变化;BCP层有效地调节了载流子的复合区域,改变了器件的发光颜色,提高了器件的亮度和发光效率。     

Spectral Characteristics of White Organic Light-emitting Diodes Based on Novel Phosphorescent Sensitizer

采用新型贵金属铱的配合物bis(1,2-dipheny1-1H-benzoimida-zole)iridium (acetylacetonate)作为磷光敏化剂,与荧光染料4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-en-yl)-4H-pyran共同掺杂到聚合物主体材料poly(N-vinylcarbazole)中，以N,N'-diphenyl-N,N'-bis(1-naphthyl) (1,1'-biphenyl)-4,4'-diami-ne作为蓝光发光层，制备了白色有机电致发光器件. 通过对掺杂体系的紫外-可见吸收光谱、光致发光光谱以及电致发光光谱的表征，分析了该磷光敏化体系的能量转移机制. 结果表明，在该聚合物磷光荧光双掺杂体系中，由于磷光与荧光材料之间的不完全的F?rster能量传递过程，导致电致发光光谱中同时存在磷光材料三线态到基态与荧光材料单线态到基态的辐射衰减发光. 该掺杂体系成功实现了白光发射，随着偏置电压的升高，器件的CIE色坐标有微小的红移，但都非常接近等能白光点，器件表现出了很好的色纯度.     

在线固相萃取/液相色谱-线性离子阱质谱法同时定性定量检测全血和尿液中7种抗凝血杀鼠药北大核心CSCD

建立了同时测定全血和尿液样品中7种抗凝血杀鼠药的在线固相萃取／液相色谱-线性离子阱质谱（ on-line SPE／LC-LIT／MS）分析方法。用乙腈沉淀样品中的蛋白质,于稀释、离心、过滤后直接进样。经在线固相萃取柱富集纯化;以 C18柱为分析柱,甲醇-乙酸铵水溶液（0.02 mol／L）为流动相进行梯度洗脱;在电喷雾电离（ ESI）负离子模式下,记录目标母离子在锁定保留时间窗口内的二级全扫描信号,通过自建数据库进行定性确证,挑选高灵敏度与专属性的二级子离子进行定量,从而实现7种杀鼠药的同时定性和定量分析。7种杀鼠药在各自质量浓度范围内线性关系良好,相关系数为0.9946～0.9997,检出限和定量限分别为0.02～1.00 ng／mL 和0.10～4.00 ng／mL,3个添加水平的回收率为81.0％～113.9％,相对标准偏差为0.1％～6.2％（ n＝6）。该方法简单方便,灵敏度高,能够满足全血和尿液样品中7种抗凝血杀鼠药的快速筛查和准确定量。     

混合蓝色和绿色发射的高亮度白色有机电致发光器件

使用星形六苯芴类新材料1,2,3,4,5,6-hexakis(9,9-diethyl-9H-fluoren-2-y1)benzene(HKEthFLYPh)分别制备了三种不同结构的有机电致发光器件.在结构为indium-tin oxide(ITO)/NPB(40nm)/HKEthFLYPh(10nm)/Alq3(50nm)/Mg:Ag(200nm)的器件中,获得了两个电致发光谱峰分别位于435和530nm处的明亮白光.HKEthFLYPh足能量传输层;N,N'-bis-(1-naphthyl)-N,N'-diphenyl-(1,1'-biphenyl)-4,4'-diamine(NPB)是空穴传输层和蓝色发光层;tris(8-hydroxyquinoline)aluminum(Alq3)是电子传输层和绿色发光层.结果表明,当驱动电压为15V时,器件的最大亮度达到8523cd·m-2;在5.5V时,器件达到最大流明效率为1.01m·W-1.在电压为9V时,CIE色坐标为(0.29,0.34).此外,通过改变HKEthFLYPh层的厚度,发现蓝色发射的相对强度随着HKEthFLYPh层厚度的增加而增强.